During the past decade, monolithic materials in the shape of discs, stacked layers, rolled sheets, sponges, irregular chunks, tubes, and cylinders have all been successfully demonstrated. These formats were prepared from a wide variety of materials including natural polymers such as cellulose, synthetic polymers that involved porous styrene-, methacrylate-, and acrylamide-based polymers, and inorganic materials, mainly silica. Each approach is interesting from the point of view of both preparation and application. Although the current papers and patents concerned with monolithic separation media are quite numerous, the information is scattered throughout a vast number of journals. This book therefore fills the gap in the market for a comprehensive reference book on this subject. Monolithic materials concerns all of the current formats of monolithic materials and provides an integrated view of this novel format of separation media. Since the flow pattern in monolithic devices is different from that in packed beds, the hydrodynamics of the system and mass transport differ considerably from those derived for packed columns. Therefore, this book presents contributions concerned with both flow and mass transfer in the monolithic materials. A significant proportion of the book is devoted to the applications of monolithic materials. It also provides the reader with valuable information about the sources of the specific materials, their properties, and potential applications. ?·Monolithic materials are currently very popular within several scientific areas such as chromatography, optics, catalysis, diagnostics, genomics, proteomics, and microfluidics. ?·Provides valuable information about the sources of the specific materials, their properties, and potential applications. ?·Chapters written by leading experts in the area.
Author(s): František àvec, Tatiana B. Tennikova and Zdeněk Deyl (Eds.)
Series: Journal of Chromatography Library 67
Edition: 1
Publisher: Elsevier Science
Year: 2003
Language: English
Pages: 1-773
Tags: Физика;Физика твердого тела;
Content:
Preface
Pages V-VI
František àvec, Zdeněk Děyl, Tatiana B. Tennikova
List of Contributors
Pages VII-XI
Chapter 1 Historical Review Review Article
Pages 1-15
František àvec, Tatiana B. Tennikova
Chapter 2 Rigid Macroporous Organic Polymer Monoliths Prepared by Free Radical Polymerization Review Article
Pages 19-50
František àvec, Jean M.J. Fréchet
Chapter 3 Short Monolithic Columns — Rigid Disks Review Article
Pages 51-75
Miloš Barut, Aleš Podgornik, Mojca Merhar, Aleš àtrancar
Chapter 4 Tubes Review Article
Pages 77-101
Aleš Podgornik, Miloš Barut, Igor MiheliČ, Aleš àtrancar
Chapter 5 Rigid Polymers Prepared by Ring-Opening Metathesis Polymerization Review Article
Pages 103-120
Michael R. Buchmeiser
Chapter 6 Monolithic Polysaccharide Materials Review Article
Pages 121-141
Per-Erik Gustavsson, Per-OlofLars Son
Chapter 7 Monolithic Continuous Beds Prepared from Water-Soluble Acrylamide-Based Monomers Review Article
Pages 143-172
Audrius Maruška
Chapter 8 Monolithic Silica Columns for Capillary Liquid Chromatography Review Article
Pages 173-196
Nobuo Tanaka, Masanori Motokawa, Hiroshi Kobayashi, Ken Hosoya, Tohru Ikegami
Chapter 9 Monolithic Columns Prepared from Particles Review Article
Pages 197-211
Qinglin Tang, Milton L. Lee
Chapter 10 Layered Stacks Review Article
Pages 213-234
Mark R. Etzel
Chapter 11 Biotextiles — Monoliths with Rolled Geometrics Review Article
Pages 235-253
Jeremiah Bwatwa, Yiqi Yang, Chenghong Li, Craig Keim, Christine Ladisch, Michael Ladisch
Chapter 12 Polymerized High Internal Phase Emulsion Monoliths Review Article
Pages 255-276
Neil R. Cameron
Chapter 13 Imprinted Monoliths Review Article
Pages 277-300
Borje Sellergren
Chapter 14 Ordered Inorganic Structures Review Article
Pages 301-322
Peidong Yang
Chapter 15 Flow and Mass Transfer Review Article
Pages 325-350
Alírio E. Rodrigues, Vera G. Mata, Michal Zabka, Luís Pais
Chapter 16 Theoretical Aspects of Separation using Short Monolithic Beds Review Article
Pages 351-371
Tatiana B. Tennikova, Frantisek àvec
Chapter 17 Monolithic Stationary Phases for the Separation of Small Molecules Review Article
Pages 373-387
Eric C. Peters, Christer Ericson
Chapter 18 Separation of Peptides and Proteins Review Article
Pages 389-415
Djuro Josić
Chapter 19 Nucleic Acid Analysis Review Article
Pages 417-456
Christian G. Huber, Herbert Oberacher
Chapter 20 Synthetic Polymers Review Article
Pages 457-487
David Sýkora, František àvec
Chapter 21 Capillary Electrochromatography Review Article
Pages 489-559
Michael Lämmerhofer, Wolfgang Lindner
Chapter 22 Large Scale Separations Review Article
Pages 561-599
Alois Jungbauer, Rainer Hahn
Chapter 23 Immunoaffinity Assays Review Article
Pages 601-621
Galina A. Platonova, Tatiana B. Tennikova
Chapter 24 Survey of Chromatographic and Electromigration Separations Review Article
Pages 623-658
Ivan Mikšík, Zdeněk Deyl
Chapter 25 Miniature and Microchip Technologies Review Article
Pages 659-685
Yolanda Fintschenko, Brian J. Kirby, Ernest F. Hasselbrink, Anup K. Singh, Timothy J. Shepodd
Chapter 26 Solid-Phase Extraction Review Article
Pages 687-697
Shaofeng Xie, Tao Jiang, František àvec, Robert W. Allington
Chapter 27 Catalysts and Enzyme Reactors Review Article
Pages 699-724
Alois Jungbauer, Rainer Hahn
Chapter 28 Solid Phase Synthesis and Auxiliaries for Combinatorial Chemistry Review Article
Pages 725-743
Alois Jungbauer, Karin Pflegerl
Index of Monolithic Materials Used
Pages 745-764
Index of Compounds Separated
Pages 765-773
