Nanoporous Materials III, Proceedings of the 3International Symposium on Nanoporous Materials

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Nanoporous Materials III contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 3rd Conference on Nanoporous Materials, which will be hosted in Ottawa, Canada, June 2002. The work covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves M41S and FSM16 and related materials including clays, carbon molecular sieves, colloidal crystal templated organic and inorganic materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic and separation processes as well as the development of nanotechnology.

The contents of this title are based on topics to be discussed by invited lecturers, which deal with periodic mesoporous organosilicas, stability and catalytic activity of aluminosilicate mesostructures, electron microscopy studies of ordered materials, imprinted polymers and highly porous metal-organic frameworks. The other contributions deal with tailoring the surface and structural properties of nanoporous materials, giving a detailed characterization as well as demonstrating their usefulness for advanced adsorption and catalytic applications.

Author(s): A. Sayari and M. Jaroniec (Eds.)
Series: Studies in Surface Science and Catalysis 141
Publisher: Elsevier Science
Year: 2002

Language: English
Pages: 1-691

Content:
Preface
Page v
Abdel Sayari, Mietek Jaroniec

Organizing Committee
Page vii

International Advisory Committee
Page vii

Recent developments in the synthesis and chemistry of periodic mesoporous organosilicas Original Research Article
Pages 1-26
Tewodros Asefa, Geoffrey A. Ozin, Hiltrud Grondey, Michal Kruk, Mietek Jaroniec

Porous materials: Looking through the electron microscope Original Research Article
Pages 27-34
O. Terasaki, T. Ohsuna, Z. Liu, M. Kaneda, S. Kamiya, A. Carlsson, T. Tsubakiyama, Y. Sakamoto, S. Inagaki, S. Che, T. Tatsumi, M.A. Camblor, R. Ryoo, D. Zhao, G. Stucky, D. Shindo, K. Hiraga

Molecular imprinting-a way to prepare effective mimics of natural antibodies and enzymes Original Research Article
Pages 35-44
Günter Wulff

Plugged hexagonal mesoporous templated silica: A unique micro- and mesoporous material with internal silica nanocapsules Original Research Article
Pages 45-52
P. Van Der Voort, P.I. Ravikovitch, A.V. Neimark, M. Benjelloun, E. Van Bavel, K.P. De Jong, B.M. Weckhuysen, E.F. Vansant

Imprinting of the surface of mesoporous silicates using organic structure directing agents Original Research Article
Pages 53-60
Kaveri R. Sawant, Raul F. Lobo

Synthesis and characterization of polymer-templated ordered silica with cage-like mesostructure Original Research Article
Pages 61-68
Jivaldo R. Matos, Michal Kruk, Lucildes P. Mercuri, Mietek Jaroniec

The modeling of wall structure of siliceous MCM-41 based on the formation process Original Research Article
Pages 69-76
Yasunori Oumi, Kazuhiko Azuma, Takuji Ikeda, Shintaro Sasaki, Tsuneji Sano

Pore size adjustment of bimodal mesoporous silica molecular sieves Original Research Article
Pages 77-84
Xiaozhong Wang, Tao Dou, Dong Wu, Bing Zhong

Alcothermal synthesis of large pore, high quality MCM-48 silica Original Research Article
Pages 85-92
Jihong Sun, Marc-Olivier Coppens

Studies of MCM-41 obtained from different sources of silica Original Research Article
Pages 93-100
Icaro S. Paulino

Synthesis and characterization of hexagonal mesoporous materials using hydrothermal restructuring method Original Research Article
Pages 101-108
Kyoung-Ku Kang, Hyun-Ku Rhee

Synthesis of highly ordered mesoporous compounds with control of morphology using a non-ionic surfactant as template Original Research Article
Pages 109-116
A. Léonard, J.L. Blin, B.-L. Su

Towards a better understanding on the mechanism of mesoporous formation via an assembly of Cn(EO)m and TMOS Original Research Article
Pages 117-125
J.L. Blin, A. Léonard, G. Herrier, G. Philippin, B.-L. Su

