New Developments in Selective Oxidation

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This volume describes state-of-the-art advances in fundamental and applied aspects of partial selective oxidation in homogeneous and heterogeneous catalysis, including electrochemical and photo-oxidation. Comprising 93 papers, this book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation, serve as a springboard for new ideas and encourage innovation and creativity. Being an up-to-date reference source for all those studying in this field, this book should be on the bookshelf of all applied and academic research centres involved in the functionalization of molecules by selective oxidation.

Author(s): G. Centi and F. Trifiro (Eds.)
Series: Studies in Surface Science and Catalysis 55
Publisher: Elsevier Science
Year: 1990

Language: English
Pages: iii-xiv, 1-891

Content:
Edited by
Page iii

Copyright Page
Page iv

Preface
Page xiii
G. Centi, F. Trifiro

New Developments in Selective Oxidation
Page xiv

Catalytic Oxidations in the Manufacture of Fine Chemicals Original Research Article
Pages 1-32
Roger A. Sheldon

Selective Oxidation with Ti-Silicalite Original Research Article
Pages 33-41
U. Romano, A. Esposito, F. Maspero, C. Neri, M.G. Clerici

Cyclohexanone Ammoximation: A Break Through In The 6-Caprolactam Production Process Original Research Article
Pages 43-52
P. Roffia, G. Leofanti, A. Cesana, M. Mantegazza, M. Padovan, G. Petrini, S. Tonti, P. Gervasutti

Modified Zeolites for Oxidation Reactions Original Research Article
Pages 53-62
Cristina Ferrini, Herman W. Kouwenhoven

Mn(III)-Tetraarylporphyrins Bearing A Covalently Anchored Axial Ligand: Efficient Catalysts In Olefin Epoxidations Under Two-Phase Conditions. Original Research Article
Pages 63-70
P.L. Anelli, S. Banfi, F. Montanari, S. Quici

Alkene Epoxidation With Hydrogen Peroxide, Catalyzed By Metalloporphyrins Original Research Article
Pages 71-79
G. Goor, G. Prescher, M. Schmidt

Use of Bimetallic Systems for The Selective Oxidation of Olefins With Hydrogen Peroxide Original Research Article
Pages 81-88
Giorgio Strukul, Andrea Zanardo, Francesco Pinna

Platinum Catalysts for Cyclohexene Epoxidation with an Oxygen-Hydrogen Mixture Original Research Article
Pages 89-96
N.I. Kuznetsova, A.S. Lisitsyn, A.I. Boronin, V.A. Likholobov

Selective Oxidation of Alcohols to Carbonyl Compounds By Manganese (III) μOxo Carboxylato Complexes Original Research Article
Pages 97-108
Hubert Mimoun, Lucien Saussine, Stéphane Menage, Jean-Jacques Girerd

Selective Oxidations Catalyzed By Dioxo(Porphyrinato)Ruthenium(VI) Species Original Research Article
Pages 109-117
Nimal Rajapakse, Brian R. James, David Dolphin

Ruthenium (II) Catalysts for the Homogeneous Oxygenation of Aliphatic Hydrocarbons and Ethers Original Research Article
Pages 119-124
M. Bressan, A. Morvillo

Direct Conversion of Benzene to Phenols Under Ambient Conditions Original Research Article
Pages 125-131
Kazuo Sasaki, Sotaro Ito, Atsutaka Kunai

A Novel and Effective Oxygenation of 2,3,6-Trimethylphenol To Trimethyl-p-Benzoquinone by Dioxygen with Copper(II) Chloride/Amine Hydrochloride System Catalyst Original Research Article
Pages 133-138
Katsuomi Takehira, Masao Shimizu, Yoshihito Watanabe, Hideo Orita, Takashi Hayakawa

Phenol Oxidation With Molecular Oxygen in The Presence of Metallic Copper Original Research Article
Pages 139-145
N. Ravasio, M. Gargano, M. Rossi

Platinum Catalyzed Oxidation of 5-Hydroxymethylfurfural Original Research Article
Pages 147-158
P. Vinke, H.E. van Dam, H. van Bekkum

The Use of Precious Metal Catalysts Supported on Activated Carbon in Oxidation Reactions for The Synthesis of Fine Chemicals, Especially for The Selective Oxidation of Glucose to Gluconic Acid Original Research Article
Pages 159-168
B.M. Despevroux, K. Deller, E. Peldszus

