Content: Lasers, chemistry, and combustion / David R. Crosley --
Laser probes for combustion applications / J.R. McDonald --
Laser-induced fluorescence spectroscopy in flames / John W. Daily --
Laser probes of premixed laminar methane-air flames and comparsion with theory / James H. Bechtel --
Laser-induced fluorescence : a powerful tool for the study of flame chemistry / C.H. Muller, III, Keith Schofield, and Martin Steinberg --
Laser-induced fluorescence spectroscopy applied to the hydroxyl radical in flames / M.J. Cottereau and D. Stepowski --
A multilevel model of response to laser-fluorescence excitation in the hydroxyl radical / Anthony J. Kotlar, Alan Gelb, and David R. Crosley --
Saturated-fluorescence measurements of the hydroxyl radical / Robert P. Lucht, D.W. Sweeney, and N.M. Laurendeau --
Nitric oxide detection in flames by laser fluorescence / Daniel R. Grieser and Russell H. Barnes --
Laser-induced fluorescence of polycyclic aromatic hydrocarbons in a flame / Donald S. Coe and Jeffrey I. Steinfeld --
Flow visualization in supersonic flows / N.L. Rapagnani and Steven J. Davis --
What really does happen to electronically excited atoms in flames? / Kermit C. Smyth, Peter K. Schenck, and W. Gary Mallard --
Collisional ionization of sodium atoms excited by one- and two-photon absorption in a hydrogen-oxygen-argon flame / C.A. Van Dijk and C. Th. J. Alkemade --
On saturated fluorescence of alkali metals in flames / C.H. Muller, III, Martin Steinberg, and Keith Schofield --
Saturation broadening in flames and plasmas as obtained by fluorescence excitation profiles / N. Omenetto, J. Bower, J. Bradshaw, S. Nikdel, and J.D. Winefordner --
Determination of flame and plasma temperatures and density profiles by means of laser-excited fluorescence / J. Bradshaw, S. Nikdel, R. Reeves, J. Bower, N. Omenetto, and J.D. Winefordner --
Raman-scattering measurements of combustion properties / Marshall Lapp --
Temperature from rotational and vibrational Raman scattering : effects of vibrational-rotational interactions and other corrections / Michael C. Drake, Chamnong Asawaroengchai, and Gerd M. Rosenblatt --
Temperature-velocity correlation measurements for turbulent diffusion flames from vibrational Raman-scattering data / S. Warshaw, Marshall Lapp, C.M. Penney, and Michael C. Drake --
Observations of fast turbulent mixing in gases using a continuous-wave laser / C.M. Penney, S. Warshaw, Marshall Lapp, and Michael Drake --
A Nd:YAG laser multipass cell for pulsed Raman-scattering diagnostics / Domenic A. Santavicca --
Time-resolved Raman spectroscopy in a stratified-charge engine / J. Ray Smith --
Spatially precise laser diagnostics for practical combustor probing / Alan C. Eckbreth --
CARS measurements in simulated practical combustion environments / Gary L. Switzer, William M. Roquemore, Royce P. Bradley, Paul W. Schreiber, and Won B. Roh --
Update on CARS diagnostics of reactive media at ONERA / M. Péalat, B. Attal, S. Druet, and J.P. Taran --
The application of single-pulse nonlinear Raman techniques to a liquid photolytic reaction / William G. Von Holle and Roy A. McWilliams --
Detailed modelling of combustion : a noninterfering diagnostic tool / Elaine S. Oran, Jay P. Boris, and M.J. Fritts --
Rate of methane oxidation controlled by free radicals / John R. Creighton --
The detailed modelling of premixed, laminar, steady-state flames : results for ozone / Joseph M. Heimerl and T.P. Coffee --
On the rate of the O + N₂ reaction / Daniel J. Seery and M.F. Zabielski --
Reactions of C₂ (X¹ [sigma]g) and (a³ [pi]u) produced by multiphoton UV excimer laser photolysis / Louise R. Pasternack, J.R. McDonald, and V.M. Donnelly --
