Content: High temperature polymers from thermally curable oligomers / Paul M. Hergenrother --
Synthesis of bisphenol-based acetylene terminated thermosetting resins / J.S. Wallace, F.E. Arnold, and W.A. Feld --
Arylether sulfone oligomers with acetylene termination from the Ullman ether reaction / P.M. Lindley, L.G. Picklesimer, B. Evans, F.E. Arnold, and J.J. Kane --
Network structure in polymers from bisphthalonitriles / Jeffrey A. Hinkley --
Intermolecular and intramolecular reactions of substituted norbornenyl imides / Chaim N. Sukenik, Vinay Malhotra, and Uday Varde --
Thermally stable polymers for electronic applications / D.J. Dawson, W.W. Fleming, J.R. Lyerla, and J. Economy --
Ethynyl end-capped polyimide oligomers containing oxyethylene linkages : synthesis and characterization / Frank W. Harris and K. Sridhar --
Polyaromatics with terminal or pendant styrene groups : a new class of thermally reactive oligomers / Virgil Percec and Brian C. Auman --
N-cyanourea-terminated resins / S.C. Lin --
Chain extendable oligomers for high-solids coatings / J.W. Holubka --
New telechelic polymers and sequential copolymers by polyfunctional initiator-transfer agents (inifers) : end reactive polyisobutylenes by semicontinuous polymerization / Rudolf Faust, Agota Fehervari, and Joseph P. Kennedy --
Functionalization of polymeric organolithium compounds : synthesis of macromolecular ketones and telechelic amines / Roderic P. Quirk, Wei-Chih Chen, and Pao-Luo Cheng --
Free-radical ring-opening polymerization : use in synthesis of reactive oligomers / William J. Bailey, Benjamin Gapud, Yin-Nian Lin, Zhende Ni, and Shang-Ren Wu --
Reactive difunctional siloxane oligomers : synthesis and characterization / Iskender Yilgör, Judy S. Riffle, and James E. McGrath --
Synthesis of poly(phenylene oxides) by electrooxidative polymerization of phenols / Eishun Tsuchida, Hiroyuki Nishide, and Toshihiko Maekawa --
Coupling and capping reactions on poly(2,6-dimethyl-1,4-phenylene oxide) / Dwain M. White and George R. Loucks --
Characterization of hydroxyl-terminated liquid polymers of epichlorohydrin / Simon H. Yu --
Thermal and photo stability of polyarylates : styrylpyridine-based polymers / Hoh-Jiear Yan and Eli M. Pearce --
Glycol bis(allyl phthalates) as cocross-linkers for diallyl phthalate resins / Akira Matsumoto and Masayoshi Oiwa --
Special functional triglyceride oils as reactive oligomers for simultaneous interpenetrating networks / L.H. Sperling, J.A. Manson, and G.M. Jordhamo.
Author(s): Frank W. Harris and Harry J. Spinelli (Eds.)
Series: ACS Symposium Series 282
Publisher: American Chemical Society
Year: 1985
Language: English
Pages: 256
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 High Temperature Polymers from Thermally Curable Oligomers......Page 8
Results and Discussion......Page 9
Literature Cited......Page 21
2 Synthesis of Bisphenol-Based Acetylene Terminated Thermosetting Resins......Page 24
Synthesis of the End-Capping Agent 4-(m-Hydroxyphenyl)-2-methyl-3-butyn-2-ol I......Page 25
Example Procedure for Preparation of Halo-Terminated Intermediate Monomer/Oligomer Mixtures......Page 26
Monomer Product......Page 27
End-Capping Agent I......Page 28
AT-Monomer and AT-Monomer/Oligomer Systems......Page 32
Conclusions......Page 34
Literature Cited......Page 36
3 Arylether Sulfone Oligomers with Acetylene Termination from the Ullman Ether Reaction......Page 37
Results and Discussion......Page 39
Experimental......Page 46
Literature Cited......Page 48
Experimental......Page 49
Dynamic Mechanical Properties......Page 50
Network Structure......Page 52
Crosslink Density......Page 54
Literature Cited......Page 57
5 Intermolecular and Intramolecular Reactions of Substituted Norbornenyl Imides......Page 58
Substrate Synthesis and Characterization......Page 59
Monomer Isomerization......Page 60
Polymer Formation......Page 61
Polymer Structure......Page 64
Literature Cited......Page 66
6 Thermally Stable Polymers for Electronic Applications......Page 67
