Content: Research in the stereochemistry of cobalt complexes / John C. Bailar, Jr. --
Absolute configuration of transition metal complexes / Yoshihiko Saito --
Circular dichroic intensities in the vibronic transitions of chiral metal complexes / Frederick S. Richardson --
Stereochemical correlations in the circular dichroism of d-d and charge-transfer transitions : applications to tris(bidentate) complexes / Pieter E. Schipper --
Circular dichroism spectra of square planar complexes containing prochiral olefins and their stereoselective olefin exchange / Kazuo Saito --
Chirality induction in coordination complexes / A.M. Sargeson --
Stereochemistry of microbial iron transport compounds / Kenneth N. Raymond, Kamal Abu-Dari, and Stephen R. Sofen --
Rational approaches to asymmetric hydrogenation / John M. Brown, Penny A. Chaloner, Barry A. Murrer, and David Parker --
Circular dichroism as a probe of metal ion interaction with azoproteins / J. Ivan Legg, Kozo Igi, Gary J. Pielak, Brian D. Warner, and Mickey S. Urdea --
Preparation and circular dichroism spectra of cobalt(III) complexes containing chiral aminophosphine chelate ligands / Isamu Kinoshita, Kazuo Kashiwabara, and Junnosuke Fujita --
Effect of solvent on the circular dichroism of metal complexes / Trevor D. Bailey and Clifford J. Hawkins --
The nature of the equilibrium displacement mechanism for the Pfeiffer effect in inorganic chemistry / Stanley Kirschner and Paul Serdiuk --
Phenyl substituent contributions in circular dichroism spectra of cobalt(III) complexes of ethylenediamine-N, Nʹ-diacetate ion --
Gary G. Hawn, Chris Maricondi, and Bodie E. Douglas --
Additivity of circular dichroism of d-d transitions : the vicinal effect in a homologous series of triethylenetetraaminecobalt(III) amino acid complexes / Robert Job --
Circular dichroism spectra of cobalt(III) complexes having optical activity owing to the arrangement of unidentate ligands / M. Shibata, S. Fujinami, and S. Shimba --
Optical resolution of facial and meridional tris(aminoacidato)cobalt(III) chelates by d-tartrate and by antimony d-tartrate / Hayami Yoneda, Shigeo Yamazaki, and Tomoyo Yukimoto --
Stereoselective synthesis of quadridentate ligands utilizing a template reaction of metal complexes / M. Saburi, T. Makino, K. Hata, K. Miyamura, and S. Yoshikawa --
Stereochemistry of cobalt(III) [beta]-ketoaminates and some mixed-ligand analogues / Charles J. Hinrichsen and Robert C. Fay --
Absolute configurations from solution reactions : the tris(diimine)iron(II)/cyanide inversion reaction / Ronald D. Archer and Christopher J. Hardiman --
Photoacoustic detection of natural circular dichroism in crystalline transition metal complexes / Richard Alan Palmer, Joseph C. Roark, and James C. Robinson --
Stereochemical description and notation for coordination systems / Thomas E. Sloan and Daryle H. Busch.
Author(s): Bodie E . Douglas and Yoshihiko Saito (Eds.)
Series: ACS Symposium Series 119
Publisher: American Chemical Society
Year: 1980
Language: English
Pages: 443
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Research in the Stereochemistry of Cobalt Complexes......Page 9
Literature Cited......Page 18
Five-Membered Chelate Rings......Page 21
Six-membered Chelate Rings......Page 25
Seven-Membered Chelate Rings......Page 28
Circular Dichroism Spectra of Tris(diamine)cobalt(III) Complexes......Page 30
Diethylenetriamine Complexes......Page 34
Complexes with a Cyclic Terdentate, R-MeTACN......Page 35
Electron-density Distribution in D3 Complexes......Page 39
The Crystal Structure of Active Racemates and Other Diastereoisomers......Page 40
Structural Study of Asymmetric Hydrogenation......Page 43
Literature Cited......Page 47
3 Circular Dichroic Intensities in the Vibronic Transitions of Chiral Metal Complexes......Page 51
II. Theory......Page 55
III. Examples......Page 74
Literature Cited......Page 79
4 Stereochemical Correlations in the Circular Dichroism of d-d and Charge-Transfer Transitions: Applications toTris(bidentate) Complexes......Page 81
Chromophore Definitions: The Model......Page 83
Circular Dichroism of Charge Transfer Transitions......Page 86
Circular Dichroism of the d-d Transitions......Page 89
Applications......Page 96
Literature Cited.......Page 98
5 Circular Dichroism Spectra of Square Planar Complexes Containing Prochiral Olefins and Their Stereoselective Olefin Exchange......Page 99
CD Pattern of Rhodium(I) and Platinum(II) Complexes......Page 100
Stereo-selectivity on Olefin Exchange......Page 114
Abbreviations......Page 121
Literature Cited......Page 122
6 Chirality Induction in Coordination Complexes......Page 123
Stereospecific hydration of olefins......Page 125
Stereo Specificity directed by the Chelates......Page 131
Stereospecific addition of CN- at a chelated imine - orbital steering......Page 132
Stereospecific Carbinolamine Formation......Page 134
Chiral metal ion cages......Page 136
Literature Cited......Page 138
7 Stereochemistry of Microbial Iron Transport Compounds......Page 140
Model Hydroxamate Complexes......Page 141
