Phenomena in Mixed Surfactant Systems

Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 An Overview of Phenomena Involving Surfactant Mixtures......Page 8
Micelle Formation......Page 9
Mixed Micelles Showing Negative Deviation from Ideality.......Page 14
Mixed Micelles Showing Positive Deviations from Ideality.......Page 19
Monolayer Formation......Page 20
Solubilization......Page 22
Adsorption on Solids......Page 24
Surfactant Precipitation......Page 25
Cloud Point Phenomena......Page 28
Conclusions......Page 29
Literature Cited......Page 30
2 Nonideal Mixed MicellesThermodynamic Models and Experimental Comparisons......Page 35
Thermodynamics of Mixed Micelle Formation......Page 38
Experimental......Page 39
Results and Discussion......Page 40
Literature Cited......Page 48
3 New Mathematical Models of Mixed Micellization......Page 49
Mass Action Model (MAM)......Page 50
Pseudo-Phase Separation Model (PSM)......Page 54
Conclusions......Page 59
Literature Cited......Page 64
4 A Study of Mixed Aqueous Solutions of Hydrocarbon and Fluorocarbon Surfactants Using 8-Anilino-1-naphthalenesulfonic Acid Ammonium Salt......Page 66
The behavior of the fluorescence probe, ANS in the aqueous single surfactant solution......Page 67
The behavior of the fluorescence probe, ANS in the mixed aqueous surfactant solutions......Page 68
Summary......Page 70
Literature Cited......Page 72
5 Solution Properties of Mixed Surfactant Systems The Interaction Between Azo Oil Dyes and Mixed Surfactant Systems......Page 73
Preparation of surfactant solutions including oil dye.......Page 74
(1) Protonation equilibrium of 4-NH2......Page 75
(2) Tautomerism equilibrium of 4-OH......Page 77
Conclusion......Page 82
Literature Cited......Page 83
6 Thermodynamics of the Mixed Micellar System Sodium Decanoate-2-Butoxyethanol in Water at 25°C......Page 84
Results and Discussion......Page 86
Literature Cited......Page 93
7 Characterization of Inverted Micelles of Calcium Alkarylsulfonates by Some Pyrene Fluorescence Probes......Page 95
Experimental......Page 96
Results......Page 97
Discussion......Page 100
Literature Cited......Page 104
8 Nonideal Mixed Monolayer Model......Page 105
Theory......Page 106
Results and Discussion......Page 110
Legend of Symbols......Page 116
Literature Cited......Page 117
9 Monolayer Properties of Octadecyldimethylamine Oxide and Sodium Alkyl Sulfate......Page 119
Experimental......Page 120
Results......Page 121
Discussion......Page 128
Literature Cited......Page 134
10 The Penetration of Monolayers by Surfactants......Page 136
Theory......Page 137
Discussion......Page 139
Legend of Symbols......Page 144
Literature Cited......Page 145
11 Molecular Interaction and Synergism in Binary Mixtures of Surfactants......Page 146
Literature Cited......Page 164
12 Thermodynamic Study of the Surface Adsorption and Micelle Formation of Mixed Surfactants......Page 165
Results and Discussion......Page 166
Literature Cited......Page 173
13 The Effect of Alkyl Alcohols on the Surface Adsorption and Micellization of Fluorocarbon and Hydrocarbon Surfactants......Page 174
Results and Discussions......Page 175
Literature Cited......Page 184
14 Surface Adsorption and Micellization of the Mixed Solution of Fluorocarbon and Hydrocarbon Surfactants......Page 186
Theoretical background......Page 187
Results and Discussions......Page 190
Conclusion......Page 199
Literature cited......Page 200
15 Adsorption of a Mixture of Anionic Surfactants on Alumina......Page 201
Experimental......Page 204
Results and Discussion......Page 207
Literature Cited......Page 215
16 Adsorption, Electrokinetic, and Flotation Properties of Minerals above the Critical Micelle Concentration......Page 217
Results and Discussion......Page 218
Literature Cited......Page 225
17 Competitive Adsorption of an Anionic and a Nonionic Surfactant on Polystyrene Latex......Page 226
Experimental......Page 227
Thermodynamic Background......Page 228
Results and Discussion......Page 235
Literature Cited......Page 241
18 Self-Emulsification of Vegetable Oil-Nonionic Surfactant Mixtures A Proposed Mechanism of Action......Page 242
Experimental......Page 243
Results and Discussion......Page 244
Literature Cited......Page 254
19 The Mesophase Formation During a Dissolution of Cholesterol Monohydrate in Glycochenodeoxycholate-Glycoursodeoxycholate-Lecithin Solutions and Calcium Carbonate Solubility in Their Solutions......Page 256
PROCEDURES......Page 257
RESULTS AND DISCUSSION......Page 258
Literature Cited......Page 269
20 The Growth of Molecular Assemblies in Mild Surfactant Solutions......Page 270
EXPERIMENTAL......Page 271
Results and Discussion......Page 272
Literature Cited......Page 281
21 Micellar Solubilization of Methanol and Triglycerides......Page 283
Materials and Methods*......Page 284
Results and Discussion......Page 285
Literature Cited......Page 296
22 Effects of Different Distributions of Lyophobic Chain Length on the Interfacial Properties of Nonaethoxylated Fatty Alcohol......Page 297
Results and Discussion......Page 298
Literature Cited......Page 311
23 Mixed Adsorbed Film of 1-Octadecanol and Dodecylammonium Chloride at the Hexane-Water Interface......Page 312
Discussion......Page 313
Literature Cited......Page 321
24 Behavior and Applications of Surfactant Mixtures......Page 322
Micelle Formation......Page 323
Solubilization......Page 328
Adsorption on Solids......Page 329
Surfactant Precipitation......Page 331
Miscellaneous......Page 332
Literature Cited......Page 333
Author Index......Page 336
A......Page 337
C......Page 339
D......Page 340
H......Page 341
I......Page 342
M......Page 343
N......Page 344
P......Page 345
S......Page 346
Y......Page 348