Experimental......Page 70
Discussion......Page 71
Conclusions......Page 76
Literature Cited......Page 83
7 Ethynyl End-Capped Polyimide Oligomers Containing Oxyethylene Linkages Synthesis and Characterization......Page 84
Results and Discussion......Page 85
Experimental......Page 91
Literature Cited......Page 93
8 Polyaromatics with Terminal or Pendant Styrene Groups A New Class of Thermally Reactive Oligomers......Page 94
Experimental......Page 95
Results and Discussion......Page 96
Literature Cited......Page 106
9 N-Cyanourea-Terminated Resins......Page 108
Experimental......Page 109
Results and Discussion......Page 110
Conclusion......Page 115
Literature Cited......Page 118
10 Chain Extendable Oligomers for High-Solids Coatings......Page 119
Experimental......Page 120
Results and Discussion......Page 121
Literature Cited......Page 125
11 New Telechelic Polymers and Sequential Copolymers by Polyfunctional Initiator-Transfer Agents (Inifers) End Reactive Polyisobutylenes by Semicontinuous Polymerization......Page 126
Experimental......Page 127
Results and Discussion......Page 128
Literature Cited......Page 138
12 Functionalization of Polymeric Organolithium Compounds Synthesis of Macromolecular Ketones and Telechelic Amines......Page 139
Results and Discussion......Page 140
Literature Cited......Page 145
13 Free-Radical Ring-Opening Polymerization Use in Synthesis of Reactive Oligomers......Page 147
Free Radical Ring-Opening Polymerization......Page 149
New Chain Transfer Agents from Ketene Acetals......Page 155
Literature Cited......Page 158
14 Reactive Difunctional Siloxane Oligomers Synthesis and Characterization......Page 160
Synthesis of α,ω-Aminopropyl Terminated Poly(dimethyl-diphenyl)-siloxane Oligomers......Page 164
Synthesis and Characterization of Hydroxybutyl Terminated Siloxane Oligomers......Page 165
Synthesis of Aminopropyl Terminated Poly(dimethyl-diphenyl)siloxane Oligomers......Page 168
Literature Cited......Page 172
15 Synthesis of Poly(phenylene Oxides) by Electrooxidative Polymerization of Phenols......Page 174
Electro-Oxidative Polymerization of 2,6-Disubstituted Phenols......Page 175
Mechanism of the Polymerization......Page 177
Electrochemical Features of the Polymerization......Page 179
Application of the Electro-Oxidative Polymerization......Page 181
Experimental......Page 182
Literature Cited......Page 184
16 Coupling and Capping Reactions on Poly(2,6-dimethyl-1,4-phenylene Oxide)......Page 185
Results and Discussion......Page 186
Experimental......Page 190
Literature Cited......Page 195
17 Characterization of Hydroxyl-Terminated Liquid Polymers of Epichlorohydrin......Page 196
Experimental......Page 197
Results and Discussion......Page 198
Literature Cited......Page 205
18 Thermal and Photo Stability of Polyarylates Styrylpyridine-Based Polymers......Page 206
A. Model Compounds......Page 208
Synthesis of Ester......Page 209
Polyarylates......Page 210
Synthesis of Polyesters......Page 213
Photo-Fries Rearrangement of Styrylpyridine Based Ester and Carbonate-UV-Spectroscopic Studies......Page 214
Conclusions......Page 218
Literature Cited......Page 219
19 Glycol Bis(allyl Phthalates) as Cocross-linkers for Diallyl Phthalate Resins......Page 221
Preparation and Polymerization of Glycol Bis(allyl phthalate)s......Page 222
Mechanical Properties of DAP Resins Cocrosslinked with Glycol Bis(allyl phthalate)s......Page 224
Mechanical Properties of DAP Resins Cocured Microheterogeneously with Vinyl Monomers Having Long-Chain Alkyl Groups......Page 228
Literature Cited......Page 230
20 Special Functional Triglyceride Oils as Reactive Oligomers for Simultaneous Interpenetrating Network......Page 232
Experimental......Page 234
Results......Page 236
Conclusions......Page 242
Literature Cited......Page 243
Author Index......Page 245
A......Page 246
C......Page 247
D......Page 248
E......Page 249
I......Page 250
M......Page 251
P......Page 252
S......Page 254
T......Page 255
Y......Page 256
