Metal Clusters in Proteins

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Content: Metalloprotein crystallography : survey of recent results and relationships to model studies / William H. Armstrong --
X-ray absorption spectroscopy for characterizing metal clusters in proteins : possibilities and limitations / James E. Penner-Hahn --
Resonance Raman spectroscopy of iron-oxo and iron-sulfur clusters in proteins / Joann Sanders-Loehr --
NMR of paramagnetic systems : magnetically coupled dimetallic systems (Cu₂Co₂superoxide dismutase as an example) / Ivano Bertini, Lucia Banci, and Claudio Luchinat --
Models for copper proteins : reversible binding and activation of dioxygen and the reactivity of peroxo and hydroperoxo dicopper(II) complexes / Zoltan Tyeklar, Phalguni Ghosh, Kenneth D. Karlin, Amjad Farooq, Brett I. Cohen, Richard W. Cruse, Yilma Gultneh, Michael S. Haka, Richard R. Jacobson, and Jon Zubieta --
Oxygen atom transfer reactions at binuclear copper sites / Lawrence D. Margerum, Kazuko I. Liao, and Joan Selverstone Valentine --
Coupled binuclear copper active sites / Edward I. Solomon --
Active sites of binuclear iron-oxo proteins / Lawrence Que, Jr. and Robert C. Scarrow --
Fe(III) clusters on ferritin protein coats and other aspects of iron core formation / Elizabeth C. Theil --
Oxo-iron(III) aggregates : a current perspective / Sergiu M. Gorun --
Involvement of manganese in photosynthetic water oxidation / Gary W. Brudvig --
Structural types in oxide-bridged manganese chemistry : toward a model of the photosynthetic water oxidation center / George Christou and John B. Vincent --
Synthetic strategies for modeling metal-sulfur sites in proteins / B.A. Averill --
Importance of peptide sequence in electron-transfer reactions of iron-sulfur clusters / Akira Nakamura and Norikazu Ueyama --
Double exchange in reduced Fe₃S₄ clusters and novel clusters with MFe₃S₄ cores / E. Münck, V. Papaefthymiou, K.K. Surerus, and J.-J. Girerd --
Variable-temperature magnetic circular dichroism studies of metalloproteins / Michael K. Johnson --
Aconitase : evolution of the active-site picture / Mark H. Emptage --
Nitrogenase : overview and recent results / E.I. Stiefel, H. Thomann, H. Jin, R.E. Bare, T.V. Morgan, S.J.N. Burgmayer, and C.L. Coyle --
Synthetic analogs for the Fe-Mo-S Site in nitrogenase : chemistry of the [Fe₆S₆(L)₆(M(CO)₃)₂]n⁻clusters / D. Coucouvanis.

Author(s): Lawrence Que, Jr. (Eds.)
Series: ACS Symposium Series 372
Publisher: American Chemical Society
Year: 1988

Language: English
Pages: 413
City: Washington, DC