Nanoporous Materials II, Proceedings of the 2nd Conference on Access in Nanoporous Materials

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The first symposium on Access in Nanoporous Materials was held in Lansing, Michigan on June 7-9, 1995. The five years that have passed since that initial meeting have brought remarkable advances in all aspects of this growing family of materials. In particular, impressive progress has been achieved in the area of novel self-assembled mesoporous materials, their synthesis, characterization and applications. The supramolecular self-assembly of various inorganic and organic species into ordered mesostructures became a powerful method for synthesis of mesoporous molecular sieves of tailored framework composition, pore structure, pore size and desired surface functionality for advanced applications in such areas as separation, adsorption, catalysis, environmental cleanup and nanotechnology.In addition to mesostructured metal oxide molecular sieves prepared through supramolecular assembly pathways, clays, carbon molecular sieves, porous polymers, sol-gel and imprinted materials, as well as self-assembled organic and other zeolite-like materials, have captured the attention of materials researchers around the globe.The contents of the current volume present a sampling of more than 150 oral and poster papers delivered at the Symposium on Access in Nanoporous Materials II held in Banff, Alberta on May 25-30, 2000. About 70% of the papers are devoted to the synthesis of siliceous mesoporous molecular sieves, their modification, characterization and applications, which represent the current research trend in nanoporous materials. The remaining contributions provide some indications on the future developments in the area of non-siliceous molecular sieves and related materials. This book reflects the current trends and advances in this area, which will certainly attract the attention of materials chemists in the 21st century.

Author(s): Abdelhamid Sayari and Mietek Jaroniec (Eds.)
Series: Studies in Surface Science and Catalysis 129
Edition: 1
Publisher: Elsevier Science
Year: 2000

Language: English
Pages: 1-889

Content:
Preface
Page xv
Abdel Sayari, Mietek Jaroniec, Thomas J. Pinnavaia

Organizing committee
Page xvi

International advisory committee
Page xvi

A novel approach to polymer-template mesoporous molecular sieves Original Research Article
Pages 1-6
Kai Schumacher, Sabine Renker, Klaus K. Unger, Ralph Ulrich, Alexander Du Chesne, Hans W. Spiess, Ulrich Wiesner

Synthesis of uniform and stable millimeter-sized mesoporous silica ropes by the addition of polymer and ammonia hydrothermal treatment Original Research Article
Pages 7-14
Hong-Ping Lin, Lu-Yi Yang, Chung-Yuan Mou, Huang-Kuei Lee, Shang-Bin Liu

The Synthesis and Characterization of Mesoporous Molecular Sieves MCM-41 with Interconnected Channels Original Research Article
Pages 15-22
Hong-Ping Lin, She-Tin Wong, Shang-Bing Liu, Chung-Yuan Mou, Chih-Yuan Tang

Synthesis of mesoporous silica molecular sieves via a novel templating scheme Original Research Article
Pages 23-30
Xiaoming Zhang, Zhaorong Zhang, Jishuan Suo, Shuben Li

Preparation of spherical micrometric MSU-X mesoporous silica particles for chromatography applications Original Research Article
Pages 31-36
Cédric Boissière, André Larbot, Eric Prouzet

Synthesis of Nanometer-sized Mesoporous Silica and Alumina Spheres Original Research Article
Pages 37-43
Qian Luo, Li Li, Zhiyuan Xue, Dongyuan Zhao

Assembly of nanoporous silica via amphoteric surfactant templating scheme Original Research Article
Pages 45-48
Jing Xin, Xiaoming Zhang, Zhaorong Zhang, Jishuan Suo

Formation of Integrated MCM-41 Mesostructure in Fluoride Medium: An Improvement of Hydrothermal Stability Original Research Article
Pages 49-56
Q.-H. Xia, K. Hidajat, S. Kawi

New way to synthesize MCM-41 and MCM-48 materials with tailored pore sizes Original Research Article
Pages 57-66
J.L. Blin, G. Herrier, C. Otjacques, Bao-Lian Su

Poly(oxyethylene) oleyl ethers as templating agents for the synthesis of large pore mesoporous materials Original Research Article
Pages 67-74
J.L. Blin, G. Herrier, Bao-Lian Su

Pore size engineering of mesoporous silicas using alkanes as swelling agents Original Research Article
Pages 75-84
J.L. Blin, C. Otjacques, G. Herder, Bao-Lian Su

