Volume II/26 supplements the previous compilations II/l, II/9 and II/17 of the magnetic properties of free radicals which were published in 1965, 1977–1980 and 1986–90. Due to the still rapid growth of the field and the necessary inclusion of new subjects the volume is divided into subvolumes which will appear in fast succession. Together with the earlier publications volume II/26 offers an up-to-date and comprehensive survey and collection of structures and data on the important chemical intermediates, namely radicals, polyradicals and related species such as carbenes, nitrenes, etc. As before the species have been grouped according to chemical aspects. The contents of the individual subvolumes are indicated on the inside of the front covers. For each group of substances the literature has been compiled and extracted by experts in the fields. A small overlap between the chapters is intentional and allows a maximum of coherence and comprehensiveness of the display. We wish to thank all the authors for their careful and experienced work and the most agreeable cooperation, the Landolt-Börnstein office, especially Mrs. A. Endemann, for the layouts and the untiring and careful checking of manuscripts and galley proofs, and Springer-Verlag for the customary care in the preparation of the volume which is published without external financial support. Zürich, December 2003 The Editor Table of contents Magnetic Properties of Free Radicals Subvolume E: Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions Part 2 I Introduction I General introduction [H. Fischer]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 A Definition and substances . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Author(s): H. Fischer (auth.), H. Fischer (eds.)
Series: Landolt-Börnstein - Group II Molecules and Radicals 26E2 : Molecules and Radicals
Edition: 1
Publisher: Springer-Verlag Berlin Heidelberg
Year: 2009
Language: English
Commentary: Reduced file size - optimized document overhead. No quality loss
Pages: 445
Cover
Front-matter
ISBN 9783540876397
Editor and Authors
Preface
Table of contents
I General introduction
A Definition and substances
B Magnetic properties
C Arrangements of the tables
D Monographs, reviews and important conference proceedings
III General symbols and abbreviations
A Symbols
B Abbreviations
C Substances or part of substances
16 Semiquinone radical anions
16.1 Introduction
16.2 Benzosemiquinones
16.2.1 1,2-Benzosemiquinones
16.2.1.1 Monosubstituted 1,2-benzosemiquinones
References for 16.2.1.1
16.2.1.2 3,4-Disubstituted 1,2-benzosemiquinones
References for 16.2.1.2
16.2.1.3 3,5-Disubstituted 1,2-benzosemiquinones
References for 16.2.1.3
16.2.1.4 3,6-Disubstituted 1,2-benzosemiquinones
References for 16.2.1.4
16.2.1.5 4,5-Disubstituted 1,2-benzosemiquinones
References for 16.2.1.5
16.2.1.6 Trisubstituted 1,2-benzosemiquinones
References for 16.2.1.6
16.2.1.7 Tetrasubstituted 1,2-benzosemiquinones
References for 16.2.1.7
16.2.1.8 Imino-1,2-benzosemiquinones
References for 16.2.1.8
16.2.2 1,4-Benzosemiquinones
16.2.2.1 Unsubstituted 1,4-benzosemiquinones
References for 16.2.2.1
16.2.2.2 Monosubstituted 1,4-benzosemiquinones
References for 16.2.2.2
16.2.2.3 Disubstituted 1,4-benzosemiquinones
References for 16.2.2.3
16.2.2.4 Trisubstituted 1,4-benzosemiquinones
References for 16.2.2.4
16.2.2.5 Tetrasubstituted 1,4-benzosemiquinones
References for 16.2.2.5
16.3 1,4-Naphthosemiquinones
References for 16.3
16.4 9,10-Phenanthrosemiquinones
References for 16.4
16.5 9,10-Anthrosemiquinones
References for 16.5
16.6 Other semiquinones
