Content: Metal-metal multiple bonds and metal clusters : new dimensions and new opportunities in transition metal chemistry / F.A. Cotton --
Anything one can do, two can do, too : and it's more interesting / Malcolm H. Chisholm --
Structure and reactivity of some unusual molybdenum and tungsten cluster systems / R.E. McCarley, T.R. Ryan, and C.C. Torardi --
Rhodium carbonyl cluster chemistry under high pressures of carbon monoxide and hydrogen : polynuclear rhodium carbonyl complexes and their relationships to mononuclear and binuclear rhodium carbonyl complexes / José L. Vidal, R.C. Schoening, and W.E. Walker --
Photochemistry of metal-metal-bonded transition element complexes / Mark S. Wrighton, James L. Graff, John C. Luong, Carol L. Reichel, and John L. Robbins --
Thermal and photochemical reactivity of H₂FeRu₃(CO)₁₃ and related mixed-metal clusters / Gregory L. Geoffroy, Henry C. Foley, Joseph R. Fox, and Wayne L. Gladfelter --
Kinetic studies of thermal reactivities of metal-metal-bonded carbonyls / Anthony Poë --
Metal-metal bond making and breaking in binuclear complexes with phosphine bridging ligands / Alan L. Balch --
Binuclear hydridoplatinum complexes with platinum-platinum bonds / R.J. Puddephatt --
Thermochemistry of metal-metal bonds / J.A. Connor and H.A. Skinner --
Breaking metal-metal multiple bonds : their use as synthetic starting materials / Richard A. Walton --
The novel reactivity of the molybdenum-molybdenum triple bond in Cp₂Mo₂(CO)₄ / M. David Curtis, Louis Messerle, Nicephoros A. Fotinos, and Robert F. Gerlach --
Reactivity of dimetallocycles / Andrew F. Dyke, Stephen R. Finnimore, Selby A.R. Knox, Pamela J. Naish, A. Guy Orpen, Geoffrey H. Riding, and Graham E. Taylor --
The coordination chemistry of metal surfaces / Earl L. Muetterties --
New approaches to the chemistry of di- and trimetal complexes : synthesis, chemical reactivity, and structural studies / Terence V. Ashworth, Michael J. Chetcuti, Louis J. Farrugia, Judith A.K. Howard, John C. Jeffery, Rona Mills, Geoffrey N. Pain, F. Gordon A. Stone, and Peter Woodward.
Author(s): Malcolm H. Chisholm (Eds.)
Series: ACS Symposium Series 155
Publisher: American Chemical Society
Year: 1981
Language: English
Pages: 324
City: Washington, D.C
Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
1 Metal-Metal Multiple Bonds and Metal Clusters New Dimensions and New Opportunities in Transition Metal Chemistry......Page 6
Survey of M-M Bonds and Clusters......Page 7
Evidence for Multiple Bonds......Page 9
Strengths of M-M Bonds......Page 14
Comparison of Clusters and Multiple Bonds......Page 15
Relevance and Uses......Page 16
Literature Cited......Page 19
Coordination Numbers and Geometries......Page 22
Ligand Substitution Reactions (17)......Page 27
Stereochemical Lability......Page 28
Organometallic Reactions......Page 29
Direct Attack on the M-M Multiple Bond......Page 38
Conclusions......Page 39
Abstract......Page 40
Literature Cited......Page 41
Experimental......Page 45
Rectangular Clusters......Page 46
New Ternary Molybdenum Oxides......Page 53
Abstract......Page 63
Literature Cited......Page 64
4 Rhodium Carbonyl Cluster Chemistry Under High Pressures of Carbon Monoxide and Hydrogen Polynuclear Rhodium Carbonyl Complexes and Their Relationships to Mononuclear and Binuclear Rhodium Carbonyl Complexes1......Page 65
RESULTS AND DISCUSSION......Page 67