Improvement of Hydrothermal Stability of Mesoporous Molecular Sieves of MCM-41 Type Original Research Article
Pages 85-92
Debasish Das, Chou-Mei Tsai, Soofin Cheng

Improvement on thermal stability and acidity of mesoporous materials with post-treatment of phosphoric acid Original Research Article
Pages 93-98
L.-M. Huang, Q.-Z. Li

In situ Synthesis of Micro- and Mesoporous Al-MFI / MCM-41 like Phases with High Hydrothermal Stability. Original Research Article
Pages 99-106
Arne Karlsson, Michael Stöcker, Karin Schäfer

Microwave Synthesis of Micro-Mesoporous Composite Material Original Research Article
Pages 107-116
D.S. Kim, S.-E. Park, S.O. Kang

Preparation of Y/MCM-41 composite materials Original Research Article
Pages 117-120
Ruifeng Li, Weibin Fan, Jianming Ma, Kechang Xie

Supported Crystallization of MFI- and FER-type Molecular Sieves on Porous Glasses Original Research Article
Pages 121-130
W. Schwieger, M. Rauscher, R. Mönnig, F. Scheffler, D. Freude

Supercritical Fluid Extraction of Amine Surfactant in Hexagonal Mesoporous Silica (HMS) Original Research Article
Pages 131-138
S. Kawi, A.-H. Goh

Performance of tetraalkylammonium ions during the formation of zeolites from tetraethylorthosilicate Original Research Article
Pages 139-146
C.E.A. Kirschhock, R. Ravishankar, K. Truyens, F. Verspeurt, P.A. Jacobs, J.A. Martens

Study of interactions between silicate species and surfactant micelles in the synthesis of organized mesoporous materials Original Research Article
Pages 147-154
Jörn Frasch, Bénédicte Lebeau, Michel Soulard, Jocl Patarin, Raoul Zana

Novel ordered mesoporous materials with hybrid organic-inorganic network in the frameworks Original Research Article
Pages 155-162
S. Inagaki, S. Guan, Y. Fukushima, T. Ohsuna, 0. Terasaki

Synthesis and Catalytic Application of Organically Modified Ti-MCM-41 Type Materials Original Research Article
Pages 163-168
Naoko lgarashi, Satoshi Kidani, Rizwan-Ahemaito, Takashi Tatsumi

Influence of silylation on the catalytic activity of Ti-MCM-41 during epoxidation of olefins. Original Research Article
Pages 169-178
A. Corma, J.L. Jordá, M.T. Navarro, J. Pérez-Pariente, F. Rey, J. Tsuji

Synthesis and Modification of Ti-containing Catalysts for Epoxidation of Alkene Original Research Article
Pages 179-186
Jie Bu, Hyun-Ku Rhee

Synthesis and adsorption properties of cerium modified MCM-41 Original Research Article
Pages 187-194
Antonio S. Araujo, Mietek Jaroniec

Microwave Synthesis of Zr (Ti)-Si-Al HDN Catalytic Material Original Research Article
Pages 195-200
Sun Wanfu, Ma Bo, Suo Jisuan, Li Shuben, Luo Xihui, Jiang Zongxuan

Characterization of mesoporous and microporous molecular sieves containing niobium and tantalum Original Research Article
Pages 201-208
Martin Hartmann, Stefan Ernst, A.M. Prakash, Larry Kevan

Direct incorporation of A1 in SBA mesoporous materials: characterization, stability and catalytic activity Original Research Article
Pages 209-218
Y.-H. Yue, A. Gédéon, J.-L. Bonardet, J.B. d'Espinose, N. Melosh, J. Fraissard

Post-synthesis alumination of MCM-41 by A1(NO3)3 (I): improvement in acidity for purely siliceous MCM-41 Original Research Article
Pages 219-226
S. Kawi, S.C. Shen

Post-synthesis alumination of Si-MCM-41 by A1(NO3)3 (II): Enhancement of hydrothermal, mechanical and chemical stabilities Original Research Article
Pages 227-234
S. Kawi, S.C. Shen

Siting of Co(II), Zn(II) and Cu(i) ions in (A1)MCM-41 Original Research Article
Pages 235-242
J. Ddeěek, N. Zilková, J. Cejka

Reversible transition of the coordination of A1 in MCM-41 Original Research Article
Pages 243-250
H. Kosslick, H. Landmesser, R. Fricke, W. Storek

Functionalised mesoporous materials for green chemistry Original Research Article
Pages 251-264
James H. Clark, Duncan J. Macquarrie, Karen Wilson