Mesoporous silicas via organic-inorganic hydrids based on charged polymers Original Research Article
Pages 127-132
Graham M Gray, John N Hay

Mesoporous silicas of hierarchical structure by hydrothermal surfactant-templating under mild alkali conditions Original Research Article
Pages 133-140
Zhong-Yong Yuan, Wuzong Zhou, Bao-Lian Su, Lian-Mao Peng

Synthesis and characterisation of super-microporous aluminosilicates prepared via primary amine templating Original Research Article
Pages 141-150
Ernesto Bastardo-Gonzalez, Robert Mokaya, William Jones

Al-MCM-41 synthesis using Al-isopropoxide as Al source Original Research Article
Pages 151-158
R. Bîrjega, R. Ganea, C. Nenu, Gr. Pop, A. Jitianu

Mesoporous aluminosilicates from coal fly ash Original Research Article
Pages 159-166
P. Kumar, N. Mal, Y. Oumi, T. Sano, K. Yamana

New route for synthesis of highly ordered mesoporous silica with very high titanium content Original Research Article
Pages 167-172
Xiang-Hai Tang, Xin Wen, Shi-Wei Sun, Hai-Yan Jiang

Synthesis and characterization of Ti-containing mesoporous alumina molecular sieves Original Research Article
Pages 173-182
Chun Yang, Xi Li

Organizing one-dimensional molecular wires in ordered mesoporous silica Original Research Article
Pages 183-188
Zongtao Zhang, Douglas A. Blom, Sheng Dai

Synthesis and catalytic properties of organically modified Ti-HMS Original Research Article
Pages 189-196
Yong Yang, Abdelhamid Sayari

Synthesis and characterization of methyl- and vinyl-functionalized ordered mesoporous silicas with high organic content Original Research Article
Pages 197-204
Michal Kruk, Tewodros Asefa, Mietek Jaroniec, Geoffrey A. Ozin

Polyfunctionalized silica adsorbents obtained by using dodecylamine as template Original Research Article
Pages 205-212
I.V. Mel'nyk (Seredyuk), Yu.L. Zub, A.A. Chuiko, M. Jaroniec, S. Mann

Characterization of mesoporous thin films formed with added organophosphonate and organosilane Original Research Article
Pages 213-220
Michael A. Markowitz, Eva M. Wong, Bruce P. Gaber

Improving the hydro-stability of MCM-41 by post-synthesis treatment and hexamethyldisilazane coating Original Research Article
Pages 221-228
Jing Yang, Antje Daehler, Michelle L. Gee, Geoffrey W. Stevens, Andrea J. O'Connor

Adsorption of CO on Zn-Cu(I)/HMCM-41 Original Research Article
Pages 229-234
Qihong Shi, Nongyue He, Fei Gao, Yibing Song, Yang Yu, Huilin Wan

Design of transition metal oxide mesoporous thin films Original Research Article
Pages 235-242
Eduardo L. Crepaldi, Galo J. de A.A. Soler-Illia, David Grosso, Pierre-Antoine Albouy, Heinz Amenitsch, Clément Sanchez

Mesoporous alumina as a support for hydrodesulfurization catalysts Original Research Article
Pages 243-250
Jiří Čejka, Naděžda ſilková, Luděk Kaluža, Miroslav Zdražil

Preparation and XAFS spectroscopic characterization of mesoporous titania with surface area more than 1200 m2/g Original Research Article
Pages 251-256
Hideaki Yoshitake, Tae Sugihara, Takashi Tatsumi

Mesoporous zirconium oxides: an investigation of physico-chemical synthesis parameters Original Research Article
Pages 257-264
J.L. Blin, L. Gigot, A. Léonard, B.L. Su

Single crystal particles of mesoporous (Nb, Ta)2O5 Original Research Article
Pages 265-272
Junko N. Kondo, Tomohiro Yamashita, Tokumitsu Katou, Byongjin Lee, Daling Lu, Michikazu Hara, Kazunari Domen

Preparation of exfoliated zeolites from layered precursors: The role of pH and nature of intercalating media Original Research Article
Pages 273-279
Wieslaw J. Roth, James C. Vartuli

