Content: Introduction to macro- and microemulsions / M.K. Sharma and D.O. Shah --
Onset of chaos in the structure of microemulsions / E. Ruckenstein --
Stability of premicellar aggregates in water-in-oil microemulsion systems / Stig E. Friberg, Tony D. Flaim, and Patricia L.M. Plummer --
Viscoelastic detergent solutions from rodlike micelles / H. Hoffmann, H. Rehage, K. Reizlein, and H. Thurn --
Enthalpy of micelle formation of mixed sodium dodecyl sulfate and sodium deoxycholate systems in aqueous media / K.S. Birdi --
Role of the fluidity of the interfacial region in water-in-oil microemulsions / A.M. Cazabat, D. Langevin, J. Meunier, O. Abillon, and D. Chatenay --
Effect of chain length compatibility on monolayers, foams, and macro- and microemulsions / M.K. Sharma, S.Y. Shiao, V.K. Bansal, and D.O. Shah --
Phase diagrams and interactions in oil-rich microemulsions / D. Roux and A.M. Bellocq --
Critical points in microemulsions : role of van der Waals and entropic forces / D. Chatenay, O. Abillon, J. Meunier, D. Langevin, and A.M. Cazabat --
Thermal and dielectric behavior of free and interfacial water in water-in-oil microemulsions / D. Senatra, G.G.T. Guarini, G. Gabrielli, and M. Zoppi --
Macro- and microemulsions in enhanced oil recovery / M.K. Sharma and D.O. Shah --
Role of the middle phase in emulsions / F.M. Fowkes, J.O. Carnali, and J.A. Sohara --
Structural considerations of lamellar liquid crystals containing large quantities of solubilized hydrocarbon alkanes / Anthony J.I. Ward, Stig E. Friberg, and David W. Larsen --
Use of videomicroscopy in diffusion studies of oil-water-surfactant systems / Kirk H. Raney, William J. Benton, and Clarence A. Miller --
Effects of polymers, electrolytes, and pH on microemulsion phase behavior / S. Qutubuddin, C.A. Miller, W.J. Benton, and T. Fort, Jr. --
Influence of temperature on the structures of inverse nonionic micelles and microemulsions / J.C. Ravey and M. Buzier --
Sulfones as unconventional cosurfactants in microemulsions / Reginald P. Seiders --
Transport properties of oil-in-water microemulsions / Kenneth R. Foster, Erik Cheever, Jonathan B. Leonard, Frank D. Blum, and Raymond A. Mackay --
Micellar structure and equilibria in aqueous microemulsions of methyl methacrylate / J.O. Carnali and F.M. Fowkes --
Photochemical reactions in microemulsions and allied systems / S. Atik, J. Kuczynski, B.H. Milosavljevic, K. Chandrasekaran, and J.K. Thomas --
Reaction kinetics as a probe for the dynamic structure of microemulsions / R. Leung, M.J. Hou, C. Manohar, D.O. Shah, and P.W. Chun --
Interfacial phenomena of miniemulsions / C.D. Lack, M.S. El-Aasser, J.W. Vanderhoff, and F.M. Fowkes --
Stability and stabilization of water-in-oil-in-water multiple emulsions / Alexander T. Florence and Douglas Whitehill --
Emulsion breaking in electrical fields / A. Kriechbaumer and R. Marr --
Stabilization of xylene in sulfapyridine-stabilized water emulsion : evaluation and role of van der Waals and Coulombic forces / V.K. Sharma and S.N. Srivastava --
Formation and stability of water-in-oil-in-water emulsions / Sachio Matsumoto --
Use of macroemulsions in mineral beneficiation / Brij M. Moudgil --
Kinetics of xylene coagulation in water emulsion stabilized by phthalylsulfathiazole / S. Raghav and S.N. Srivastava --
Colloidal stability : comparison of sedimentation with sedimentation flocculation / D.H. Melik and H.S. Fogler --
Rheology of concentrated viscous crude oil-in-water emulsions / Yein Ming Lee, Sylvan G. Frank, and Jacques L. Zakin.