Peculiarities of alkyl-modification of ordered mesoporous materials: A single-step treatment of uncalcined MCM-41 involving template removal and surface functionalization Original Research Article
Pages 265-274
Valentyn Antochshuk, Mietek Jaroniec

New organically modified hexagonal mesoporous silicas: Preparation and applications in catalysis Original Research Article
Pages 275-282
Duncan J Macquarrie, Dominic B Jackson, Stephane Tailland, Karen Wilson, James H Clark

Organo-functionalized surface modified MCM-41 type mesoporous materials having various organic functional groups Original Research Article
Pages 283-286
Priyabrata Mukherjee, Subhash Laha, Deendayal Mandai, Rajiv Kumar

Phenyl-functionalized silicate mesophases with hexagonal or cubic symmetries: influence of synthesis parameters. Original Research Article
Pages 287-294
Valérie Goletto, Marianne Imperor, Florence Babonneau

Covalent attachment of dye molecules to the inner surface of MCM-41 Original Research Article
Pages 295-302
Yven Rohlfing, Dieter Wöhrle, Michael Wark, Günter Schulz-Ekloff, Jiri Rathousky, Arnost Zukal

Preparation and Characterization of Metal-Chalcogenide/MCM-41 Complexes Original Research Article
Pages 303-310
C.M. Kowalchuk, Y. Huang, J.F. Corrigan

Studies on immobilization of Co(II)-La(III) schiff base complex in MCM-41 Original Research Article
Pages 311-316
Binbin Fan, Ruifeng Li, Zhihong Liu, Jinghui Cao, Bing Zhong

The use of alkylchlorosilanes as coupling agents for the synthesis of stable, hydrophobic, surfactant extracted MCM-48/VOx catalysts. Original Research Article
Pages 317-326
P. Van Der Voort, E.F. Vansant

Epoxidation over niobium and titanium grafted MCM-41 and MCM-48 mesoporous molecular sieves. Original Research Article
Pages 327-334
M.P. Kapoor, Anuj Raj

Titanium iso-propoxide grafting on M41S type hosts : catalytic and adsorption study Original Research Article
Pages 335-340
K.K. Kang, C.S. Byun, W.S. Ahn

Ternary transition metal oxides within mesoporous MCM-48 silica phases: Synthesis and characterization Original Research Article
Pages 341-348
R. Köhn, F. Brider, M. Fröba

The inclusion of polymeric carbon in channels of the siliceous MCM-41 mesoporous molecular sieve Original Research Article
Pages 349-356
J. Hlavatý, L. Kavan, J. Rathousky, A. Zukal

On the Way to New Nanoporous Transition Metal Oxides Original Research Article
Pages 357-366
Olaf Muth, Michael Fröba

First synthesis of mesostructured hexagonal germanium sulfides using gemini surfactants Original Research Article
Pages 367-374
Nadine Oberender, Michael Fröba

Synthesis and characterization of mesostructured molybdenum sulfides with intercalated cationic surfactants Original Research Article
Pages 375-382
Jie-Sheng Chen, Ying Wang, Ru-Ren Xu

Synthesis and characterization of novel mesostructured tungsten sulfides Original Research Article
Pages 383-390
Charles Liu, Amy Ferryman, Julia E.Fulghum, Songping D. Huang

The mesopores developed during boronation of zeolites β Original Research Article
Pages 391-399
Chun Yang, Qinhua Xu

Mesostructured clay catalysts: a new porous clay heterostructure (PCH) derived from synthetic saponite Original Research Article
Pages 401-408
Mihai Polverejan, Yu Liu an, Thomas J.Pinnavaia

A1-modified porous clay heterostructures with combined micro and mesoporosity Original Research Article
Pages 409-416
P. Cool, J. Ahenach, O. Collart, E.F. Vansant

Mesoporous synthetic clays: synthesis, characterization, and use as HDS catalyst supports Original Research Article
Pages 417-424
K.A. Carrado, L. Xu, C.L. Marshall, D. Wei, S. Seifert, C.A.A. Bloomquist

Techniques for Tailoring the Pore Structure of SiO2-TiO2 Sol Pillared Clays Original Research Article
Pages 425-434
H.Y. Zhu, Z. Ding, G.Q. Lu

Porous Smectite-type Materials Containing Catalytically Active Divalent Cations in Octahedral Sheets Original Research Article
Pages 435-442
M. Shirai, K. Aoki, Y. Minato, K. Torii, M. Arai

