Content: Transmission infrared spectroscopy for high surface area oxides / Michael L. Hair --
Applications of Fourier transform infrared spectroscopy to studies of adsorbed species / Alexis T. Bell --
Organic monolayer studies using Fourier transform infrared reflection spectroscopy / D.L. Allara --
Intermolecular interactions and the infrared reflection-absorption spectra of chemisorbed carbon monoxide on copper / P. Hollins and J. Pritchard --
Investigation of carbon monoxide on nickel(100) by infrared ellipsometric spectroscopy / J.D. Fedyk and M.J. Dignam --
Surface electromagnetic wave spectroscopy / R.J. Bell, R.W. Alexander, Jr., and C.A. Ward --
Raman spectroscopic studies of surface species / B.A. Morrow --
Investigations of adsorption centers, molecules, surface complexes, and interactions among catalyst components by diffuse reflectance spectroscopy / K. Klier --
The application of high resolution electron energy loss spectroscopy to the characterization of adsorbed molecules on rhodium single crystal surfaces / L.H. Dubois and G.A. Somorjai --
An electron energy loss spectroscopic investigation of the adsorption of nitric oxide, carbon monoxide, and hydrogen on the basal plane of ruthenium / Patricia A. Thiel and W. Henry Weinberg --
Inelastic electron tunneling spectroscopy / John Kirtley --
Neutron scattering spectroscopy of adsorbed molecules / H. Taub.
Author(s): Alexis T. Bell and Michael L. Hair (Eds.)
Series: ACS Symposium Series 137
Publisher: American Chemical Society
Year: 1980
Language: English
Pages: 295
City: Washington, D.C
Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
Some History......Page 7
Silica......Page 8
Sample Preparation......Page 10
Isotopic Exchange......Page 11
2. Surface Acidity.......Page 13
Conclusions......Page 15
LITERATURE CITED......Page 16
Optical Principles......Page 18
Comparison of Fourier-Transform and Grating Spectrometers......Page 23
Applications of Fourier-Transform Spectroscopy......Page 30
Acknowledgment......Page 38
Literature Cited......Page 39
3 Organic Monolayer Studies Using Fourier Transform Infrared Reflection Spectroscopy......Page 41
Theory......Page 42
Acetic Acid......Page 43
Relationship to Catalysis......Page 48
Conclusions......Page 52
References......Page 53
4 Intermolecular Interactions and the Infrared Reflection-Absorption Spectra of Chemisorbed Carbon Monoxide on Copper......Page 54
Infrared Spectra of CO Adsorbed on Polycrystalline Copper......Page 55
Surface Coverage Effects in the Infrared Spectra of Chemisorbed CO......Page 58
Dipole Coupling......Page 62
Image Effects in Dipole Coupling......Page 64
Spectra of 12CO-13CO Mixtures on Cu (111)......Page 67
Implications of Dipole Coupling for the Interpretation of Transmission Infrared Spectra of Adsorbates on Supported Metals......Page 73
Literature Cited......Page 75
IRES Spectroscopy......Page 78
Experimental Procedures......Page 87
Results and Discussion......Page 89
Summary and Conclusions......Page 98
Abstract......Page 99
Literature Cited......Page 100
Two Media......Page 101
Three Media......Page 105
Optical Excitation of Sew......Page 108
Results......Page 110
Conclusion......Page 116
Literature Cited......Page 119
7 Raman Spectroscopic Studies of Surface Species......Page 121
Experimental Considerations......Page 122
Adsorption on Zeolites......Page 124
Chemisorption on Oxides......Page 128
The Surface Structure of Oxide Catalysts......Page 133
Adsorption on Metals......Page 135
Summary......Page 139
Literature Cited......Page 140
Theory......Page 143
Vibrational Spectra......Page 147
Correlation Motion......Page 152
Electronic Spectra of Adsorption Centers and Complexes.......Page 154
Photoluminescence......Page 157
Electronic Spectra of Bulk Catalyst Particles......Page 160
Abstract......Page 161
Literature Cited......Page 162
Overview......Page 165
Experimental......Page 169
The Chemisorption of CO on Rhodium......Page 170
The Chemisorption of Acetylene and Ethylene on Rh (111) (24)......Page 177
Conclusion......Page 187
Literature Cited......Page 188
10 An Electron Energy Loss Spectroscopic Investigation of the Adsorption of Nitric Oxide, Carbon Monoxide, and Hydrogen on the Basal Plane of Ruthenium......Page 193
Electron Energy Loss Spectroscopy......Page 194
Experimental Methods......Page 195
Adsorption and Dissociation of Nitric Oxide (12,14)......Page 197
Co-adsorption of Nitric Oxide and Carbon Monoxide (13)......Page 206
Conclusions......Page 213
Literature Cited......Page 215
The Fundamentals......Page 218
Resolution and Sensitivity......Page 224
Intensities and Selection Rules......Page 229
Applications......Page 236
VI. Conclusions......Page 243
Literature Cited......Page 245
I. Distinguishing Features of Neutron Scattering as a Surface Probe......Page 247
II. Vibrational Spectroscopy of Adsorbed Molecules by Inelastic Neutron Scattering......Page 250
III. Determination of the Orientation of Adsorbed Molecules by Elastic Neutron Diffraction......Page 269
IV. Conclusions and Prospects for the Future......Page 275
IV. Acknowledgement......Page 276
Abstract......Page 277
Literature Cited......Page 278
A......Page 281
C......Page 282
D......Page 284
F......Page 285
I......Page 286
M......Page 288
N......Page 289
R......Page 290
S......Page 292
V......Page 294
Z......Page 295