Author(s): Dinesh O. Shah (Eds.)
Series: ACS Symposium Series 272
Publisher: American Chemical Society
Year: 1985
Language: English
Pages: 496
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Introduction to Macro- and Microemulsions......Page 9
Mechanism of Macroemulsion Formation......Page 10
Stability of Macroemulsions......Page 13
Mechanism of Microemulsion Formation......Page 18
Stability and Structural Aspects of Microemulsions......Page 20
Literature Cited......Page 24
2 Onset of Chaos in the Structure of Microemulsions......Page 27
Qualitative Considerations......Page 29
Basic Thermodynamic Equations......Page 31
The Origin of the Middle Phase Microemulsion and of its Structure......Page 34
Discussion of The NMR Experiments in Single Phase Microemulsions......Page 36
Concluding Remarks......Page 37
Literature Cited......Page 38
3 Stability of Premicellar Aggregates in Water-in-Oil Microemulsion Systems......Page 39
Results and Comments......Page 40
Literature Cited......Page 45
4 Viscoelastic Detergent Solutions from Rodlike Micelles......Page 46
Materials and Methods......Page 48
Results......Page 51
Discussion......Page 60
Conclusions......Page 69
Literature Cited......Page 70
Materials and Methods......Page 72
Discussion......Page 74
Conclusions......Page 76
Literature Cited......Page 79
Light Scattering Data and Critical Consolute Point......Page 80
Electrical Conductivity......Page 83
Transient Electrical Birefringence Data (23)......Page 85
Conclusion......Page 89
Literature Cited......Page 91
7 Effect of Chain Length Compatibility on Monolayers, Foams, and Macro- and Microemulsions......Page 92
Experimental......Page 93
Results and Discussion......Page 94
Literature Cited......Page 108
8 Phase Diagrams and Interactions in Oil-Rich Microemulsions......Page 109
Experimental study: phase diagrams of the water-dodecane-pentanol (or hexanol)-sodium dodecyl sulfate (SDS) systems......Page 110
Discussion......Page 116
Literature Cited......Page 122
Description of the system......Page 123
Interfacial properties......Page 124
Bulk properties......Page 128
Complementary results......Page 130
Study of an oil free system......Page 132
Conclusion......Page 133
Literature Cited......Page 136
10 Thermal and Dielectric Behavior of Free and Interfacial Water in Water-in-Oil Microemulsions......Page 137
Materials and Methods......Page 138
Results......Page 140
Conclusion......Page 150
Literature Cited......Page 151
11 Macro- and Microemulsions in Enhanced Oil Recovery......Page 153
Enhanced Oil Recovery By Microemulsion Flooding......Page 154
Macroemulsions in Enhanced Oil Recovery Processes......Page 163
Literature Cited......Page 174
12 Role of the Middle Phase in Emulsions......Page 177
Experimental Details......Page 178
Experimental Results and Discussion......Page 180
Acknowledgments......Page 185
Literature Cited......Page 187
13 Structural Considerations of Lamellar Liquid Crystals Containing Large Quantities of Solubilized Hydrocarbon Alkanes......Page 188
Results & Discussion......Page 189
Literature Cited......Page 195
14 Use of Videomicroscopy in Diffusion Studies of Oil-Water-Surfactant Systems......Page 196
Materials and Methods......Page 198
Results......Page 201
Discussion......Page 218
Conclusions......Page 223
Literature Cited......Page 225
15 Effects of Polymers, Electrolytes, and pH on Microemulsion Phase Behavior......Page 226
Materials and Methods......Page 228
Results and Discussion......Page 231
Conclusions......Page 249
Literature Cited......Page 252
16 Influence of Temperature on the Structures of Inverse Nonionic Micelles and Microemulsions......Page 255
Materials and Methods......Page 256
Results......Page 259
Literature Cited......Page 264