Liquid-Phase Oxidation of Hydrocarbons and Alcohols Catalyzed by Heterogeneous Palladium and Platinum Catalysts Original Research Article
Pages 169-176
M. Hronec, Z. Cvengrosova, J. Tuleja, J. Ilavsky

Catalytic Oxidation of 1-Alkenes With Molecular Oxygen and Palladium Nitro Complexes Original Research Article
Pages 177-184
N.H. Kiers, B.L. Feringa, P.W.N.M. van Leeuwen

Selective Cyclohexane Oxidation Catalyzed By The Gif System Original Research Article
Pages 185-194
Ulf Schuchardt, Valdir Mano

Metalloporphyrin-Catalyzed Oxidation of Cyclohexane with Dioxygen Original Research Article
Pages 195-203
R. Iwanejko, T. Mulodnicka, J. Potowicz

Oxometalates and Dioxygen in Catalytic Oxidation Original Research Article
Pages 205-212
J.-M. Brégeault, B. El Ali, J. Mercier, J. Martin, C. Martin, O. Mohammedi

H NMR Study of The Mechanism of Ethyleneglycol Monoacetate Formation in Oxidative Acetoxylation of Ethylene Catalyzed by Pd(II) Complexes Original Research Article
Pages 213-220
E.V. Gusevskaya, I.E. Beck, A.G. Stepanov, V.A. Likholobov, K.I. Zamaraev

Perspectives in Improvement of Selectivity In Liquid Phase Oxidation by Dioxygen. New Models of Enzymatic Oxidation Original Research Article
Pages 221-228
I.P. Skibida, A.M. Sakharov

Catalytic Nitroxidation of Aliphatic and Aromatic Hydrocarbons by No (review) Original Research Article
Pages 229-238
G.M. Pajonk

Selective Oxidation of Hydrocarbons by Nitric Oxide to Nitriles Original Research Article
Pages 239-246
V.M. Belousov, S.B. Grinenko

Selective Oxidation of Anthracene Original Research Article
Pages 247-255
N.T. Do, R. Kalthoff, J. Laacks, S. Trautmann, M. Baerns

Vapor-Phase Oxidation of Alpha-Methylstyrene to Phenylacrolein Original Research Article
Pages 257-266
M. Ai

Partial Oxidation of o-Xylene to Phthalic Anhydride in a Structured Fixed Bed Containing a Sequence of Catalysts Original Research Article
Pages 267-274
M. Kotter, D.X. Li, L. Riekert

YBa2Cu3O6 – A Selective Ammoxidation Catalyst Original Research Article
Pages 275-286
J.C. Otamiri, A. Andersson, S. Hansen, J.-O. Bovin

Catalytic Properties of The High – Temperature Superconductor Y-Ba-Cu-Ag-O Towards The Oxidation of Methanol Original Research Article
Pages 287-294
D. Klissurski, J. Pesheva, Y. Dimitriev, N. Abadjieva, L. Minchev

Selective Oxidation of Propylene Over Rare Earth-Molybdate Catalysts Original Research Article
Pages 295-304
J.M. Lopez Nieto, R. Bielsa, G. Kremenic, J.L.G. Fierro

Oxyesterification of Methanol To Methylformate Over V-Ti Oxide Catalysts Original Research Article
Pages 305-315
A.S. Elmi, G. Busca, C. Cristiani, P. Forzatti, E. Tronconi

Oxidative Transformation of Methanol To Higher Aldehydes Over Zeolite — Oxide Catalysts Original Research Article
Pages 317-325
P. Jiru, Z. Tvaruzkova, K. Habersberger

Tin-Germanium Phosphates As Selective Catalysts For The Oxidative Dehydrogenation of Ethylbenzene To Styrene Original Research Article
Pages 327-334
M. Turco, G. Bagnasco, P. Ciambelli, A. La Ginestra, G. Russo

Selective Photochemical Conversion of Methane Into Worthier Compounds Original Research Article
Pages 335-342
K. Ogura, C.T. Migita, T. Yamada, S. Chaki

Working Principle of Li Doped Mgo Applied For The Oxidative Coupling of Methane Original Research Article
Pages 343-349
J.M.N. van Kasteren, J.W.M.H. Geerts, K. van der Wiele

Working Principle of Li Doped Mgo Applied for The Oxidative Coupling of Methane Original Research Article
Pages 350-352
J.M.N. van Kasteren, J.W.M.H. Geerts, K. van der Wiele