LDH-Surfactant Composite Nanoribbons Original Research Article
Pages 443-450
P.C. Pavan, L.P. Cardoso, E.L. Crepaldi, J.B. Valim

Synthesis and characterization of a new Sn-incorporated CoAl-layered double hydroxide (LDH) and catalytic performance of Co-spinel microcrystallites in the partial oxidation of methanol Original Research Article
Pages 451-458
S. Velu, K. Suzuki

Construction strategies for new generation micro-porous solids Original Research Article
Pages 459-466
Ian D. Williams, Stephen S-Y. Chui, Samuel M-F. Lo, Mingmei Wu, John A. Cha, Teresa S-C. Law, Herman H-Y. Sung, Fanny L-Y. Shek, Jenny L. Gao, Tolulope M. Fasina

Preparation effects on titania-sulfate aerogel morphology Original Research Article
Pages 467-474
J. Mrowiec-Bialoń, L. Pajak, A.B. Jarzebski, A.I. Lachowski

Distribution of Pt clusters in SiO2 and TiO2 nanotubes Original Research Article
Pages 475-482
Michael Wark, Christina Hippe, Günter Schulz-Ekloff

Catalytic formation of carbon nanotubes on Fe-loading molecular sieves materials: an XPS study Original Research Article
Pages 483-490
N.Y. He, C. Yang, P.F. Xiao, G.H. Wang, Y.J. Zhao, Z.H. Lu, C.W. Yuan

Probing the pore space in mesoporous solids with NMN spectroscopy and magnetic resonance microimaging Original Research Article
Pages 491-499
S.R. Breeze, S.J. Lang, A.V. Nosov, A. Sanchez, I.L. Moudrakovski, C.I. Ratcliffe, J.A. Ripmeester

Characterization of mesoporous molecular sieves: differences between M41s and pillared layered zeolites Original Research Article
Pages 501-508
Wieslaw J. Roth, James C. Vartuli, Charles T. Kresge

Magnetic Resonance Microimaging Studies of Porous Petroleum Coke Original Research Article
Pages 509-516
Eric B. Brouwer, Igor Moudrakovski, Keng H. Chung, Gerald Pleizier, John A.Ripmeester, Yves Deslandes

Effect of pore size on the adsorption of xenon on mesoporous MCM-41 and on the 129Xe NMR chemical shifts: a variable temperature study Original Research Article
Pages 517-524
Wen-Hua Chen, Hong-Ping Lin, Jin-Fu Wu, Sung-Jeng Jong, DgChung-Yuan Mou, Shang-Bin Liu

What does TEM tell us about mesoporous silicas Original Research Article
Pages 525-534
W. Zhou

Transmission electron microscopy — an indispensable tool for the characterisation of M41S-type materials. Original Research Article
Pages 535-542
Patricia J.Kooyman, Michel J.Verhoef, Eric Prouzet

SEM and TEM investigations of macroporous and toroidal mesostructured transition metal oxides Original Research Article
Pages 543-549
D. Antonelli, M. Trudeau

1H, 2H and 29Si solid state NMR study of guest acetone molecules occupying the zeolitic channels of partially dehydrated sepiolite clay Original Research Article
Pages 551-558
M. R.Weir, G. A.Facey, C. Detellier

In-situ small angle x-ray scattering (SAXS) studies on the formation of mesostructured aluminophosphate / surfactant composite materials Original Research Article
Pages 559-566
M. Tiemann, M. Fröba, G. Rapp, S.S. Funari

Thermogravimetric characterization of mesoporous molecular sieves Original Research Article
Pages 567-576
Michal Kruk, Abdelhamid Sayari, Mietek Jaroniec

Self-consistent determination of the lamellar phase content in MCM-41 using X-ray diffraction, nitrogen adsorption and thermogravimetry Original Research Article
Pages 577-586
Michal Kruk, Mietek Jaroniec, Yong Yang, Abdelhamid Sayari

Recent advances in adsorption characterization of mesoporous molecular sieves Original Research Article
Pages 587-596
Mietek Jaroniec, Michal Kruk, Abdelhamid Sayari

Calculations of pore size distributions in nanoporous materials from adsorption and desorption isotherms Original Research Article
Pages 597-606
Peter I. Ravikovitch, Alexander V. Neimark

Determination of pore size distribution of mesoporous materials by regularization Original Research Article
Pages 607-615
C.G. Sonwane, S.K. Bhatia

