Polymer Characterization by ESR and NMR

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Content: Conformation and mobility of polymers adsorbed on oxide surfaces by ESR spectroscopy / Taiming Liang, Peter N. Dickenson, and Wilmer G. Miller --
An ESR investigation of environmental effects on nylon fibers / K.L. Devries and M. Igarashi --
An ESR study of initially formed intermediates in the photodegradation of poly(vinyl chloride) / N.-L. Yang, J. Liutkus, and H. Haubenstock --
Manganese(II) and gadolinium(III) EPR studies of membrane-bound ATPases / Charles M. Grisham --
Molecular structure of vinyl chloride-vinylidene chloride copolymers by carbon-13 NMR / Charles J. Carman --
Characterization of long-chain branching in polyethylenes using high-field carbon-13 NMR / J.C. Randall --
Molecular dynamics of polymer chains and alkyl groups in solution / George C. Levy, Peter L. Rinaldi, James J. Dechter, David E. Axelso, and Leo Mandelkern --
Use of pulsed NMR to study composite polymeric systems / D.C. Douglass --
Multiple-pulse NMR of solid polymers : dynamics of polytetrafluoroethylene / A.D. English and A.J. Vega --
Variable-temperature magic-angle spinning carbon-13 NMR studies of solid polymers / W.W. Fleming, C.A. Fyfe, R.D. Kendrick, J.R. Lyerla, H. Vanni, and C.S. Yannoni --
Drug-DNA interactions in solution : acridine mutagen, anthracycline antitumor, and peptide antibiotic complexes / Dinshaw J. Patel.

Author(s): Arthur E. Woodward and Frank A. Bovey (Eds.)
Series: ACS Symposium Series 142
Publisher: American Chemical Society
Year: 1980

Language: English
Pages: 311
City: Washington, D.C

Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
Basis of Method......Page 9
Experimental......Page 10
Conformation and Mobility at the Solid-Liquid Interface......Page 14
Effect of the Surface on Segmental Mobility in the Dry State......Page 19
Literature Cited......Page 25
Experimental Procedures......Page 27
Results......Page 28
Discussion and Conclusions......Page 40
Literature Cited......Page 41
3 An ESR Study of Initially Formed Intermediates in the Photodegradation of Poly(vinyl chloride)......Page 43
Sample Preparation......Page 44
ESR Spectra......Page 45
Discussion......Page 46
Conclusion......Page 54
Literature Cited......Page 55
4 Manganese(II) and Gadolinium(III) EPR Studies of Membrane-Bound ATPases......Page 57
Theoretical Basis for Mn(II) and Gd(III) EPR Studies of Membrane Enzymes......Page 58
Mn(II) EPR Studies of Sheep Kidney (Na+ + K+)-ATPase and Mg2+-ATPase......Page 60
Gd(lII) as a Probe in NMR and EPR Studies of Sarcoplasmic Reticulum Ca2+-ATPase......Page 72
Summary......Page 82
Abstract......Page 85
Literature Cited......Page 86
Results and Discussion......Page 89
Abstract......Page 98
Literature Cited......Page 99
6 Characterization of Long-Chain Branching in Polyethylenes Using High-Field Carbon-13 NMR......Page 100
REFERENCES......Page 124
7 Molecular Dynamics of Polymer Chains and Alkyl Groups in Solution......Page 126
Experimental......Page 127
Results and Discussion......Page 128
Acknowledgements......Page 150
Literature Cited......Page 151
8 Use of Pulsed NMR to Study Composite Polymeric Systems......Page 153
Literature Cited......Page 173
Results......Page 175
Discussion......Page 186
References......Page 196
Background to Magic Angle Spinning for 13C NMR in Solids......Page 198
Spinning Apparatus......Page 201
Spectrometer......Page 206
Results and Discussion......Page 207
Acknowledgments......Page 219
References and Notes......Page 220
11 Drug-DNA Interactions in Solution: Acridine Mutagen, Anthracycline Antitumor, and Peptide Antibiotic Complexes......Page 223
Synthetic DNA. Alternating Adenosine-Uridine Sequences......Page 224
Counterion Binding. Alkylammonium Ions......Page 239
Proflavine-DNA Complexes......Page 245
Daunomycin-DNA Complexes......Page 260
Netropsin-DNA Complexes......Page 277
Conclusion......Page 291
References......Page 294
B......Page 299
C......Page 300
D......Page 301
E......Page 302
H......Page 303
M......Page 304
N......Page 305
P......Page 306
R......Page 309
V......Page 310
Z......Page 311