Control of mesopore structure of smectite-type materials synthesized with a hydrothermal method Original Research Article
Pages 281-288
Masayuki Shirai, Kuriko Aoki, Kazuo Torii, Masahiko Arai

Synthesis, characterization and catalytic application of mesoporous sulfated zirconia Original Research Article
Pages 289-296
Young-Woong Suh, Hyun-Ku Rhee

Synthesis of mesoporous silicoaluminophosphates (SAPO) Original Research Article
Pages 297-300
Erica C. de Oliveira, Heloise O. Pastore

Synthesis and characterization of mesostructured vanadium-phosphorus-oxide phases Original Research Article
Pages 301-308
Moises A. Carreon, Vadim V. Guliants

Novel macroporous vanadium-phosphorus-oxides with three-dimensional arrays of spherical voids Original Research Article
Pages 309-316
Moises A. Carreon, Vadim V. Guliants

Engineering active sites in bifunctional nanopore and bimetallic nanoparticle catalysts for one-step, solvent-free processes Original Research Article
Pages 317-328
Robert Raja, John Meurig Thomas

Using Au nanoparticles-surfactant aqueous solution for a convenient preparation of mesoporous aluminosilicates containing Au-nanoparticles Original Research Article
Pages 329-336
Yu-Shan Chi, Hong-Ping Lin, Chinn-Nan Lin, Chung-Yuan Mou, Ben-Zu Wan

The use of templated mesoporous materials as templates for the development of ordered arrangements of nanowire and nanorods of electronically important materi Original Research Article
Pages 337-344
J.D. Holmes, T.R. Spalding, K.M. Ryan, D. Lyons, T. Crowley, M.A. Morris

Synthesis and adsorption properties of novel carbons of tailored porosity Original Research Article
Pages 345-352
Zuojiang Li, Michal Kruk, Mietek Jaroniec

Flexible metal-organic frameworks with isomerizing building units Original Research Article
Pages 353-362
D.V. Soldatov, J.A. Ripmeester

Dynamic porous frameworks of coordination polymers controlled by anions Original Research Article
Pages 363-370
Shin-ichiro Noro, Susumu Kitagawa

Mesoporous polymeric materials based on comb-coil supramolecules Original Research Article
Pages 371-378
Sami Valkama, Riikka Mäki-Ontto, Manfred Stamm, Gerrit ten Brinke, Olli Ikkala

Electron microscopic investigation of mesoporous SBA-2 Original Research Article
Pages 379-386
Wuzong Zhou, Alfonso E. Garcia-Bennett, Hazel M.A. Hunter, Paul A. Wright

A study of morphology of mesoporous silica SBA-15 Original Research Article
Pages 387-394
Man-Chien Chao, Hong-Ping Lin, Hwo-Shuenn Sheu, Chung-Yuan Mou

SBA-15 versus MCM-41: are they the same materials? Original Research Article
Pages 395-402
Anne Galarneau, Hélène Cambon, Thierry Martin, Louis-Charles De Ménorval, Daniel Brunel, Francesco Di Renzo, François Fajula

Comprehensive characterization of iron oxide containing mesoporous molecular sieve MCM-41 Original Research Article
Pages 403-410
Z.Y. Yuan, W. Zhou, Z.L. Zhang, Q. Chen, B.-L. Su, L.-M. Peng

Mesoporous molecular sieves of MCM-41 type modified with Cs, K and Mg-physico-chemical and catalytic properties Original Research Article
Pages 411-416
Maria Ziolek, Aleksandra Michalska, Jolanta Kujawa, Anna Lewandowska

Meso-ALPO prepared by thermal decomposition of the organic-inorganic composite: A FTIR study Original Research Article
Pages 417-422
Enrica Gianotti, Erica C. Oliveira, Valeria Dellarocca, Salvatore Coluccia, Heloise O. Pastore, Leonardo Marchese

Organic-inorganic phase interaction in AlSBA-15 mesoporous solids by double resonance NMR spectroscopy Original Research Article
Pages 423-428
Elias Haddad, Jean-Baptiste d'Espinose, Andrei Nossov, Flavien Guenneau, Claude Mignon, Antoine Gédéon