Investigations On The Heterogeneously Catalyzed Oxidative Coupling of Methane Over Alkali Doped Metal Oxides Original Research Article
Pages 353-364
S. Bartsch, H. Hofmann

Oxidative Coupling of Methane Over LnLiO2 Catalysts. (Ln = Sm, Nd, La). Promoting Effect of MgO and CaO. Original Research Article
Pages 365-372
A. Kiennemann, R. Kieffer, A. Kaddouri, P. Poix, J.L. Rehspringer

Behavior of Metallic Oxides Suported On Li/MgO In The Methane Oligomerization Original Research Article
Pages 373-380
G.T. Baronetti, E.J. Lazzari, A.A. Castro, O.A. Scelza

Oxidative Coupling of Methane, the Effect of Gas Composition and Process Conditions. Original Research Article
Pages 381-392
J.A. Roos, S.J. Korf, J.J.P. Biermann, J.G. van Ommen, J.R.H. Ross

Role of Some Experimental Parameters In The Catalytic Conversion of Methane By Oxidative Coupling. Original Research Article
Pages 393-404
R. Spinicci

Models of The Direct Catalytic Partial Oxidation of Light Alkanes Original Research Article
Pages 405-415
J.G. McCarty, A.B. McEwen, M.A. Quinlan

General Mechanism for the oxidative coupling of methane Original Research Article
Pages 417-425
O. Forlani, M. Lupieri, V. Piccoli, S. Rossini, D. Sanfilippo, J.A. Dumesic, L.A. Aparicio, J.A. Rekoske, A.A. Trevino

The Mechanism of The Oxidative Coupling of Methane: Evidence That Ethylene Is A Primary Product Original Research Article
Pages 427-435
George W. Keulks, Min Yu

Heterolytic Mechanism of Methane Activation In Oxidative Dehydrodimerization Original Research Article
Pages 437-446
V.D. Sokolovskii, O.V. Buyevskaya, S.M. Aliev, A.A. Davydov

Sers-In Situ Study of The Surface Species Formed In Methane Oxidative Coupling Original Research Article
Pages 447-452
A.A. Kadushin, O.V. Krylov, S.E. Plate, Yu.P. Tulenin, V.A. Seleznev, A.V. Bobrov, Ya.M. Kimelfeld

In Situ Studies of the Oxidative Coupling of Methane Over Li-Ni-O Catalysts Original Research Article
Pages 453-458
I.J. Pickering, J.M. Thomas, P.J. Maddox

Selective Oxidation of Methane To Formaldehyde At Ambient Pressure: The Role of Dopants In Determining Optimum Carrier Loading For The Molybdena/Silica System Original Research Article
Pages 459-468
E. MacGiolla Coda, B.K. Hodnett

Oxidative Dimerization of Methane In High Temperature Electrochemical Devices Original Research Article
Pages 469-476
V.D. Belyaev, O.V. Bazhan, V.A. Sobyanin, V.N. Parmon

Selective Dehydrogenation of Ethane By Carbon Dioxide Over Fe-Mn Oxide Catalyst. An In Situ Study of Catalyst Phase Composition And Structure. Original Research Article
Pages 477-482
A.Kh. Mamedov, P.A. Shiryaev, D.P. Shashkin, O.V. Krylov

Role of Active Oxygen Forms and Acidity in Oxidative Conversion of Ethane on Zeolites Original Research Article
Pages 483-489
S.N. Vereshchagin, N.N. Shishkina, A.G. Anshits

Selective Oxidation of Propane To Acrolein and Ammoxidation To Acrylonitrile Over Ag-Doped Bismuth Vanadomolybdate Catalysts Original Research Article
Pages 491-504
Young-Chul Kim, Wataru Ueda, Yoshihiko Moro-Oka

Oxidative Dehydrogenation of Alkanes Over Alkali and Alkaline Earth Orthovanadates Original Research Article
Pages 505-514
K. Seshan, H.M. Swaan, R.H.H. Smits, J.G. Van Ommen, J.R.H. Ross

Synthesis of Acrylonitrile from Propane on V-Sb-based Mixed Oxides Original Research Article
Pages 515-526
G. Centi, R.K. Grasselli, E. Patane', F. Trifiro

Selective Catalytic Oxidation of Propane By Sulphur Dioxide Original Research Article
Pages 527-535
Z.G. Osipova, S.B. Ushkov, V.D. Sokolovskii, A.V. Kalinkin

