Organogels: Thermodynamics, Structure, Solvent Role, and Properties

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This book provides a physics-oriented introduction to organogels with a comparison to polymer thermoreversible gels whenever relevant. The past decade has seen the development of a wide variety of newly-synthesized molecules that can spontaneously self-assemble or crystallize from their organic or aqueous solutions to produce fibrillar networks, namely organogels, with potential applications in organic electronics, light harvesting, bio-imaging, non-linear optics, and the like. This compact volume presents a detailed outlook of these novel molecular systems with special emphasis upon their thermodynamics, morphology, molecular structure, and rheology. The definition of these complex systems is also tackled, as well as the role of the solvent. The text features numerous temperature-phase diagrams for a variety of organogels as well as illustrations of their structures at the microscopic, mesoscopic and macroscopic level. A review of some potential applications is provided including hybrid functional materials with polymers and with carbon nanotubes. Throughout, discussions of theoretical developments and experimental advances are written at a level suitable for beginning graduate students through practicing researchers.

Author(s): Jean-Michel Guenet (auth.)
Series: SpringerBriefs in Materials
Edition: 1
Publisher: Springer International Publishing
Year: 2016

Language: English
Pages: XII, 122
Tags: Soft and Granular Matter, Complex Fluids and Microfluidics;Polymer Sciences;Nanotechnology;Phase Transitions and Multiphase Systems;Organic Chemistry;Inorganic Chemistry

Front Matter....Pages i-xii
Introduction....Pages 1-5
Gels: A Definition....Pages 7-15
Thermodynamic and Kinetic Aspects....Pages 17-36
Molecular Structure and Morphology....Pages 37-67
Solvent Role, Current Approaches....Pages 69-81
Rheological Aspects....Pages 83-94
Hybrid Gels....Pages 95-104
Current and Potential Applications....Pages 105-117
Back Matter....Pages 119-122