Pulsed-laser studies of the kinetics of C₂O(Ã3[pi]i and X̃³[sigma]⁻) / V.M. Donnelly, William M. Pitts, and A.P. Baronavski --
Kinetics of CH radical reactions important to hydrocarbon combustion systems / J.E. Butler, J.W. Fleming, L.P. Goss, and M.C. Lin --
Carbon monoxide laser resonance absorption studies of O(3P) + 1-alkynes and methylene radical reactions / W.M. Shaub and M.C. Lin --
Absorption spectroscopy of combustion gases using a tunable IR diode laser / R.K. Hanson, P.L. Varghese, S.M. Schoenung, and P.K. Falcone --
Multiangular absorption measurements in a methane diffusion jet / Robert J. Santoro, H.G. Semerjian, P.J. Emmerman, R. Goulard, and R. Shabahang --
Temperature measurement in turbulent flames via Rayleigh scattering / Robert W. Dibble, R.E. Hollenbach, and G.D. Rambach --
Droplet-size measurements in reacting flows by laser interferometry / Umberto Ghezzi, Aldo Coghe, and Fausto Gamma --
Continuous-wave intracavity dye laser spectroscopy : dependence of enhancement on pumping power / Stephen J. Harris --
The use of photoacoustic spectroscopy to characterize and monitor soot in combustion processes / D.K. Killinger, J. Moore, and S.M. Japar.
Author(s): David R. Crosley (Eds.)
Series: ACS Symposium Series 134
Publisher: American Chemical Society
Year: 1980
Language: English
Pages: 468
City: Washington, D.C
Tags: Топливно-энергетический комплекс;Топливо и теория горения;Исследования процессов горения и взрыва;
Title Page......Page 1
Half title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Lasers, Chemistry, and Combustion......Page 9
Laser Combustion Probes......Page 10
Modelling and Kinetics......Page 15
Laser-Induced Fluorescence in OH......Page 18
Literature Cited......Page 23
2 Laser Probes for Combustion Applications......Page 25
Coherent Anti-Stokes Raman Spectroscopy......Page 26
Conclusions......Page 60
Literature Cited......Page 63
3 Laser-Induced Fluorescence Spectroscopy in Flames......Page 65
Theoretical Considerations......Page 66
Detectability and Dynamic Range......Page 75
Applications......Page 81
Summary and Conclusions......Page 85
Literature Cited......Page 86
4 Laser Probes of Premixed Laminar Methane-Air Flames and Comparsion with Theory......Page 88
Experimental Apparatus and Methods......Page 89
Experimental results......Page 95
Acknowledgments......Page 101
Literature Cited......Page 104
Experimental......Page 106
Fluorescence Measurements......Page 109
Results......Page 112
Discussion......Page 122
Acknowledgments......Page 128
Literature Cited......Page 133
Theory......Page 134
[OH] measurement......Page 136
Literature cited......Page 139
Optical Saturation in Laser-Induced Fluorescence......Page 140
The Multilevel Model......Page 141
Results......Page 142
Literature Cited......Page 147
Frozen Excitation Model......Page 148
Experimental System and Results......Page 151
IV. Literature Cited......Page 154
9 Nitric Oxide Detection in Flames by Laser Fluorescence......Page 155
Literature Cited......Page 160
10 Laser-Induced Fluorescence of Polycyclic Aromatic Hydrocarbons in a Flame......Page 161
Results......Page 162
Acknowledgement......Page 165
References......Page 167
Theory:......Page 168
Experiment:......Page 169
Results and Discussions:......Page 170
References:......Page 173
12 What Really Does Happen to Electronically Excited Atoms in Flames?......Page 174
Literature Cited......Page 180
13 Collisional Ionization of Sodium Atoms Excited by One- and Two-Photon Absorption in a Hydrogen-Oxygen-Argon Flame......Page 181
ACKNOWLEDGMENT......Page 185
LITERATURE CITED......Page 186
14 On Saturated Fluorescence of Alkali Metals in Flames......Page 187
Literature Cited.......Page 192
15 Saturation Broadening in Flames and Plasmas As Obtained by Fluorescence Excitation Profiles......Page 193