Fluidized Bed Oxidation of n-Butane: A New Commercial Process for Maleic Anhydride Original Research Article
Pages 537-552
G. Stefani, F. Budi, C. Fumagalli, G.D. Suciu

Butane Oxidation in A Transport Bed Reactor – Redox Characteristics of The Vanadium Phosphorus Oxide Catalyst Original Research Article
Pages 553-562
Rashmi Contractor, Jerry Ebner, Michael J. Mummey

Reactivity and Structure of Vanadyl Pyrophosphate as A Butane Oxidation Catalyst Original Research Article
Pages 563-572
I. Matsuura, M. Yamazaki

Investigation of Active and Selective Oxygen In V-P-O Catalysts for n-Butane Conversion To Maleic Anhydride Original Research Article
Pages 573-583
M.E. Lashier, T.P. Moser, G.L. Schrader

Comparative Study of Structure-Sensitive Oxidations of n-Butane and 1-Butene in Maleic Anhydride on Two Kinds of Catalysts Original Research Article
Pages 585-593
E. Bordes

Identification of A Catalytically Active Copper Oxychloride Phase for The Synthesis of Maleic Anhydride Original Research Article
Pages 595-603
M.J. Davies, D. Chadwick, J.A. Cairns

Selective Oxidation of n-Butane To Maleic Anhydride Over Well-Characterized Vanadium-Phosphorus Mixed Oxides Original Research Article
Pages 605-615
Makoto Misono, Koichi Miyamoto, Katsuyuki Tsuji, Tatsuya Goto, Noritaka Mizuno, Toshio Okuhara

Product Distribution In The V-P-O Catalyst Bed And An Efect of Reaction Products on The Catalyst In C4 Oxidation Original Research Article
Pages 617-624
V.A. Zazhigalov, V.M. Belousov, A.I. Pyatnitskaya, G.A. Komashko, Yu.N. Merkureva, J. Stoch

A Dynamic Model of The Oxidation of n-Butane and 1-Butene on Various Crystalline Faces of (VO)2P2O7 Original Research Article
Pages 625-633
J. Ziolkowski, E. Bordes, P. Courtine

Synthesis of Phthalic and Maleic Anhydrides from n-Pentane: Reactivity of Possible Intermediates and co-Feeding Experiments Original Research Article
Pages 635-642
G. Centi, D. Pinelli, F. Trifiro, F. Ungarelli, J. Lopez Nieto

Non-Faradaic Electrochemical Modification of Catalytic Activity: Partial Oxidation of C2H4 On Ag And CH3OH On Pt Original Research Article
Pages 643-652
C.G. Vayenas, S. Bebelis, S. Neophytides

Electrogenerative Oxidation of Ethanol on Platinized-Carbon Electrodes Original Research Article
Pages 653-660
Huang Zhong-Tao, Ye Daiqi, Pang Xianxing

Oxidation of L-Phenylalanine and Related Reactions: Preparation of L-DOPA. Original Research Article
Pages 661-666
M. Blanchard, C. Bouchoule, G. Djaneye-Boundjou, P. Canesson

Selective Electrooxidation of 4-(Di-n-propylsulfamyl)toluene to 4-(Di-n-propylsulfamyl)benzoic acid. Original Research Article
Pages 667-673
M. Michman, M. Weiss

Photocatalytic Oxidations At Room Temperature in Various Media Original Research Article
Pages 675-682
J.M. Herrmann, H. Courbon, J. Disdier, M.N. Mozzanega, P. Pichat

Dynamic Studies of Photocatalytic Oxidation of C3H6 WITH O2 On Vanadium Oxide Supported On Porous Vycor Glass Original Research Article
Pages 683-692
M. Anpo, T. Suzuki, Y. Yamada, Y. Otsuji, E. Giamello, M. Che

On Principles of Catalyst Choice for Selective Oxidation Original Research Article
Pages 693-700
G.I. Golodets

Mutual Orientation of Oxygen and Hydrocarbon Molecules as Factor Determining The Reaction Pathway Original Research Article
Pages 701-706
M. Witko, J. Haber, E. Broclawik

Characterizing Oxygen Adspecies for Ethylene Epoxidation Over Silver with The Tap Reactor System Original Research Article
Pages 707-716
N.C. Rigas, J.T. Gleaves, P.L. Mills

