Content: Phosphorus-carbon compounds with p[pi]-p[pi] bonds / R. Appel --
Selective bond formation of organophosphorus acids with functional groups of biological importance / L. Horner, R. Gehring, and H.-W. Flemming --
Chemical synthesis and biological properties of the 5'-terminus of eukaryotic messenger ribonucleic acids (mRNA) / Tsujiaki Hata, Mitsuo Sekine, Iwao Nakagawa, Kazuo Yamaguchi, Shinkichi Honda, Takashi Kamimura, Kazuko Yamaguchi, and Kin-Ichiro Miura --
Triphenylphosphane-diethylazodicarboxylate : a useful system for directed structural variation of carbohydrates / E. Zbiral, H.H. Brandstetter, and E. Mark --
Synthetic application of element organic substituted phosphorus ylides / H.J. Bestmann --
Mono-, di-, and multi-ylides in organometallic chemistry / Hubert Schmidbaur --
Synthetic and spectroscopic investigations involving [alpha]-heterosubstituted phosphonate carbanions / Hans Zimmer --
A new approach to activation of hydroxy compounds using pentacoordinated spirophosphoranes / J.I.G. Cadogan, I. Gosney, D. Randles, and S. Yaslak --
Synthetic applications of [alpha]-amino substituted phosphine oxides / A. Van Der Gen and N.L.J.M. Broekhof --
Reactions of aziridines, 4-oxazolines, and their derivatives with alkylidene phosphoranes and phosphorus(III) nucleophiles / M. Vaultier and R. Carrié --
Phosphonates containing sulfur and selenium : synthesis, reactions, and new applications / M. Mikołajczyk, S. Grzejszczak, W. Midura, M. Popielarczyk, and J. Omelańczuk --
Umpolung of [alpha], [beta]-ethylenic ketones and aldehydes by phosphorus groups / H.J. Cristau, J.P. Vors, Y. Beziat, C. Niangoran, and H. Christol --
Monomeric metaphosphates in enzymic and in enzyme-model systems / F.H. Westheimer --
Stereoelectronic effects in phosphate esters / D.G. Gorenstein, R. Rowell, and K. Taira --
Stereospecific synthesis and assignment of absolute configuration at phosphorus in nucleoside 3'- and 5'-O-arylphosphorothioates and nucleoside cyclic 3',5'-phosphorothioates / J. Baraniak, Z.J. Leśnikowski, W. Niewiarowski, W.S. Zieliński, and W.J. Stec --
The stereochemistry of chiral cyclic phosphorus esters : do theories of bond-forming and bond-breaking processes fit the facts? / Thomas D. Inch and C. Richard Hall --
The stereochemical course of the alkaline hydrolysis of 1,3,2-oxazaphospholidine-2-thiones / C. Richard Hall and Thomas D. Inch --
Hydrolysis of adenosine 5'-triphosphate : an isotope-labeling study / Seymour Meyerson, Eugene S. Kuhn, Fausto Ramirez, and James F. Marecek --
Nucleoside phosphorothioates for the study of enzyme mechanisms / F. Eckstein --
Chiral [¹⁶O, ¹⁷O, ¹⁸O] phosphate monoesters for determining the stereochemical course of phosphokinases / Gordon Lowe, Paul M. Cullis, Richard L. Jarvest, and Barry V.L. Potter --
Syntheses and configurational assignments of thymidine 3'- and 5'-(4-nitrophenyl [¹⁷O, ¹⁸O] phosphates) / Shujaath Mehdi, Jeffrey A. Coderre, and John A. Gerlt --
The mechanism of aldehyde-induced ATPase activities of kinases / W.W. Cleland and Alan R. Rendina --
Kinetic and thermodynamic studies of yeast inorganic pyrophosphatase / Barry S. Cooperman --
The role of histidine residues and the conformation of bound ATP on ATP-utilizing enzymes / P.R. Rosevear, G.M. Smith, S. Meshitsuka, A.S. Mildvan, P. Desmeules, and G.L. Kenyon --
[¹⁸O/[¹⁶O]³¹P-NMR studies of phosphoryl transfer enzymes / J.J. Villafranca, F.M. Raushel, R.P. Pillai, M.S. Balakrishnan, C. Debrosse, and T.D. Meek --
Potential antiviral nucleotides / D.W. Hutchinson --
Phosphinomethanes : synthesis and reactivity / H.H. Karsch --
Preparation and synthetic reactions of [alpha]- alkoxyallyl phosphorus ylides / M. Maleki, J.A. Miller, and O.W. Lever, Jr. --
[Alpha]-phosphorylated carbanions : synthetic features / G. Sturtz, B. Corbel, M. Baboulène, and J.J. Yaouanc --
A new synthesis of indoles / M. Le Corre, A. Hercouet, and H. Le Baron --
Alkylation by way of monomeric and polymeric alkoxyphosphonium salts / Donald W. Hamp and Edward S. Lewis --
Some preparative and mechanistic aspects of the chemistry of phosphoric acid and thiophosphoric acid chloride betaines / M. Meisel, C. Donath, and H. Grunze --
"Activated" phosphoranes for the cyclodehydration and chlorination of simple diols / S. Woody Bass, Carey N. Barry, Philip L. Robinson, and Slayton A. Evans, Jr. --