The sorption of n-butyl and tert-butyl alcohols by phenyl-modified porous silica Original Research Article
Pages 617-622
Claire M. Bambrough, Robert C.T. Slade, Ruth T.Williams

Change of reorientational-vibrational relaxation upon capillary condensation in silica mesopores Original Research Article
Pages 623-632
H. Tanaka, S. Inagaki, Y. Fukishima, K. Kaneko

Characterisation of microporous materials by dynamic sorption methods Original Research Article
Pages 633-638
F. Thielmann, D.A. Butler, D.R. Williams, E. Baumgarten

Diffusion of high molecular weight hydrocarbons in mesostructured materials of the MCM-41 type Original Research Article
Pages 639-648
D.S. Campos, M. Eic, Ml Occelli

Modeling single-component permeation through a zeolite membrane from atomic-scale principles Original Research Article
Pages 649-654
David S. Sholl

Adsorption and transport of polyatomic species in one-dimensional systems: exact forms of the thermodynamic functions and chemical diffusion coefficient Original Research Article
Pages 655-664
A.J. Ramirez-Pastor, F. Roma, A. Aligia, V.D. Pereyra, J.L. Riccardo

Mechanical Strength of Micelle-Templated Silicas (MTS) Original Research Article
Pages 665-672
Delphine Desplantier-Giscard, Olivier Collart, Anne Galameau, Pascal Van Der Voort, Francesco Di Renzo, FranÇois Fajula

Structural analysis of hexagonal mesoporous silica films produced from triblock-copolymer-structuring sol-gel Original Research Article
Pages 673-682
D. Grosso, A.R. Balkenende, P.A. Albouy, F. Babonneau

On structure/property-relations in nanoporous semiconductors of the cetineite-type Original Research Article
Pages 683-690
U. Simon, J. Jockel, F. Starrost, E.E. Krasovskii, W. Schattke, B. Marier, S. Schunk, M. Wark, H. Wellmann

Structural and textural properties of zinc(II)-chromium(III) spinel oxides prepared using a hydrotalcite-like compound Original Research Article
Pages 691-700
E.L. Crepaldi, P.C. Pavan, W. Jones, J.B. Valim

New porous composite material — characterization and properties Original Research Article
Pages 701-710
A.N. Scian, M. Marturano, V. Cagnoli

Stabilized cluster formation of supercritical Xe in carbon nanopores Original Research Article
Pages 711-720
M. Aoshima, T. Suzuki, K. Kaneko

Adsorption of halocarbons in nanoporous materials: current status and future challenges Original Research Article
Pages 721-728
C. Mellot Draznieks, J. Eckert, A.K. Cheetham

Synthesis and Applications of Functionalized Nanoporous Materials for Specific Adsorption Original Research Article
Pages 729-738
J. Liu, G.E. Fryxell, S. Mattigod, T.S. Zemanian, Y. Shin, L.-Q. Wang

Non-electrostatic surfactant assembly routes to functionalized nanostructured silica: prospects for environmental applications Original Research Article
Pages 739-746
L. Mercier

The Use of Mesoporous Silica in Liquid Chromatography. Original Research Article
Pages 747-755
Karl W. Gallis, Andrew G. Eklund, Sara T. Jull, James T. Araujo, Joseph G. Moore, Christopher C. Landry

Pressure swing adsorption of butanone on silica MCM-41 Original Research Article
Pages 757-764
S. Namba, M. Aikawa, K. Takeuchi, D. Yomoda, Y. Inoue, S. Aoki, J. Izumi

Mercury-Sorption Characteristics of Nanoscale Metal Sulfides Original Research Article
Pages 765-772
G.A. Moore, P.J. Martellaro, E.S. Peterson

New Chiral Hybrid Organic-Inorganic Mesoporous Materials for Enantioselective Epoxidation. Original Research Article
Pages 773-780
D. Brunei, P. Sutra, F. Fajula

The Direct Enantioselective Synthesis of Diols from Olefins using Hybrid Catalysts of Chiral Salen Cobalt Complexes Immobilized on MCM-41 and Titanium-containing Mesoporous Zeolite Original Research Article
Pages 781-788
Geon Joong Kim, Dae Woon Park, Wha Seung Ahn, Dong Wha Park

Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in MCM-41. Part I. Original Research Article
Pages 789-796
Douglas S. Shephard

Nano-Clusters, Enantioselective Catalysis and Molecular Recognition Contrast Agents in MCM-41. Part II. Original Research Article
Pages 797-805
Douglas S. Shephard