Ethylene Oxidation Over α-Alumina Supported Silver-Gold Catalysts Original Research Article
Pages 717-724
Herrera Rafael, Varma Arvind, Martínez Enrico

Ethylene Epoxidation on Silver-Based Alloy Catalysts Original Research Article
Pages 725-732
N. Toreis, X.E. Verykios

Ethylene Oxidation Over Hydrophobic Thin Layer Catalysts Original Research Article
Pages 733-738
F. Frusteri, A. Iannibello, A. Parmaliana, A. Cannizzaro, N. Giordano

The Mechanism of Alkene Epoxidation and Epoxide Conversion on Single Crystal Silver Surfaces Original Research Article
Pages 739-746
S. Hawker, C. Mukoid, J.P.S. Badyal, R.M. Lambert

Active Sites in Propylene Mild Oxidation as Studied on New [100] Oriented MoO3 Catalysts Original Research Article
Pages 747-756
M. Abon, B. Mingot, J. Massardier, J.C. Volta

Effects of Added SnO2, WO3, MoO3 and α-Sb2O4 on The Catalytic Properties of Bi2MoO6 in Selective Oxidation of Isobutene to Methacrolein Original Research Article
Pages 757-765
L.T. Weng, E. Sham, B. Doumain, P. Ruiz, B. Delmon

MoO3 On Anatase And Rutile Low-Surface-Area TiO2: Characterization And Oxidation of o-Xylene And Butene-1 Original Research Article
Pages 767-778
E. Filipek, B. Grzybowska, E. Serwicka, Y. Barbaux, J.P. Bonnelle, J. Grimblot

The Role of The Distribution of Double Bonded Oxygen on Surface of V-Mo-O Catalysts In Selective Oxidation of Benzene to Maleic Anhydride Original Research Article
Pages 779-787
M. Najbar, W. Wal, J. Chrzaszcz

Effect of Promoters on Activity and Selectivity of Benzene Oxidation on V2O5 Catalysts: Study by Well-Defined V2O5 Catalysts Original Research Article
Pages 789-796
Atsushi Satsuma, Michiatsu Nakata, Shun-ichi Iwasaki, Tadashi Hattori, Yuichi Murakami

Cooperation Between Phases in Mixed SnSbO Selective Oxidation Catalysts Original Research Article
Pages 797-806
L.T. Weng, E. Sham, P. Ruiz, B. Delmon, P. Patrono

Ir Spectroscopic Identification of Adsorbed Surface Species on Oxidation Catalysts Exposed To Propene and Ethene in Air Original Research Article
Pages 807-815
M.J. Pires, N.T. Do, M. Baerns, M.F. Portela

Oxidation of Propene and Toluene on CoO-MgO Solid Solutions: A Spectroscopic Study Original Research Article
Pages 817-824
E. Giamello, E. Garrone, S. Coluccia, G. Spoto, A. Zecchina

FT-IR Study of Selective Oxidation Intermediates of Benzene on The Surface of Vanadia-Titania “Monolayer” Catalysts Original Research Article
Pages 825-831
Guido Busca, Gianguido Ramis, Vincenzo Lorenzelli

Proposal for Active Sites of Iron Phosphates In Isobutyric Oxidative Dehydrogenation Reaction Original Research Article
Pages 833-841
Jean-Marc M. Millet, Jacques C. Vedrine, Gérard Hecquet

Heteropolyacid Catalysts for Oxydehydrogenation of Isobutyric Acid: Kinetics and Deactivation Original Research Article
Pages 843-852
O. Watzenberger, Th. Haeberle, D.T. Lynch, G. Emig

A Study of The Catalytic Oxydehydrogenation of Ethylbenzene Using Nitrobenzene Original Research Article
Pages 853-860
R. Fiedorow, S. Beszterda, W. Przystajko, I.G. Dalla Lana

The Adsorption of Aliphatic Nitrocompounds on Oxides Investigated By Ft-Ir Spectroscopy Original Research Article
Pages 861-868
P.A.J.M. Angevaare, E.J. Grootendorst, A.P. Zuur, V. Ponec

The Model of Active Centers for Partial Oxidation in The Structure of Heteropoly Compounds Original Research Article
Pages 869-879
M.Yu. Kutyrev, I.N. Staroverova, N.Z. Thiep, O.V. Krylov

Author Index
Pages 881-884

Subjext Index
Pages 885-887

Studies in Surface Science and Catalysis
Pages 889-891