N-alkylation of organophosphorus amides : a new, convenient route to primary and secondary amines / A. Zwierzak --
Phosphoric amide reagents / Erik B. Pedersen --
Reversible masking of acetylcholinesterase by covalent phosphorylation in the presence of a novel cyclic phosphate ester / H. Leader, L. Raveh, R. Brukstein, M. Spiegelstein, and Y. Ashani --
[Alpha]-aminophosphonous acids: a new class of biologically active amino acid analogs / E.K. Baylis, C.D. Campbell, J.G. Dingwall, and W. Pickles --
Phosphonodipeptides / Lidia Kupczyk-Subotkowska, Pawel Kafarski, Janusz Kowalik, Barbara Lejczak, Przemyslaw Mastalerz, Józef Oleksyszyn, and Jerzy Szewczyk --
Some aspects of the chemical synthesis of oligodeoxyribonucleotides / Colin B. Reese and Lydia Valente --
Coupling of fatty diazomethylketones with organophosphorus acids : an approach to glycerophospholipid analog synthesis / David A. Marsh and Joseph G. Turcotte --
Design of organophosphorus reagents for peptide synthesis / R. Ramage, B. Atrash, and M.J. Parrott --
The nature of the energy transduction links in mitochondrial oxidative phosphorylation / Fausto Ramirez, Shu-I Tu, Prabha R. Chatterji, Hiroshi Okazaki, James F. Marecek, and Brian McKeever --
ADP hydrolysis promoted by cobalt(III) / Markus Hediger and Ronald M. Milburn --
PMR measurements of chair-twist conformational equilibria for diastereomeric P-derivatives of thymidine cyclic 3',5'-monophosphate : possible implications for naturally occurring cyclic nucleotides / Alan E. Sopchik, Gurdip S. Bajwa, Keith A. Nelson, and Wesley G. Bentrude --
Phosphonate inhibitors of carboxypeptidase A / Neil E. Jacobsen and Paul A. Bartlett --
"Illicit transport" systems for organophosphorus antimetabolites / Maqsood Sheikh, Barry Gotlinsky, Burton E. Tropp, Robert Engel, and Thomas Parker --
The preparation of phosphorus esters and thioesters from white phosphorus / Charles Brown, Robert F. Hudson, Gary A. Wartew, and Harold Coates --
Thermal rearrangement and condensation of O, O-dimethyl-O-phenylphosphorothionate / Herbert Teichmann and Gerhard Schramm --
Synthesis and reactivity of (silylamino)phosphines / Robert H. Neilson, Patty Wisian-Neilson, David W. Morton, and H. Randy O'Neal --
Addition of lithium dialkylcuprates to [alpha], [beta]-unsaturated phosphoryl compounds : nucleophilic properties of adducts / R. Bodalski, T. Michalski, J. Monkiewicz, and K.M. Pietrusiewicz --
Phosphorylated ketenes / O.I. Kolodyazhnyi, V.I. Yakovlev, and V.P. Kukhar --
Preparation and properties of N-(Hydroxycarbonylmethyl)aminomethyl alkyl- and arylphosphinic acids and derivatives / Ludwig Maier --
Some aspects of aminoalkylphosphonic acids synthesis by the reductive amination approach / P. Savignac and N. Collignon --
Recent results on open-chain and cyclic phosphanes and organylphosphanes / Marianne Baudler --
Formation of phosphorus oxoacids with P-P-P-P-P-P and P-P-P-P-P frameworks and related compounds / Toshio Nakashima, Hirohiko Waki, and Shigeru Ohashi --
NMR characterization of homologous cyclic phosphoramides / Jack E. Richman, Robert B. Flay, and O.D. Gupta --
Synthesis and chemical behavior of some bicyclophosphanes / C. Bonningue, O. Diallo, D. Houalla, A. Klaebe, and R. Wolf --
Reactions of 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide / Sven-Olov Lawesson --
Small rings with tervalent phosphorus / Ekkehard Fluck and Horst Richter --
The unexpected formation of 1,2-oxaphosphol-3-ene 2-oxides in the reaction of diacetone alcohol with phosphonous dihalides / Kurt Moedritzer and Raymond E. Miller --
Dihydrophenophosphazines via the interaction of diarylamines and phosphorus trichloride : applications and limitations / Harold S. Freeman and Leon D. Freedman --
Contributions to the chemistry of N-phosphoryl phosphazenes / L. Riesel, E. Herrmann, A. Pfützner, J. Steinbach, and B. Thomas --
Conjugation in phosphazenes: pyrrylphosphazenes and phosphazenyl carbanions / K.D. Gallicano, R.T. Oakley, R.D. Sharma, and N.L. Paddock --
Structure, conformation, and basicity in cyclophosphazenes and related compounds / R.A. Shaw and S.N. Nabi --
Phosphazene rings and high polymers linked to transition metals or biologically active organic species / H.R. Allcock --
Polymerization of hexachlorocyclotriphosphazene / John W. Fieldhouse and Daniel F. Graves --