17 Sulfones as Unconventional Cosurfactants in Microemulsions......Page 266
Methods and Materials......Page 267
Results and Discussion......Page 268
Acknowledgments.......Page 273
Literature Cited......Page 274
18 Transport Properties of Oil-in-Water Microemulsions......Page 275
Materials and Methods......Page 276
Theoretical......Page 277
Results......Page 278
Discussion......Page 282
Conclusions......Page 284
Literature Cited......Page 286
19 Micellar Structure and Equilibria in Aqueous Microemulsions of Methyl Methacrylate......Page 287
Materials and Methods......Page 288
Experimental Results......Page 290
Discussion......Page 295
Acknowledgments......Page 301
Literature Cited......Page 302
20 Photochemical Reactions in Microemulsions and Allied Systems......Page 303
Experimental......Page 304
Results and Discussion......Page 305
Literature Cited......Page 323
21 Reaction Kinetics as a Probe for the Dynamic Structure of Microemulsions......Page 325
Experimental......Page 326
Results and Discussions......Page 328
Acknowledgments......Page 342
Literature Cited......Page 343
22 Interfacial Phenomena of Miniemulsions......Page 345
Interfacial Tension Theory......Page 346
Materials and Methods......Page 347
Results and Discussion......Page 348
Conclusions......Page 353
Literature Cited......Page 355
23 Stability and Stabilization of Water-in-Oil-in-Water Multiple Emulsions......Page 357
Multiple emulsion types......Page 359
Surfactants......Page 360
Stability and release mechanism......Page 364
(a) Osmotic effects......Page 366
(b) Interfacial effects......Page 368
Properties of the primary emulsion......Page 369
Attempts to improve the stability of multiple emulsions......Page 370
Conclusions......Page 374
Literature Cited......Page 377
24 Emulsion Breaking in Electrical Fields......Page 379
Theory of Stability......Page 380
Coalescence in Electrical Fields......Page 381
Materials......Page 384
Technical Applications......Page 394
Literature Cited......Page 395
25 Stabilization of Xylene in Sulfapyridine-Stabilized Water Emulsion Evaluation and Role of van der Waals and Coulombic Forces......Page 397
Theoretical......Page 398
Results and Discussion......Page 402
Conclusion......Page 406
Literature Cited......Page 411
26 Formation and Stability of Water-in-Oil-in-Water Emulsions......Page 412
Formation of W/O/W Emulsions......Page 413
Thinning of Oil Layer......Page 418
Water Permeability of Oil Layers......Page 424
Stability of W/O/W Emulsions......Page 427
Literature Cited......Page 432
27 Use of Macroemulsions in Mineral Beneficiation......Page 434
Electronic Ore Sorting......Page 435
Emulsion Flotation......Page 438
Liquid-Liquid Extraction......Page 440
Summary......Page 441
Literature Cited......Page 442
28 Kinetics of Xylene Coagulation in Water Emulsion Stabilized by Phthalylsulfathiazole......Page 443
Theoretical......Page 444
Effect of Cationic detergents on Coalescence......Page 447
Kinetics of Coagulation of the system under investigation......Page 451
Literature Cited......Page 456
29 Colloidal Stability: Comparison of Sedimentation with Sedimentation Flocculation......Page 457
Theory......Page 459
Results and Discussion......Page 463
Summary......Page 465
Literature Cited......Page 466
30 Rheology of Concentrated Viscous Crude Oil-in-Water Emulsions......Page 467
Experimental......Page 468
Theoretical......Page 470
(1) Stability......Page 472
D. Effect of the Nature of Crude Oil......Page 477
Discussion......Page 478
Conclusions......Page 480
Literature Cited......Page 483
Author Index......Page 484
A......Page 485
C......Page 486
D......Page 487
F......Page 488
I......Page 489
M......Page 490
Ρ......Page 492
R......Page 493
S......Page 494
V......Page 495
Ζ......Page 496