References:......Page 196
Concepts and Methods......Page 197
REFERENCES......Page 201
17 Raman-Scattering Measurements of Combustion Properties......Page 202
Raman Scattering Diagnostics......Page 207
Recent Results for pdf Data......Page 212
Literature Cited......Page 223
Rotational Raman Scattering......Page 226
Summary......Page 230
Literature Cited......Page 232
19 Temperature-Velocity Correlation Measurements for Turbulent Diffusion Flames from Vibrational Raman-Scattering Data......Page 233
Literature Cited......Page 240
20 Observations of Fast Turbulent Mixing in Gases Using a Continuous-Wave Laser......Page 241
Literature Cited......Page 247
21 A Nd:YAG Laser Multipass Cell for Pulsed Raman-Scattering Diagnostics......Page 248
Literature Cited......Page 251
22 Time-Resolved Raman Spectroscopy in a Stratified-Charge Engine......Page 252
References......Page 260
23 Spatially Precise Laser Diagnostics for Practical Combustor Probing......Page 262
Coherent Anti-Stokes Raman Spectroscopy (CARS)......Page 263
Saturated Laser Fluorescence......Page 283
Acknowledgements......Page 289
Literature Cited......Page 290
24 CARS Measurements in Simulated Practical Combustion Environments......Page 293
Literature Cited......Page 300
Development of CARS Spectrometer......Page 301
Resonance CARS......Page 305
Literature Cited......Page 308
Theory......Page 309
Results......Page 310
Discussion......Page 312
Literature Cited......Page 317
27 Detailed Modelling of Combustion: A Noninterfering Diagnostic Tool......Page 318
Problems in Modelling Reactive Flows......Page 320
Choosing an Algorithm Based on the Physics of the Problem......Page 327
Testing the Model Against Theoretical Results......Page 331
Testing the Model with Experiment......Page 335
Conclusion......Page 339
Literature Cited......Page 341
28 Rate of Methane Oxidation Controlled by Free Radicals......Page 343
Literature Cited......Page 349
29 The Detailed Modelling of Premixed, Laminar, Steady-State Flames. Results for Ozone......Page 350
Literature Cited......Page 358
30 On the Rate of the Ο + N2 Reaction......Page 359
Literature Cited......Page 364
Experiment......Page 365
Results......Page 367
Discussion......Page 369
Literature Cited......Page 371
PART 1: C2O(Ã3IIi) Fluorescence Lifetimes and Quenching Rate Constants......Page 372
Summary......Page 374
Summary......Page 376
Literature Cited......Page 379
Kinetics......Page 380
Comments on CH + N2......Page 382
Literature Cited......Page 384
O(3P) + 1-Alkynes......Page 385
Reactions of CH2 with O(3P), O2 and CO2......Page 388
Literature Cited......Page 391
Experimental Arrangement......Page 392
Absorption Theory......Page 394
Room Temperature Cell Experiments......Page 396
Flat Flame Burner Experiments......Page 397
Acknowledgements......Page 404
Literature Cited......Page 405
36 Multiangular Absorption Measurements in a Methane Diffusion Jet......Page 406
Experiment......Page 407
Results......Page 409
Literature Cited......Page 412
37 Temperature Measurement in Turbulent Flames Via Rayleigh Scattering......Page 413
38 Droplet-Size Measurements in Reacting Flows by Laser Interferometry......Page 420
Literature Cited......Page 426
39 Continuous-Wave Intracavity Dye Laser Spectroscopy: Dependence of Enhancement on Pumping Power......Page 427
Literature Cited......Page 430
Experimental......Page 432
Results......Page 433
Literature Cited......Page 437
A......Page 438
C......Page 439
D......Page 443
E......Page 444
F......Page 445
G......Page 448
H......Page 449
I......Page 450
L......Page 451
M......Page 454
N......Page 456
O......Page 457
P......Page 458
Q......Page 459
R......Page 460
S......Page 462
T......Page 465
V......Page 467
Y......Page 468