Alkenylfluorocyclotriphosphazenes / Christopher W. Allen, Randall P. Bright, and Kolikkara Ramachandran --
The reactions of halophosphazenes with organometallic reagents / Paul J. Harris and Harry R. Allcock --
1,2-bis(dichlorophosphino)alkanes / E.H. Uhing and A.D.F. Toy --
Products of peracid oxidation of S-alkyl phosphorothiolate pesticides / Yoffi Segall and John E. Casida --
Research on organophosphorus insecticides, synthesis of O-alkyl O-substituted phenyl alkylphosphonothioates / Wu Kiun-Houo, Sun Yung-Min, and Wang Sing-Min --
Introduction of phosphorus into the polyethyleneterephthalate molecule / G. Borisov, K. Troev, and A. Grozeva --
Selected novel trivalent organophosphorus processing stabilizers for polyolefins / J.D. Spivack, A. Patel, and L.P. Steinhuebel --
Oligomeric phosphorus esters with flame retardant utility / Edward D. Weil, Ralph B. Fearing, and Fred Jaffe. Crystalline calcium polyphosphate fibers / E.J. Griffith --
Fluorination of phosphoapatites : possible alterations of their structure / G. Montel, G. Bonel, J.C. Heughebaert, M. Vignoles, M. Hamad, and G. Bacquet --
Photo- and thermo-coloring of reduced phosphate glasses / Y. Abe, R. Ebisawa, D.E. Clark, and L.L. Hench --
A gel chromatographic study on the interactions of long-chain polyphosphate anions with magnesium ions / Tohru Miyajima, Toshimitsu Onaka, and Shigeru Ohashi --
Phosphaalkenes, R₂C=PR', and phosphaalkynes, RC:::P / H.W. Kroto and J.F. Nixon --
Recent developments in the chemistry of dicoordinated phosphorus radicals and cations / S.G. Baxter, A.H. Cowley, R.A. Kemp, S.K. Mehrotra, and J.C. Wilburn --
³¹P NMR investigations on dicoordinated phosphorus compounds in P(II) = C-P(III) systems / R. Appel, V. Barth, H. Kunze, B. Laubach, V. Paulen, and F. Knoll --
Synthesis and properties of phosphaalkenes / T.A. Van Der Knaap, T.C. Klebach, F. Visser, R. Lourens, and F. Bickelhaupt --
Routes to dicoordinated phosphorus compounds / K. Issleib, H. Oehme, H. Schmidt, and G.-R. Vollmer --
Reactions of 2,4,6-tri(t-butyl)phenyllithium with phosphorus halides / Masaaki Yoshifuji, Ichiro Shima, and Naoki Inamoto --
Synthesis of new dicoordinated phosphorus compounds with a P(III)=N bond / C. Malavaud, L. Lopez, T. N'gando M'pondo, M.T. Boisdon, Y. Charbonnel, and J. Barrans --Cyano anions of dicoordinated, tricoordinated, tetracoordinated, pentacoordinated, and hexacoordinated phosphorus / Alfred Schmidpeter, Franz Zwaschka, and William S. Sheldrick --
Preparation, reactions, and structures of some N, N'-dimethylurea-bridged phosphorus compounds / Norbert Weferling and Reinhard Schmutzler --
A stable monocyclic triarylalkoxyhydridophosphorane / A 10-P-5 species with an apical P-H bond --
Michael R. Ross and J.C. Martin --
Monocyclic phosphoranide and phosphoranoxide anions : P(V) oxyphosphorane carbanion --
P(IV) ylide alkoxide tautomerism / Itshak Granoth, Rivka Alkabets, Ezra Shirin, Yair Margalit, and Peter Bell --
Selectivity in reactions of tricyclic phosphatranes / D. Van Aken, I.I. Merkelbach, J.H.H. Hamerlinck, P. Schipper, and H.M. Buck --
The perfluoropinacolyl group : a stabilizing substituent for unusual phosphites and phosphoranes / Gerd-Volker Röschenthaler, Rainer Bohlen, and Werner Storzer --
Tartaric acid in phosphorus chemistry : phosphor emetics and oligomers / A. Munoz, L. Lamandé, M. Koenig, and R. Wolf --
Nucleophilic substitution at pentacoordinated phosphorus : addition-elimination mechanism / A. Skowrońska, J. Stanek-Gwara, and M. Nowakowski --
Metal chelates of aminoalkylphosphonic acids : stabilities, properties, and reactions / Arthur E. Martell --
Transition VIB metal [pi]-complexes of [lambda]³- and [lambda]⁵-phosphorins and some of their reactions / K. Dimroth --
Synthesis of transition metal phosphoranides : conversion of bicyclic phosphoranes into phosphoranides and phosphane adducts with transition metal derivatives / J.G. Riess, F. Jeanneaux, P. Vierling, J. Wachter, and A. Grand --
Secondary phosphino macrocyclic ligands / Evan P. Kyba and Heinz H. Heumüller --
Dicoordinated and tricoordinated acyclic phosphazenes as complex ligands / O.J. Scherer, H. Jungmann, and R. Konrad --
Metal complexes of amino(cyclophosphazenes) / V. Chandrasekhar, S.S. Krishnamurthy, and M. Woods --
Structural and magnetic investigation on transition metal complexes with tripodal polytertiary phosphines / L. Sacconi --