Hydroxamate Siderophore Complexes......Page 151
Thiohydroxamate Siderophore Complexes......Page 156
Catecholate Siderophore Complexes......Page 161
Model Catecholate Complexes......Page 165
Summary......Page 168
Literature Cited......Page 172
8 Rational Approaches to Asymmetric Hydrogenation......Page 175
Stereoselection in Metal-Olefin Complexation......Page 176
Mechanistic Studies on Asymmetric Hydrogenation......Page 178
Catalysis and Binding by 5-Ring Chelate Biphosphine Rhodium Complexes......Page 181
Catalysis and Binding by 7-Ring Chelate Biphosphine Rhodium Complexes......Page 183
Catalytic Asymmetric Hydrogenation of other Substrates by 7-Ring Chelate Biphosphines......Page 191
Rhodium Complexes with Larger-ring Chelates of Chiral Biphosphines......Page 193
Rationalization and Summary......Page 196
Literature Cited......Page 198
Azophenol Chelation of Metal Ions as Determined by Ligand Associated Spectral Changes......Page 201
Preparation of Model Azoligand Co(III) Complexes for the Characterization of Co(III) Azoprotein Derivatives......Page 203
Circular Dichroic Properties of Model Azophenol and Azonaphthol Complexes......Page 206
Circular Dichroism as a Monitor of Co (III) Chelation by an Azotyrosine in a Protein......Page 209
Acknowledgment......Page 211
Literature Cited......Page 212
10 Preparation and Circular Dichroism Spectra of Cobalt(III) Complexes Containing Chiral Aminophosphine Chelate Ligands......Page 213
Preparation of Complexes......Page 214
a) trans-[CoCl2(aminophosphine)2]+......Page 216
b) [Co(acac)2L]+......Page 219
Literature Cited......Page 225
Stereoselective Solvation of the Chiral Ligand......Page 226
Solvation of the Non-Chiral Ligand......Page 229
Conformer Population Change......Page 230
Solvent Dependent CD of Pentaamminecobalt(III) Complexes of Chiral Carboxylates......Page 231
Literature Cited......Page 241
12 The Nature of the Equilibrium Displacement Mechanism for the Pfeiffer Effect in Inorganic Chemistry......Page 243
The Equilibrium Displacement Mechanism......Page 244
Absolute Configuration and Equilibrium Displacement......Page 246
Hydrogen Bonding and the Pfeiffer Effect......Page 250
Environment Compounds With No Available Hydrogen for Hydrogen Bonding......Page 251
Literature Cited......Page 257
Additivity of Circular Dichroism Contributions......Page 259
Circular Dichroism of Ethylenediaminediacetic Acid Complexes......Page 261
Literature Cited......Page 275
14 Additivity of Circular Dichroism of d-d Transitions: The Vicinal Effect in a Homologous Series of Triethylenetetraaminecobalt(III) Amino Acid Complexes......Page 277
Discussion......Page 278
Literature Cited......Page 290
Syntheses and Optical Resolutions of Complexes with cis-cis Distribution of Unidentates......Page 292
Synthesis and CD Spectra of Complexes Containing 1,1,1-Tris (aminomethyl) ethane or Hexaniobate Ion as a Terdentate Ligand......Page 304
Synthesis and CD Spectra of a Series of Complexes Containing 1,4,7-Triazacyclononane......Page 306
Literature Cited......Page 316
Complete Resolution of fac-[Co(β-ala)3]......Page 318
Separation and Identification of Isomers of fac-[Co(α-AA)3-n(β-AA)n] (6)......Page 319
Trend of the Separation Factors of Enantiomeric Pairs Eluted with d-Tart......Page 320
Trend of the Seaparation Factors of Enantiomeric Pairs Eluted with Antimony d-Tart......Page 322
Association Model of Sb d-Tart (10)......Page 324
Literature Cited......Page 327
17 Stereoselective Synthesis of Quadridentate Ligands Utilizing a Template Reaction of Metal Complexes......Page 328
Summary......Page 336
Literature Cited......Page 338
18 Stereochemistry of Cobalt(III) β-Ketoaminates and Some Mixed-Ligand Analogues......Page 339
Experimental Section......Page 340
Results and Discussion......Page 344
Literature Cited......Page 357
19 Absolute Configurations from Solution Reactions: The Tris(diimine)iron(II)/Cyanide Inversion Reaction......Page 359
Handedness......Page 361
Activation Parameter Separation Through Stereochemical Results......Page 362
Unsymmetrical Diimine Potential......Page 365
Experimental Section......Page 366
Results and Discussion......Page 368
Addendum......Page 372
Literature Cited......Page 373
20 Photoacoustic Detection of Natural Circular Dichroism in Crystalline Transition Metal Complexes......Page 376
The Nature of the Condensed Phase Photocacoustic Effect......Page 377
The PACD Experiment......Page 379
PAS Theory......Page 380
PACD Theory......Page 382
Experimental......Page 385
Discussion......Page 387
Literature Cited......Page 395
21 Stereochemical Description and Notation for Coordination Systems......Page 397
Ligand Indexing......Page 400
Chemical Abstracts Service Stereochemical Notation......Page 406
More Complex Stereochemical Systems......Page 414
Literature Cited......Page 418
A......Page 420
Β......Page 422
C......Page 423
D......Page 430
E......Page 431
I......Page 432
M......Page 434
N......Page 435
O......Page 436
P......Page 437
R......Page 439
S......Page 440
T......Page 441
V......Page 442
Z......Page 443