ACKNOWLEDGEMENT......Page 85
LITERATURE CITED......Page 86
5 Photochemistry of Metal-Metal-Bonded Transition Element Complexes......Page 88
Photochemistry of Dinuclear Complexes......Page 89
Photochemistry of Trinuclear Complexes......Page 105
Photochemistry of Tetranuclear Complexes......Page 107
Literature Cited......Page 111
6 Thermal and Photochemical Reactivity of H2FeRu3(CO)13 and Related Mixed-Metal Clusters......Page 114
Results and Discussion......Page 115
Summary and Outlook......Page 134
Literature Cited......Page 135
7 Kinetic Studies of Thermal Reactivities of Metal-Metal-Bonded Carbonyls......Page 138
Reactivities and Reaction Mechanisms of M2(CO)10 (M2 = Mn2, Tc2, MnRe, and Re2) and some Substituted Derivatives......Page 140
Reactivities and Reaction Mechanisms of Co2(CO)8 and Some Substituted Derivatives......Page 149
Reactivities and Reaction Mechanisms of Some Metal-Carbonyl Clusters......Page 150
Reactivities and the Strengths of Metal-Metal Bonds in Organometallic Compounds......Page 157
Recent Kinetic Studies of Some Co4 Clusters......Page 161
Summary......Page 164
Literature Cited......Page 166
8 Metal-Metal Bond Making and Breaking in Binuclear Complexes with Phosphine Bridging Ligands......Page 170
Metal-Metal Bond Formation and Rupture in Diphosphine Bridged Dinuclear Metal Complexes......Page 176
2-Diphenylphosphinopyridine, a Ligand for the Stepwise Construction of Binuclear Complexes......Page 179
Literature Cited......Page 187
Synthesis and Characterisation of Electron-Deficient Hydrido and Methyl Diplatinum Complexes......Page 189
Binuclear Reductive Elimination Reactions......Page 193
Catalysis of the Water Gas Shift Reaction......Page 196
Acknowledgments......Page 197
Literature Cited......Page 198
Diatomic Molecules of Transition Metal Elements.......Page 199
Binary metal carbonyl clusters......Page 202
Compounds containing multiple metal-to-metal bonds......Page 203
Literature cited......Page 206
11 Breaking Metal-Metal Multiple Bonds Their Use as Synthetic Starting Materials......Page 208
Cleavage Reactions by σ-Donors.......Page 211
Cleavage Reactions by π-Acceptor Ligands.......Page 213
Conclusions.......Page 218
Literature Cited......Page 219
12 The Novel Reactivity of the Molybdenum-Molybdenum Triple Bond in Cp2Mo2(CO)4......Page 222
General Reactivity Considerations......Page 223
Synthesis and Structure of Cp2M2(CO)4......Page 225
Nucleophilic Addition to ΜΞΜ Bonds......Page 228
Electrophilic Additions to ΜΞΜ Bonds......Page 244
Summary and Prognosis......Page 252
Acknowledgements......Page 254
Literature Cited......Page 255
DI-IRON AND DIRUTHENIUM METALLOCYCLES.......Page 259
DIMOLYBDENUM AND DITUNGSTEN METALLOCYCLES.......Page 267
LITERATURE CITED.......Page 270
14 The Coordination Chemistry of Metal Surfaces......Page 272
Experimental......Page 274
Discussion......Page 275
Acknowledgment......Page 294
Literature Cited......Page 295
15 New Approaches to the Chemistry of Di- and Trimetal Complexes Synthesis, Chemical Reactivity, and Structural Studies......Page 297
COMPOUNDS WITH BRIDGING ALKYLIDENE AND ALKYLIDYNE LIGANDS.......Page 298
REACTIONS OF LOW VALENT METAL COMPOUNDS WITH COMPLEXES CONTAINING METAL—METAL MULTIPLE BONDS.......Page 307
LITERATURE CITED.......Page 310
B......Page 312
C......Page 313
F......Page 316
I......Page 317
M......Page 318
P......Page 321
R......Page 322
V......Page 323
Z......Page 324