The use of alkylaminobis(difluorophosphines) as ligands to stabilize novel binuclear complexes / J.H. Kim, K.S. Raghuveer, T.W. Lee, L. Norskov-Lauritzen, V. Kumar, M.G. Newton, and R.B. King --
New aspects of the coordination chemistry of carbonyl phosphines / Edith F. Landvatter and Thomas B. Rauchfuss --
New chiral aminophosphine ligands : application to catalytic asymmetric C-C bond formation / Gérard Buono, Christian Triantaphylides, Gilbert Peiffer, André Mortreux, and Francis Petit --
31P NMR studies of catalytic intermediates in triphenylphosphine rhodium complex hydroformylation systems / Alexis A. Oswald, Joseph S. Merola, Edmund J. Mozeleski, Rodney V. Kastrup, and John C. Reisch --
New data on the mechanism of the Perkow-Arbuzov reaction / László Tőke, Imre Petneházy, Győngyi Szakál, Harry R. Hudson, Luba Powroznyk, and Christopher J. Cooksey --
Structure and reactivity of quasiphosphonium intermediates / H.R. Hudson, A.T.C. Kow, and K. Henrick --
Reactions of triorganosilyl halides with esters of tricoordinated and tetracoordinated phosphorus / J. Chojnowski, M. Cypryk, J. Michalski, and L. Wozniak --
Halogenolysis of the phosphorus-sulfur bond in thioloesters of organic phosphorus thioacids / B. Krawiecka, J. Michalski, and E. Tadeusiak --
Isotope effects in amination reactions of chlorocyclophosphazenes / J.M.E. Goldschmidt, R. Halevi, and E. Licht --
Zwitterionic [sigma]-complexes : their role as intermediates in phosphorylation of aromatics by phosphorus compounds / Y. Gololobov and P. Onys'ko --
Use of X-ray structural results on phosphorus compounds in modeling reaction mechanisms / Robert R. Holmes, Judith C. Gallucci, and Joan A. Deiters --
Ligand effects on the reaction of alkoxide ions with organophosphorus derivatives containing multiple leaving groups / Kenneth E. Debruin, Charles E. Ebersole, Morgan M. Hughes, and David M. Johnson --
Methanolysis of a phosphate ester / William S. Wadsworth, Jr. --
Reactivity of tricoordinated phosphorus compounds : a mechanistic study with a variety of substrates / C. Dennis Hall, Robert C. Edwards, John R. Lloyd, Paul D. Beer, Philip J. Hammond, Alberto O. D'amorim, and Melvin P. Melrose --
A new stereospecific synthesis of a P(III) organophosphorus ester / Leonard J. Szafraniec, Linda L. Szafraniec, and Herbert S. Aaron --
A single crystal X-ray diffraction analysis of (1R,1'S)-1,1'-ethylenebis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) diperchlorate / Narayanasamy Gurusamy, K. Darrell Berlin, Dick Van Der Helm, and M. Bilayet Hossain --
Stereochemical investigation of chiral onium hexaarylphosphates / G.P. Schiemenz and J. Pistor --
Spectroscopy of phosphorus compounds : d[pi]-p[pi] bonding effects on the 31P NMR chemical shifts of N-aryliminophosphoranes / Philip C. Murphy and John C. Tebby --
¹H, ¹⁹F, ³¹P, and ¹³C NMR investigation of diphosphanes and triphosphanes / J.P. Albrand and C. Taïeb --
Principal ³¹P chemical shift tensor components as determined by solid state NMR / J.P. Dutasta, J.B. Robert, and L. Wiesenfeld --
Application of the ¹⁸O shift on the ³¹P NMR spectrum to the elucidation of biochemical phosphate transfer mechanisms / Frank Jordan, Salvatore J. Salamone, and Alice L. Wang --
Phospholipase A2 hydrolysis of phospholipids : use of ³¹P NMR to study the hydrolysis, acyl migration, regiospecific synthesis, and solubilization of phospholipids / Andreas Plũckthun and Edward A. Dennis --
Photolytic rearrangement of phosphorus, germanium, and silicon azides : evidence for new hybridized species / J.P. Majoral, G. Bertrand, A. Baceiredo, and P. Mazerolles --
Diphenylphosphinous acid by UV irradiation of aroyl diphenyl phosphines / K. Praefcke and M. Dankowski --
Chemical model showing three phenomena : phosphorane [yields] ylide, ylide [yields] phosphorane, and phosphorane [equilibrium] ylide / Ramon Burgada, Yves Leroux, and Y.O. El Khoshnieh --
Base-catalyzed reactions of phosphonomethylphosphinates, bis(phosphonomethyl)phosphinates, and bis(phosphonomethyl)phosphinic amides with aldehydes / W. Franklin Gilmore and Joon Sup Park --
Structure-reactivity studies on oxygen-containing phosphorus-based ligands / Yuan Chengye, Ye Weizhen, Zhou Chengming, and Hui Yongzheng --
Phosphoric and carboxylic amides : comparison of bonding and reactivity / Tomasz A. Modro.
Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
1 Phosphorus-Carbon Compounds with pπ-pπ Bonds Opening Lecture......Page 7
2 Selective Bond Formation of Organophosphorus Acids with Functional Groups of Biological Importance......Page 16
3 Chemical Synthesis and Biological Properties of the 5'-Terminus of Eukaryotic Messenger Ribonucleic Acids (mRNA)......Page 19
4 Triphenylphosphane-diethylazodicarboxylate: A Useful System for Directed Structural Variation of Carbohydrates......Page 22
Literature cited......Page 25
5 Synthetic Application of Element OrganicSubstituted Phosphorus Ylides......Page 26
Literature cited:......Page 29
6 Mono-, Di-, and Multi-Ylides in Organometallic Chemistry......Page 30
7 Synthetic and Spectroscopic Investigations Involving α-Heterosubstituted Phosphonate Carbanions......Page 38
Literature Cited......Page 41
8 A New Approach to Activation of Hydroxy Compounds Using Pentacoordinated Spirophosphoranes......Page 42
Literature Cited......Page 47
9 Synthetic Applications of α-Amino Substituted Phosphine Oxides......Page 48
REFERENCES......Page 51
10 Reactions of Aziridines, 4-Oxazolines, and Their Derivatives with Alkylidene Phosphoranes and Phosphorus(III) Nucleophiles......Page 52
References......Page 55
11 Phosphonates Containing Sulfur and Selenium: Synthesis, Reactions, and New Applications......Page 56
Literature Cited......Page 59
12 Umpolung of α,β-Ethylenic Ketones and Aldehydes by Phosphorus Groups......Page 60
Literature Cited.......Page 63
13 Monomeric Metaphosphates in Enzymic and in Enzyme-Model Systems......Page 64
Enzymology......Page 65
Literature Cited......Page 67
14 Stereoelectronic Effects in Phosphate Esters......Page 68
LITERATURE CITED......Page 74
15 Stereospecific Synthesis and Assignment of Absolute Configuration at Phosphorus in Nucleoside 3'- and 5'-O-Arylphosphorothioates and Nucleoside Cyclic 3',5'-Phosphorothioates......Page 75
Literature Cited......Page 79
16 The Stereochemistry of Chiral Cyclic Phosphorus Esters Do Theories of Bond-Forming and Bond-Breaking Processes Fit the Facts?......Page 80
Literature Cited......Page 84
17 The Stereochemical Course of the Alkaline Hydrolysis of 1,3,2-Oxazaphospholidine-2-thiones......Page 85
Literature Cited......Page 88
18 Hydrolysis of Adenosine 5'-Triphosphate An Isotope-Labeling Study......Page 89
Literature Cited......Page 93
19 Nucleoside Phosphorothioates for the Study of Enzyme Mechanisms......Page 94
Myosin ATPase......Page 95
Literature Cited......Page 96
20 Chiral [16O, 17O, 18O] Phosphate Monoesters for Determining the Stereochemical Course of Phosphokinases......Page 97
Literature Cited......Page 101
21 Syntheses and Configurational Assignments of Thymidine 3'- and 5'-(4-Nitrophenyl [17O, 18O] Phosphates)......Page 102
Acknowledgements......Page 106
Literature Cited......Page 107
22 The Mechanism of Aldehyde-Induced ATPase Activities of Kinases......Page 108
Literated Cited......Page 111
Binding Studies......Page 112
Kinetic and Thermodynamic Studies......Page 114
Literature Cited......Page 117
24 The Role of Histidine Residues and the Conformation of Bound ATP on ATP-Utilizing Enzymes......Page 118
Literature Cited......Page 123
25 [18O/16O]31P-NMR Studies of Phosphoryl Transfer Enzymes......Page 124
Literature Cited......Page 126
26 Potential Antiviral Nucleotides......Page 128
Literature Cited......Page 131
27 Phosphinomethanes: Synthesis and Reactivity......Page 132
28 Preparation and Synthetic Reactions of α- Alkoxyallyl Phosphorus Ylides......Page 136
LITERATURE CITED......Page 139
29 α-Phosphorylated Carbanions: Synthetic Features......Page 140
LITERATURE CITED......Page 143
30 A New Synthesis of Indoles......Page 144
31 Alkylation by Way of Monomeric and Polymeric Alkoxyphosphonium Salts......Page 147
Literature Cited......Page 150
32 Some Preparative and Mechanistic Aspects of the Chemistry of Phosphoric Acid and Thiophosphoric Acid Chloride Betaines......Page 151
Literature Cited......Page 154
33 "Activated" Phosphoranes for the Cyclodehydration and Chlorination of Simple Diols......Page 155
Literature Cited......Page 158
34 N-Alkylation of Organophosphorus Amides A New, Convenient Route to Primary and Secondary Amines......Page 159
