Nanomaterials are materials with a characteristic length scale (particle diameter, grain size) or less than 100 nanometers. The use of nanoparticles aims to take advantage of their better or even different properties as compared to bulk behaviour (confinement effect, larger surface area to volume ratio). At first nanomaterials were used as catalysts and pigments but now the mechanical, optical, electric and biological properties of silicon based nanostructures and nanostructured ceramics are finding applications at all stages of materials processsing. nanostrcutured Silicon-Based Powders and Composites will be an invaluable reference for researchers in materials science, ceramics and biomaterials.
Author(s): Andre Pierre Legrand, Christiane Senemaud
Edition: 1
Publisher: Taylor & Francis
Year: 2003
Language: English
Pages: 319
City: London; New York
Book Cover......Page 1
Title......Page 4
Contents......Page 5
List of contributors......Page 12
Foreword......Page 14
Preface......Page 16
Acknowledgements......Page 17
Objectives and state-of-the-art of nanocomposites......Page 18
Laser synthesis of nanosized powders......Page 23
Thermal behaviour of as-formed silicon-based nanopowders......Page 42
Thermal behaviour in a high-temperature graphite furnace......Page 43
Thermal reactivity of silicon-based nanopowders......Page 58
Structure of some nanopowders and micro/nano composites by transmission electron microscopy......Page 71
From short- to long-range order......Page 127
Chemical order studied by solid-state nuclear magnetic resonance......Page 128
Paramagnetic defect states in silicon-based nanopowders......Page 156
Electronic structure studied by X-ray photoemission (XPS) and soft-X-ray (SXS) spectroscopies......Page 170
Local order in Si/C/N nanopowders studied by X-ray absorption spectroscopy: study at the Si;K edge......Page 199
Neutron and X-ray diffraction applied to the study of the medium-range order in SiCN nanopowders......Page 228
Conductivity and dielectric properties of Si/C nanopowders......Page 244
Processing and tailoring of Si/C/N-based nanocomposites......Page 255
Mechanical properties......Page 281
Theoretical investigations of Si/C/N-based alloys......Page 299
Index......Page 316