Adsorption of nitrogen on organized mesoporous alumina Original Research Article
Pages 429-436
Jirí Cejka, Lenka Veselá, Jirí Rathouský, Arnošt Zukal

The use of ordered mesoporous materials for improving the mesopore size analysis: Current state and future Original Research Article
Pages 437-444
Mietek Jaroniec, Michal Kruk, Abdelhamid Sayari

Sorption properties and hydrothermal stability of MCM-41 prepared by pH adjustment and salt addition Original Research Article
Pages 445-452
Nawal Kishor Mal, Prashant Kumar, Masahiro Fujiwara

Acidity characterization of MCM-41 materials using solid-state NMR spectroscopy Original Research Article
Pages 453-458
Qi Zhao, Wen-Hua Chen, Shing-Jong Huang, Yu-Chih Wu, Huang-Kuei Lee, Shang-Bin Liu

Acidity of calcined Al-, Fe- and La-containing MCM-41 mesoporous materials: An investigation of adsorption of pyridine Original Research Article
Pages 459-466
Nong-Yue He, Chun Yang, Zu-Hong Lu

Acid properties of ammonium exchanged AlMCM-41 with different Si/Al ratio Original Research Article
Pages 467-472
Antonio S. Araujo, Cristiane D.R. Souza, Marcelo J.B. Souza, Valter J. Fernandes Jr, Luiz A.M. Pontes

Kinetic evaluation of the pyrolysis of high density polyethylene over H-AlMCM-41 material Original Research Article
Pages 473-478
Antonio S. Araújo, Valter J. Fernandes, Sulene A. Araujo, Massao Ionashiro

Electrorheological response of mesoporous materials under applied electric fields Original Research Article
Pages 479-486
Min S. Cho, Hyoung J. Choi, Wha-Seung Ahn, Myung S. Jhon

Synthesis and characterization of TiO2 loaded Cr-MCM-41 catalysts Original Research Article
Pages 487-494
E.P. Reddy, Lev Davydov, Panagiotis G. Smirniotis

Photocatalytic ethylene polymerization over chromium containing mesoporous molecular sieves Original Research Article
Pages 495-502
Hiromi Yamashita, Katsuhiro Yoshizawa, Masao Ariyuki, Shinya Higashimoto, Masakazu Anpo

Catalytic reduction of nitric oxide on Al-containing mesoporous molecular sieves Original Research Article
Pages 503-510
W. Li, Y. Zhang, Y. Lin, X. Yang

Catalytic oxidation of alpha-eicosanol to alpha-eicosanoic acid over Ti, Zr and Mn doped MCM-48 molecular sieves Original Research Article
Pages 511-516
Changping Wei, Yining Huang, Qiang Cai, Wenqin Pang, Yingli Bi, Kaiji Zhen

Preparation of Pd/Al-MCM-41 catalyst and its hydroisomerization properties for long chain alkane compounds Original Research Article
Pages 517-524
Shui Lin, Han Ning, Sun Wan-Fu, Liu Wei-Min, Xue Qun-Ji

Alkylation of phenol with methyl tert-butyl ether over mesoporous material catalysts Original Research Article
Pages 525-530
Xiang-Hai Tang, Xin-Liang Fu, Hai-Yan Jiang

Isopropanol dehydration over nanostructured sulfated MCM-41 Original Research Article
Pages 531-536
Antonio S. Araujo, Joana.M.F.B. Aquino, Cristiane D.R. Souza, Marcelo J.B. Souza

Effects of Si/Al ratio and pore size on cracking reaction over mesoporous MCM-41 Original Research Article
Pages 537-542
Wen-Hua Chen, Qi Zhao, Hong-Ping Lin, Chung-Yuan Mou, Shang-Bin Liu

Hydrogenation and mild hydrocracking of synthetic crude distillate by Pt-supported mesoporous material catalysts Original Research Article
Pages 543-552
Hong Yang, Craig Fairbridge, Zbigniew Ring, Randall Hawkins, Josephine M. Hill