LITERATURE CITED......Page 162
35 Phosphoric Amide Reagents......Page 163
36 Reversible Masking of Acetylcholinesterase by Covalent Phosphorylation in the Presence of a Novel Cyclic Phosphate Ester......Page 167
References......Page 170
37 α-Aminophosphonous Acids: A New Class of Biologically Active Amino Acid Analogs......Page 171
REFERENCES......Page 174
38 Phosphonodipeptides......Page 175
References:......Page 178
39 Some Aspects of the Chemical Synthesis of Oligodeoxyribonucleotides......Page 179
Literature Cited......Page 182
40 Coupling of Fatty Diazomethylketones with Organophosphorus Acids An Approach to Glycerophospholipid Analog Synthesis......Page 183
Literature Cited......Page 186
41 Design of Organophosphorus Reagents for Peptide Synthesis......Page 187
42 The Nature of the Energy Transduction Links in Mitochondrial Oxidative Phosphorylation......Page 193
Literature Cited......Page 197
43 ADP Hydrolysis Promoted by Cobalt(III)......Page 198
Literature Cited......Page 202
44 PMR Measurements of Chair-Twist Conformational Equilibria for Diastereomeric P-Derivatives of Thymidine Cyclic 3',5'-Monophosphate Possible Implications for Naturally Occurring Cyclic Nucleotides......Page 204
LITERATURE CITED......Page 207
45 Phosphonate Inhibitors of Carboxypeptidase A......Page 208
LITERATURE CITED......Page 211
46 "Illicit Transport" Systems for Organophosphorus Antimetabolites......Page 212
Literature Cited......Page 215
47 The Preparation of Phosphorus Esters and Thioesters from White Phosphorus......Page 216
LITERATURE CITED......Page 219
48 Thermal Rearrangement and Condensation of O,O-Dimethyl-O-phenylphosphorothionate......Page 220
Literature cited......Page 223
49 Synthesis and Reactivity of (Silylamino)phosphines......Page 224
Literature Cited......Page 227
50 Addition of Lithium Dialkylcuprates to α,β-Unsaturated Phosphoryl Compounds Nucleophilic Properties of Adducts......Page 228
Literature Cited:......Page 231
51 Phosphorylated Ketenes......Page 232
Literature Cited......Page 235
52 Preparation and Properties of N-(Hydroxycarbonylmethyl)aminomethyl Alkyl- and Arylphosphinic Acids and Derivatives......Page 236
Literature Cited......Page 238
53 Some Aspects of Aminoalkylphosphonic Acids Synthesis by the Reductive Amination Approach......Page 239
Literature Cited......Page 242
Phosphorus Hydrides......Page 243
Polycyclic Organylphosphanes......Page 245
Literature Cited......Page 247
Experimental......Page 248
Results and Discussion (5, 6)......Page 249
Literature Cited......Page 251
56 NMR Characterization of Homologous Cyclic Phosphoramides......Page 252
Notes and References......Page 255
57 Synthesis and Chemical Behavior of Some Bicyclophosphanes......Page 256
REFERENCES......Page 259
58 Reactions of 2,4-Bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-Disulfide......Page 260
59 Small Rings with Tervalent Phosphorus......Page 263
Literature Cited......Page 266
60 The Unexpected Formation of 1,2-Oxaphosphol-3-ene 2-Oxides in the Reaction of Diacetone Alcohol with Phosphonous Dihalides......Page 267
Literature Cited......Page 270
61 Dihydrophenophosphazines via the Interaction of Diarylamines and Phosphorus Trichloride: Applications and Limitations......Page 271
Literature Cited......Page 274
62 Contributions to the Chemistry of N-Phosphoryl Phosphazenes......Page 275
Literature Cited......Page 278
63 Conjugation in Phosphazenes: Pyrrylphosphazenes and Phosphazenyl Carbanions......Page 279
Literature Cited.......Page 284
64 Structure, Conformation, and Basicity in Cyclophosphazenes and Related Compounds......Page 285
Literature cited......Page 288
65 Phosphazene Rings and High Polymers Linked to Transition Metals or Biologically Active Organic Species......Page 289
References......Page 292
66 Polymerization of Hexachlorocyclotriphosphazene......Page 293
Literature Cited......Page 298
67 Alkenylfluorocyclotriphosphazenes......Page 299
Literature Cited......Page 302
68 The Reactions of Halophosphazenes with Organometallic Reagents......Page 303
Literature Cited......Page 307
69 1,2-Bis(dichlorophosphino)alkanes......Page 308
LITERATURE CITED......Page 311
70 Products of Peracid Oxidation of S-Alkyl Phosphorothiolate Pesticides......Page 312
