Content: Resonant electron scattering and anion states in polyatomic molecules / Kenneth D. Jordan and Paul D. Burrow -- Negative ion states of polyatomic molecules / L.G. Christophorou -- Electronic states and excitations in polymers / John J. Ritsko -- Exciton states and exciton transport in molecular crystals / R. Silbey and R. Munn -- Percolation of molecular excitons / Raoul Kopelman -- Localization of electronic states in polymers and molecular solids / C.B. Duke -- Electronic structure of some simple polymers and of highly conducting and biopolymers / J. Ladik, S. Suhai, and M. Seel -- Spectroscopic studies of polydiacetylenes / D. Bloor -- Bond length alternation and forbidden energy gap in conjugated periodic polymers / M. Kertesz, J. Koller, and A. Azman -- Models of radical cation states in molecules, molecular solids, and polymers / C.B. Duke -- Intermolecular relaxation effects in the ultraviolet photoelectron spectroscopy of molecular solids : molecular-ion states in aromatic pendant group polymers / W.R. Salaneck -- Band structure calculations and their relations to photoelectron spectroscopy / Jean-Marie AndreĢ, Joseph Delhalle, and Jean Jacques Pireaux -- Electronic structure of polymers : X-ray photoelectron valence band spectra / J.J. Pireaux, J. Riga, R. Caudano, and J. Verbist -- Identification of chemical states by spectral features in X-ray photoelectron spectroscopy / C.D. Wagner -- Chemical labels to distinguish surface functional groups using X-ray photoelectron spectroscopy (ESCA) / C.D. Batich and R.C. Wendt -- Interactions of ion beams with organic surfaces studied by XPS, UPS, and SIMS / J. Wayne Rabalais -- The modification, degradation, and synthesis of polymer surfaces studied by ESCA / D.T. Clark -- X-ray photoelectron spectroscopy for the investigation of polymer surfaces / A. Dilks -- Surface studies on multicomponent polymer systems by X-ray photoelectron spectroscopy / H.R. Thomas and J.J. O'Malley -- Metal-polymer interfaces : studies with X-ray photoemission / J.M. Burkstrand -- Surface characterization of plasma-fluorinated polymers / M. Anand, R.E. Cohen, and R.F. Baddour -- ESCA and SEM studies on polyurethanes for biomedical applications / B.D. Ratner -- Surface analysis of silicon : alloyed and unalloyed LTI pyrolytic carbon / R.N. King, J.D. Andrade, A.D. Haubold, and H.S. Shim -- Oxidation of polystyrene and pyrolytic carbon surfaces by radiofrequency glow discharge / G.K. Iwamoto, R.N. King, and J.D. Andrade -- ESCA studies of polyimide and modified polyimide surfaces / H.J. Leary, Jr. and D.S. Campbell
Author(s): David W. Dwight, Thomas J. Fabish, and H. Ronald Thomas (Eds.)
Series: ACS Symposium Series 162
Publisher: American Chemical Society
Year: 1981
Language: English
Pages: 439
City: Washington, D.C
Title Page
......Page 1
Half Title Page
......Page 3
Copyright
......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Resonant Electron Scattering and Anion States in Polyatomic Molecules......Page 10
Use Of ETS To Study Substituent Effects......Page 11
Comparison Of Spectra Of Gas Phase And Condensed Phase Anions......Page 12
Conclusions and Discussion......Page 14
Literature Cited......Page 17
2 Negative Ion States of Polyatomic Molecules1......Page 20
Nonaromatic Double-Bonded Structures......Page 21
Benzene and Derivatives......Page 30
Selected Halocarbons......Page 36
Literature Cited......Page 40
3 Electronic States and Excitations in Polymers......Page 44
Literature Cited......Page 52
4 Exciton States and Exciton Transport in Molecular Crystals......Page 54
Principles......Page 55
Untransformed Coupling......Page 56
Transformed Coupling......Page 58
Diffusion Constant......Page 59
Discussion......Page 60
Literature Cited......Page 63
Band Theory, Localization and Percolation......Page 66
Excitation Percolation......Page 67
Scaling Experiments......Page 69
Epilogue......Page 71
Abstract......Page 72
Literature Cited......Page 73
6 Localization of Electronic States in Polymers and Molecular Solids......Page 74
Relaxation and Fluctuations......Page 75
Localization......Page 76
Contact Charge Exchange......Page 78
Literature Cited......Page 79
Method......Page 82
Polyacetylenes and Polydiacetylenes......Page 83
Concluding Remarks......Page 87
Literature Cited......Page 88
8 Spectroscopic Studies of Polydiacetylenes......Page 90
Optical Spectroscopy......Page 93