Carbon-carbon bond forming reactions catalyzed by meso- and microporous silicate-quaternary ammonium composite Original Research Article
Pages 553-560
Yoshihiro Kubota, Yusuke Nishizaki, Hisanori Ikeya, Junko Nagaya, Yoshihiro Sugi

A selectivity of zeolite matrices in the Cu(II) reduction process Original Research Article
Pages 561-568
Vitalii Petranovskii, Valerij Gurin, Nina Bogdanchikova, Miguel-Angel Hernandez, Miguel Avalos

Reduction of binary silver-copper ion mixture in mordenite: an example of synergetic behavior Original Research Article
Pages 569-574
Vitalii Petranovskii, Nina Bogdanchikova

Preparation, characterization and catalytic properties of CuPC/Y nano-composite Original Research Article
Pages 575-582
Huaixin Yang, Ruifeng Li, Kechang Xie

Environmental applications of self-assembled monolayers on mesoporous supports (SAMMS) Original Research Article
Pages 583-590
Glen E. Fryxell, Yuehe Lin, Hong Wu, Kenneth M. Kemner

A possible use of modified mesoporous molecular sieves in water treatment processes Original Research Article
Pages 591-598
Izabela Nowak, Barbara Kasprzyk, Maria Ziolek, Jacek Nawrocki

Organized mesoporous titanium dioxide—A powerful photocatalyst for the removal of water pollutants Original Research Article
Pages 599-606
Jiří Rathouský, Markéta Slabová, Kateřina Macounová, Arnošt Zukal

Mesoporous materials for heavy metal ion adsorption synthesized by displacement of polymeric template Original Research Article
Pages 607-614
V. Antochshuk, M. Jaroniec, S.H. Joo, R. Ryoo

Organically-modified mesoporous silica spheres with MCM-41 architecture as sorbents for heavy metals Original Research Article
Pages 615-622
M. Etienne, S. Sayen, B. Lebeau, A. Walcarius

NO and NO2 gas sensors based on surface photovoltage system fabricated by self-ordered mesoporous silicate film Original Research Article
Pages 623-630
Hao-Shen Zhou, Takeo Yamada, Keisuke Asai, Itaru Honma, Hidekazu Uchida, Teruaki Katsube

Polymerisations in mesoporous environments Original Research Article
Pages 631-633
James Clark, Duncan Macquarrie, Valerie Sage, Katie Shorrock, Karen Wilson

Incorporation of nano-sized zeolites into a mesoporous matrix, TUD-1 Original Research Article
Pages 635-640
Z. Shan, W. Zhou, J.C. Jansen, C.Y. Yeh, J.H. Koegler, Th. Maschmeyer

Formation and stabilization of gold nanoparticles in organo-functionalized MCM-41 mesoporous materials and their catalytic applications Original Research Article
Pages 641-646
Chitta Ranjan Patra, Anirban Ghosh, Priyabrata Mukherjee, Murali Sastry, Rajiv Kumar

Entrapment and stabilization of cadmium sulphide (CdS) nanoclusters formed inside propylthiol functionalized MCM-41 mesoporous materials Original Research Article
Pages 647-652
Anirban Ghosh, Chitta Ranjan Patra, Priyabrata Mukherjee, Murali Sastry, Rajiv Kumar

SnO2 nanoparticles in the pores of non-structured SiO2 and Si-MCM-41: Comparison of their properties in gas sensing Original Research Article
Pages 653-660
Yücel Altindag, Andrei Jitianu, Michael Wark

Spontaneous nitride formation in the reaction of mesoporous titanium oxide with bis(toluene) titanium in a nitrogen atmosphere Original Research Article
Pages 661-668
M. Vettraino, X. He, Michel Trudeau, David Antonelli

Isolation and characterization of amorphous solids from oil sands fine tailings Original Research Article
Pages 669-674
Abdul Majid, Steve Argue, Irina Kargina, Victor Boyko, Gerry Pleizier, Jim Tunney

Author index
Pages 675-678

Subject index
Pages 679-682