Literature Cited......Page 315
71 Research on Organophosphorus Insecticides, Synthesis of O-Alkyl O-Substituted Phenyl Alkylphosphonothioates......Page 316
Literature Cited......Page 319
72 Introduction of Phosphorus into the Polyethyleneterephthalate Molecule......Page 320
LITERATURE CITED......Page 324
73 Selected Novel Trivalent Organophosphorus Processing Stabilizers for Polyolefins......Page 325
Polypropylene (Profax 6801, Hercules Inc.) Multiple Extrusion At 500°F (260°C)......Page 327
REFERENCES CITED......Page 328
Polycondensation of 2-Chloroalkyl Phosphates and Phosphonates......Page 329
Copolycondensation......Page 330
Applications as Flame Retardants......Page 331
LITERATURE CITED......Page 332
Phosphate Fibers......Page 333
Animal Studies......Page 334
Literature Cited......Page 337
Mechanism of formation of fluorapatite from apatitic tricalcium phosphate and calcium fluoride in the solid state.......Page 338
Apatites with large amounts of fluoride ions : the B-type carbonated fluorapatite.......Page 339
Literature cited......Page 341
Sample Preparation......Page 342
Photo-Coloring (Photochromism)......Page 343
Literature Cited:......Page 346
78 A Gel Chromatographic Study on the Interactions of Long-Chain Polyphosphate Anions with Magnesium Ions......Page 347
Literature Cited......Page 350
79 Phosphaalkenes, R2C=PR', and Phosphaalkynes, RC≡P......Page 351
Literature Cited......Page 356
Phosphinyl Radicals as Ligands......Page 359
Pentamethylcyclopentadienyl-Substituted Phosphenium Ions......Page 360
Literature Cited......Page 361
81 31P NMR Investigations on Dicoordinated Phosphorus Compounds in P(II) = C-P(III) Systems......Page 363
NMR Investigations......Page 364
Results and Discussion......Page 366
Literature Cited......Page 368
82 Synthesis and Properties of Phosphaalkenes......Page 369
Literature Cited......Page 372
1,3-Benzazaphospholes......Page 373
Carbosilylated Phospha-Alkenes......Page 374
Dialkylamino Alkylidene Phosphines......Page 375
Literature Cited......Page 376
84 Reactions of 2,4,6-Tri(t-butyl)phenyllithium with Phosphorus Halides......Page 377
Literature Cited......Page 379
85 Synthesis of New Dicoordinated Phosphorus Compounds with a P(III)=N Bond......Page 381
Litterature cited :......Page 384
86 Cyano Anions of Dicoordinated, Tricoordinated, Tetracoordinated, Pentacoordinated, and Hexacoordinated Phosphorus......Page 385
87 Preparation, Reactions, and Structures of Some N,N'-Dimethylurea-Bridged Phosphorus Compounds......Page 391
Literature cited......Page 394
88 A Stable Monocyclic Triarylalkoxyhydridophosphorane A 10-P-5 Species with an Apical P-H Bond......Page 395
Literature Cited......Page 399
89 Monocyclic Phosphoranide and Phosphoranoxide Anions P(V) Oxyphosphorane Carbanion — P(IV) Ylide Alkoxide Tautomerism......Page 400
Literature Cited......Page 402
90 Selectivity in Reactions of Tricyclic Phosphatranes......Page 404
Literature Cited......Page 407
91 The Perfluoropinacolyl Group: A Stabilizing Substituent for Unusual Phosphites and Phosphoranes......Page 408
92 Tartaric Acid in Phosphorus Chemistry: Phosphor Emetics and Oligomers......Page 412
LITERATURE CITED......Page 416
93 Nucleophilic Substitution at Pentacoordinated Phosphorus Addition-Elimination Mechanism......Page 417
Literature Cited:......Page 420
Stabilities......Page 421
Insolubility of Protonated Chelates......Page 422
Polyphosphates as Ligands......Page 423
Literature Cited......Page 424
95 Transition VIB Metal π-Complexes of λ3- and λ5-Phosphorins and Some of Their Reactions......Page 425
Literature cited......Page 428
96 Synthesis of Transition Metal Phosphoranides Conversion of Bicyclic Phosphoranes into Phosphoranides and Phosphane Adducts with Transition Metal Derivatives......Page 430
Literature Cited......Page 433
97 Secondary Phosphino Macrocyclic Ligands......Page 434
Literature Cited.......Page 436
98 Dicoordinated and Tricoordinated Acyclic Phosphazenes as Complex Ligands......Page 438
Experimental Procedure......Page 441
Discussion......Page 442
Literature Cited......Page 445
100 Structural and Magnetic Investigation on Transition Metal Complexes with Tripodal Polytertiary Phosphines......Page 446