Electron Spin Resonance Spectroscopy......Page 100
Acknowledgements......Page 107
Literature Cited......Page 108
The Nuclear Distortion Problem......Page 114
Forces Acting On The Nuclei......Page 115
The Blue Shift In Polydiacetylenes:......Page 116
Abstract......Page 118
Literature Cited......Page 119
10 Models of Radical Cation States in Molecules, Molecular Solids, and Polymers......Page 121
CNDO/S3 Model......Page 122
Relaxation In Isolated Molecules......Page 123
Relaxation In Condensed Media......Page 124
Literature Cited......Page 125
Historical Background......Page 128
Photoelectron Spectra of Molecular Solids: Basic Issues......Page 129
Some Technical Aspects of the UPS of Insulating Solids......Page 133
Examples of Contributions of Intermolecular Relaxation Effects to UPS Spectra of Molecular Solids......Page 134
Appendix: Sample Preparation and some other Experimental Details Relevant to the Study of Polystyrene and Poly(2-Vinyl Pyridine)......Page 151
Literature Cited......Page 152
Methods For The Determination of One-Electron Bands......Page 157
Relations Between One-Electron Bands And PS Spectra......Page 161
Comparisons Between Theoretical and Experimental XPS Valence Spectra......Page 163
Abstract......Page 171
Literature Cited......Page 172
13 Electronic Structure of Polymers X-Ray Photoelectron Valence Band Spectra......Page 175
Experiment......Page 176
Substitution Effects in the Valence Bands......Page 182
Isomerism......Page 194
Other Informations Available from the Valence Band Spectra......Page 202
Acknowledgements......Page 203
Literature Cited......Page 204
14 Identification of Chemical States by Spectral Features in X-Ray Photoelectron Spectroscopy......Page 208
Abstract......Page 218
Literature Cited......Page 222
15 Chemical Labels to Distinguish Surface Functional Groups Using X-Ray Photoelectron Spectroscopy(ESCA)......Page 225
Primary......Page 228
Carboxylic Acid Group Model System......Page 229
Literature Cited......Page 239
16 Interactions of Ion Beams with Organic Surfaces Studied by XPS, UPS, and SIMS......Page 240
Abstract......Page 248
Literature Cited......Page 249
17 The Modification, Degradation, and Synthesis of Polymer Surfaces Studied by ESCA......Page 250
Migration Phenomena (9)......Page 258
The Plasma Synthesis Of Ultra Thin Fluoropolymer Films......Page 262
An ESCA Investigation Of The Surface Chemistry Of The Nitration And Denitration Of Cellulose Materials......Page 272
Literature Cited......Page 292
Absolute and Relative Signal Intensities......Page 295
Absolute and Relative Binding Energies......Page 304
Conclusion......Page 317
Literature Cited......Page 318
EXPERIMENTAL......Page 320
A) Regular Block Copolymers.......Page 322
B) Random Block Copolymers......Page 332
PEO/PS Layers......Page 334
Conclusions......Page 336
Literature Cited......Page 338
20 Metal-Polymer Interfaces: Studies with X-Ray Photoemission......Page 340
Results......Page 341
Discussion......Page 345
Literature Cited......Page 350
21 Surface Characterization of Plasma-Fluorinated Polymers......Page 353
Results and Discussion......Page 354
Fluorination of Other Polymers......Page 361
Treatment Of Polymer Powders......Page 363
Abstract......Page 368
Literature Cited......Page 369
22 ESCA and SEM Studies on Polyurethanes for Biomedical Applications......Page 371
Results and Discussion......Page 372
Acknowledgement......Page 381
Literature Cited......Page 382
23 Surface Analysis of Silicon: Alloyed and Unalloyed LTI Pyrolytic Carbon......Page 383
Background......Page 384
Materials and Methods......Page 385
Results and Discussion......Page 388
Abstract......Page 402
Literature Cited......Page 403
24 Oxidation of Polystyrene and Pyrolytic Carbon Surfaces by Radiofrequency Glow Discharge......Page 405
Experimental......Page 407
Results and Discussion......Page 411
Abstract......Page 416
Literature Cited......Page 417
25 ESCA Studies of Polyimide and Modified Polyimide Surfaces......Page 419
Experimental......Page 420
Results and Discussion......Page 421
Literature Cited......Page 432
C
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F
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N
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P
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S
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X
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