References for 16.6
17 Organic radical cations
17.1 Introduction
17.1.1 Coverage of this chapter
17.1.2 Presentation of the data
17.1.3 Spectroscopic methods
17.1.4 Generation of radical cations
17.1.4.1 By metals in high oxidation states
17.1.4.2 By protic acids
17.1.4.3 By Lewis acids
17.1.4.4 By stable radical cations
17.1.4.5 By Zeolites
17.1.4.6 By anodic oxidation
17.1.4.7 By γ-, X-, or electron irradiation
17.1.4.8 By optically-detected electron spin resonance
References for 17.1
17.2 Radical cations of alkanes
References for 17.2
17.3 Radical cations of cycloalkanes
17.3.1 Radical cations of cyclohexanes
References for 17.3.1
17.3.2 Radical cations of other cycloalkanes
References for 17.3.2
17.4 Radical cations of alkenes
17.4.1 Radical cations of acyclic monoenes
References for 17.4.1
17.4.2 Radical cations of acyclic di- and higher-enes
References for 17.4.2
17.4.3 Radical cations of cyclic monoenes
References for 17.4.3
17.4.4 Radical cations of cyclic di- and higher-enes
References for 17.4.4
17.5 Radical cations of alkynes
References for 17.5
17.6 Aromatic hydrocarbons
17.6.1 Benzene hydrocarbons
References for 17.6.1
17.6.2 Radical cations of bi-, tri-, and tetra-phenylenes
References for 17.6.2
17.6.3 Radical cations of biphenyls and higher biaryls
References for 17.6.3
17.6.4 Radical cations of azulenes
References for 17.6.4
17.6.5 Radical cations of polycyclic aromatic hydrocarbons
References for 17.6.5
17.7 Radical cations of cyclophanes
References for 17.7
17.8 Radical cations of compounds of oxygen
17.8.1 Radical cations of aliphatic alcohols and ethers
References for 17.8.1
17.8.2 Radical cations of furans
References for 17.8.2
17.8.3 Radical cations of carbonyl compounds
References for 17.8.3
17.8.4 Radical cations of phenols and aromatic ethers
References for 17.8.4
17.9 Radical cations of compounds of nitrogen
17.9.1 Radical cations of aliphatic amines and derivatives
References for 17.9.1
17.9.2 Radical cations of imines
References for 17.9.2
17.9.3 Radical cations of diazo compounds
References for 17.9.3
17.9.4 Radical cations of azo compounds
References for 17.9.4
17.9.5 Radical cations of hydrazines
References for 17.9.5
17.9.6 Radical cations of aromatic amines
References for 17.9.6
17.9.7 Radical cations of nitroso and related compounds
References for 17.9.7
17.9.8 Radical cations of pyrroles
References for 17.9.8
17.9.9 Heteroaromatic compounds containing 1 or 2 nitrogen atoms
References for 17.9.9
17.9.10 Heteroaromatic compounds containing 3 or 4 nitrogen atoms
References for 17.9.10
17.9.11 Radical cations of heteroaromatic compounds containing both nitrogen and sulphur
References for 17.9.11
17.10 Radical cations of compounds of sulfur.
17.10.1 Radical cation of sulfides
References for 17.10.1
17.10.2 Radical cations of thiophenes
References for 17.10.2
17.10.3 Radical cations of thiofulvalenes
References for 17.10.3
17.10.4 Radical cations of aromatic and heterocyclic sulphur compounds
References for 17.10.4
17.10.5 Radical cations of other compounds of sulfur, selenium, and tellurium
References for 17.10.5
17.11 Radical cations of halides
17.11.1 Radical cations of alkyl halides
References for 17.11.1
17.11.2 Radical cations of aryl fluorides
References for 17.11.2
17.12 Radical cations of compounds of phosphorus
References for 17.12
17.13 Radical cations of organometallic compounds
17.13.1 Radical cations of organosilanes
References for 17.13.1
17.13.2 Radical cations of organomercury compounds
References for 17.13.2
17.13.3 Radical cations of other organometallic compounds
References for 17.13.3
