Content: Raymond B. Seymour : coming of age with polymers / W.N. Tinnerman --
Degradation of polymers in hostile environments / Herman F. Mark --
Effects of radiation environments on plastics / Malcolm Dole --
Thermal analysis of metal-containing polymers : generalizations / Charles E. Carraher, Jr. --
New styrene-maleic anhydride terpolymer blends / W.J. Hall, R.L. Kruse, R.A. Mendelson, and Q.A. Trementozzi --
Polyphenylene sulfide (PPS) in harsh environments / Van C. Vives, J.S. Dix, and D.G. Brady --
Advances in high-performance polymers / Raymond B. Seymour --
Model fungicidal monomers, polymers, and latices for paints / Charles U. Pittman, Jr. and G. Allan Stahl --
Typical uses and durability of various plastics in hostile environments / A.A. Boova --
Water permeation through elastomers / Patrick E. Cassidy --
Polyurethane aging in water and methanol environments / Douglas L. Faulkner, Michael G. Wyzgoski, and Mark E. Myers, Jr. --
Hostile effects of oxygenated solvent interaction with type II rigid poly(vinyl chloride) / Richard F. Miller and Paul E. Rider --
Chemical and solvent resistance of selected styrene-maleic anhydride copolymers / Richard F. Miller --
Effects of ethanol/gasoline and methyl t-butyl ether/gasoline mixtures on elastomers / Ismat A. Abu-Isa --
Effects of ozone exposure on the physical properties of butadiene and styrene/butadiene copolymers / K.E. Stephens and C.L. Beatty --
X-ray photoemission spectroscopic study of the effect of ozone on various styrene/butadiene copolymers / K.E. Stephens, M. Ammons, C.D. Batich, C.L. Beatty, and W. Swartz --
Environmental corrosion of polymers : causes and main reactions / B. Rånby and J.F. Rabek --
Influence of sulfur dioxide on organic coatings / W. Funke and H. Haagen --
Photochemical degradation and biological defacement of polymers / P.D. Gabriele, J.R. Geib, R.M. Iannucci, and W.J. Reid.
Author(s): David P. Garner and G. Allan Stahl (Eds.)
Series: ACS Symposium Series 229
Publisher: American Chemical Society
Year: 1983
Language: English
Pages: 330
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Raymond Β. Seymour: Coming of Age with Polymers......Page 9
2 Degradation of Polymers in Hostile Environments......Page 17
Discussion......Page 18
Summary......Page 21
3 Effects of Radiation Environments on Plastics......Page 22
Major Chemical Effects......Page 23
Effects of Radiation on Physical Properties......Page 25
Resistance of Polymers to Radiation......Page 27
Literature Cited......Page 28
4 Thermal Analysis of Metal-Containing Polymers: Generalizations......Page 30
Generalizations......Page 31
Degradation Pathways......Page 33
Attempts to Enhance Thermal Stabilities......Page 38
Differentiation of Depolymerization Mechanisms......Page 42
Coupled Instrumentation Employing MS......Page 45
Summary......Page 47
Recommendations......Page 48
Literature Cited......Page 49
5 New Styrene-Maleic Anhydride Terpolymer Blends......Page 51
Results and Discussion......Page 52
Acknowledgment......Page 65
Literature Cited......Page 66
6 Polyphenylene Sulfide (PPS) in Harsh Environments......Page 67
Chemical Resistance......Page 68
Resistance To Automotive Fluids......Page 73
Thermal Stability......Page 77
Weatherability......Page 82
Flammability......Page 83
Radiation Resistance......Page 84
Applications......Page 85
Literature Cited......Page 86
7 Advances in High-Performance Polymers......Page 88
Polyacetals (POM)......Page 89
Polyamides......Page 90
Polycarbonates......Page 92
Polyphenylene oxide......Page 93
Polyphenylene sulfide......Page 94
Polyaryl esters......Page 95
Polyether ether ketone......Page 96
Polyimides......Page 97
Literature Cited......Page 98
Summary......Page 100
Introduction......Page 101
Monomer Preparation......Page 104
Acrylate and Extended-Chain Acrylate Synthesis12,14-16......Page 108
Known Biological Activity of the Monomers......Page 109
Polymerizations12,14,16......Page 111
Latex Syntheses14......Page 119
Derivatization of Preformed Polymers with Fungicidal Moieties......Page 123
Minimum Inhibitory Concentration Tests......Page 124
Agar Dish Accelerated Growth Tests......Page 128
Effect of UV Exposure......Page 133
"Zabel" Accelerated Growth Tests......Page 136
Conclusions......Page 137
Literature Cited......Page 138
9 Typical Uses and Durability of Various Plastics in Hostile Environments......Page 140
Design Criteria......Page 141
Fabrication......Page 143
B. Insert for Existing Carbon Steel Tube Pickling Tank(Figure 2)......Page 145
Summary......Page 147
10 Water Permeation Through Elastomers......Page 151
Discussion......Page 152
Effects of Elevated Temperature......Page 155
Effect of Mechanical Stress on Permeability......Page 159
Conclusions......Page 167
Literature Cited......Page 169
11 Polyurethane Aging in Water and Methanol Environments......Page 170
Experimental......Page 171
Chemical Analysis......Page 172
Chemical Analysis......Page 173
Conclusions......Page 187
Literature Cited......Page 188
12 Hostile Effects of Oxygenated Solvent Interaction with Type II Rigid Poly(vinyl Chloride)......Page 189
EXPERIMENTAL......Page 191
Results and Discussion......Page 193
Literature Cited......Page 199
13 Chemical and Solvent Resistance of Selected Styrene-Maleic Anhydride Copolymers......Page 200
Experimental......Page 201
Results and Discussion......Page 206
Literature Cited......Page 217
14 Effects of Ethanol/Gasoline and Methyl t-Butyl Ether/Gasoline Mixtures on Elastomers......Page 220
Experimental......Page 221
Results and Discussion......Page 223
Literature Cited......Page 255
Experimental......Page 256
Tensile Stress-Strain......Page 257
Results and Discussion......Page 259
Summary......Page 264
Literature Cited......Page 270
16 x-Ray Photoemission Spectroscopic Study of the Effect of Ozone on Various Styrene/Butadiene Copolymers......Page 272
Contact Angle Measurement and Critical Surface Energy......Page 274
XPS Study......Page 276
Literature Cited......Page 282
17 Environmental Corrosion of Polymers Causes and Main Reactions......Page 284
Mechanical corrosion of polymers by particulate matter......Page 286
Corrosion of polymers by sulfur oxides......Page 288
Corrosion of polymers by nitrogen oxides......Page 290
Photochemical smog......Page 291
Photosensitized reaction by hydrocarbons......Page 293
Free radical oxidation processes......Page 294
Oxidation processes with atomic oxygen, ozone and singlet oxygen......Page 295
Service Life of Polymeric Materials in Polluted Atmosphere......Page 296
Conclusions......Page 297
Literature Cited......Page 298
Corrosion Protection......Page 301
Comparison of SO2 Permeability with Permeabilities of Other Gases......Page 303
Literature Cited......Page 306
19 Photochemical Degradation and Biological Defacement of Polymers......Page 308
3. Multiple Internal Reflectance (MIR) Infrared Spectroscopy.......Page 312
RESULTS......Page 313
DISCUSSION......Page 317
CONCLUSION......Page 320
Literature Cited......Page 321
C......Page 322
D......Page 323
G......Page 324
K......Page 325
Ο......Page 326
Ρ......Page 327
S......Page 328
T......Page 329
Ζ......Page 330