Chromium, Molybdenum, and Tungsten Derivatives......Page 448
Iron Carbonyl Derivatives......Page 449
Literature Cited......Page 451
102 New Aspects of the Coordination Chemistry of Carbonyl Phosphines......Page 452
Literature Cited......Page 456
Synthesis of chiral aminophosphines from natural aminoacids.......Page 457
Asymmetric C-C bond formation catalysed by metallic complexes with chiral amino-phosphines as ligands.......Page 459
Literature cited......Page 460
104 31P NMR Studies of Catalytic Intermediates in Triphenylphosphine Rhodium Complex Hydroformylation Systems......Page 461
Literature Cited:......Page 467
105 New Data on the Mechanism of the Perkow-Arbuzov Reaction......Page 468
Literature cited......Page 471
106 Structure and Reactivity of Quasiphosphonium Intermediates......Page 472
Literature cited......Page 475
107 Reactions of Triorganosilyl Halides with Esters of Tricoordinated and Tetracoordinated Phosphorus......Page 476
Literature Cited......Page 479
108 Halogenolysis of the Phosphorus-Sulfur Bond in Thioloesters of Organic Phosphorus Thioacids......Page 480
Literature Cited......Page 483
109 Isotope Effects in Amination Reactions of Chlorocyclophosphazenes......Page 484
Literature Cited......Page 487
110 Zwitterionic σ-Complexes: Their Role as Intermediates in Phosphorylation of Aromatics by Phosphorus Compounds......Page 488
σ-Complexes of PIII with derivatives of TNB......Page 489
Nucleophilic phosphorylation of 5-nitropyrimidines......Page 490
Literature Cited......Page 491
111 Use of X-Ray Structural Results on Phosphorus Compounds in Modeling Reaction Mechanism......Page 492
Literature Cited......Page 496
112 Ligand Effects on the Reaction of Alkoxide Ions with Organophosphorus Derivatives Containing Multiple Leaving Groups......Page 497
Literature Cited......Page 500
113 Methanolysis of a Phosphate Ester......Page 501
Literature Cited......Page 504
114 Reactivity of Tricoordinated Phosphorus Compounds A Mechanistic Study with a Variety of Substrates......Page 505
Literature cited......Page 508
115 A New Stereospecific Synthesis of a P(III) Organophosphorus Ester......Page 509
Literature Cited......Page 511
116 A Single Crystal X-Ray Diffraction Analysis of (1R,1'S)-1,1'-Ethylenebis(1,2,3,4-tetrahydro-4,4-dimethyl-1-phenylphosphinolinium) Diperchlorate......Page 512
Literature Cited......Page 516
117 Stereochemical Investigation of Chiral Onium Hexaarylphosphates......Page 517
LITERATURE CITED......Page 520
Results and Discussion......Page 521
Literature Cited......Page 524
Results......Page 525
Literature cited......Page 528
Experimental.......Page 529
Results.......Page 530
References......Page 532
121 Application of the 18O Shift on the 31P NMR Spectrum to the Elucidation of Biochemical Phosphate Transfer Mechanisms......Page 533
Studies on Purine Nucleoside Phosphorylases......Page 534
Position of Bond Cleavage or Formation in Some Other Phosphate Transfers......Page 536
Literature Cited......Page 537
122 Phospholipase A2 Hydrolysis of Phospholipids: Use of 31P NMR to Study the Hydrolysis, Acyl Migration, Regiospecific Synthesis, and Solubilization of Phospholipids......Page 538
123 Photolytic Rearrangement of Phosphorus, Germanium, and Silicon Azides: Evidence for New Hybridized Species......Page 542
Literature cited :......Page 545
124 Diphenylphosphinous Acid by UV Irradiation of Aroyl Diphenyl Phosphines......Page 546
References......Page 549
125 Chemical Model Showing Three Phenomena: Phosphorane→Ylide, Ylide → Phosphorane, and Phosphorane Ylide......Page 550
Literature cited......Page 553
Phosphonomethylphosphinates with Aldehydes......Page 554
Bis(Phosphonomethyl)phosphinates with Aldehydes......Page 555
Discussion......Page 556
Literature Cited......Page 557
127 Structure-Reactivity Studies on Oxygen-Containing Phosphorus-Based Ligands......Page 558
Literature Cited......Page 561
Restricted Rotation......Page 562
Molecular Structures......Page 563
Solvolytic Behavior......Page 564
Literature Cited......Page 565
POSTER PRESENTATIONS......Page 566
B......Page 574
D......Page 575
H......Page 576
N......Page 577
P......Page 578
R......Page 580
S......Page 581
T......Page 582
Z......Page 583
