Content: Surfactant association structures / Stig E. Friberg and Tony Flaim --
Radical pair reactions in micellar solution in the presence and absence of magnetic fields / Nicholas J. Turro, Jochen Mattay, and Gary F. Lehr --
Light-induced electron transfer reactions of metalloporphyrins and polypyridyl ruthenium complexes in organized assemblies / D.G. Whitten, R.H. Schmehl, T.K. Foreman, J. Bonilha, and W.M. Sobol --
Aspects of artificial photosynthesis : the role of potential gradients in promoting charge separation in the presence of surfactant vesicles / Mohammad S. Tunuli and Janos H. Fendler --
Control of photosensitized electron transfer reactions in organized interfacial systems : vesicles, water-in-oil microemulsions, and colloidal silicon dioxide particles / Itamar Willner, Colja Laane, John W. Otvos, and Melvin Calvin --
Photochemistry on colloidal silica solutions / J. Wheeler and J.K. Thomas --
Efficient water cleavage by visible light in colloidal solutions of bifunctional redox catalysts / Michael Grätzel --
The use of cationic surfactants in electrochemistry and catalysis on platinum / Thomas C. Franklin, Maurice Iwunze, and Stephen Gipson --
Reactions of long-chain acidato complexes of transition metals in micelles and microemulsions / G. Mattney Cole, Jr. --
Chemical reactions in water-in-oil microemulsions / Alvoro Gonzalez, John Murphy, and Smith L. Holt --
Inorganic reactions in microemulsions / R.A. Mackay, N.S. Dixit, and R. Agarwal --
The hydrolysis of chlorophyll a in detergentless microemulsion media : an initial study in the development of a kinetic model for the geologic transmetalation reactions of porphyrins found in petroleum / David K. Lavallee, Euphemia Huggins, and Shelley Lee --
Reactions on solid potassium permanganate surfaces / Fredric M. Menger --
Photochemical studies of zeolites / Steven L. Suib, Ovidiu G. Bordeianu, Kerry C. McMahon, and Dimitrios Psaras.
Author(s): Smith L. Holt (Eds.)
Series: ACS Symposium Series 177
Publisher: American Chemical Society
Year: 1982
Language: English
Pages: 253
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Surfactant Association Structures......Page 9
Surfactant Systems - A Word of Caution......Page 10
Minimum Water Content......Page 14
Premicellar Aggregates/Inverse Micelles/Liquid Crystals......Page 18
Summary......Page 22
Literature Cited......Page 23
2 Radical Pair Reactions in Micellar Solution in the Presence and Absence of Magnetic Fields......Page 26
The Radical Pair Mechanism......Page 27
The Magnetic Isotope Effect......Page 34
CIDNP in Micellar Solution......Page 36
Acknowledgements......Page 40
Literature Cited......Page 43
3 Light-Induced Electron Transfer Reactions of Metalloporphyrins and Polypyridyl Ruthenium Complexes in Organized Assemblies......Page 44
Intramicellar Electron Transfer Quenching......Page 45
Interfacial Electron Transfer Processes in Micellar Solutions......Page 47
Net Chemical Conversion via Selective Scavenging of Porphyrin-Viologen Photoredox Products in Micellar Systems......Page 51
The Use of Extramicellar Probe Luminescence Quenching to Monitor Binding of Charged Substrates to Micelles......Page 53
Literature Cited......Page 56
4 Aspects of Artificial Photosynthesis The Role of Potential Gradients in Promoting Charge Separation in the Presence of Surfactant Vesicles......Page 59
Types of Potentials Associated with Surfactant Vesicles......Page 62
Exploitation of Potentials for Energy and Electron Transfer and Charge Separation in Surfactant Vesicles......Page 66
Conclusion......Page 72
Literature Cited......Page 74
5 Control of Photosensitized Electron Transfer Reactions in Organized Interfacial Systems Vesicles, Water-in-Oil Microemulsions, and Colloidal Silicon Dioxide Particles......Page 77
Photosensitized Electron Transfer Across Bilayer Membranes......Page 83
Photosensitized Electron Transfer in Water-in-Oil Microemulsions......Page 85
Photosensitized Electron Transfer Reactions in SiO2 Colloids......Page 88
Correlation of Quantum Yields with Interfacial Potentials......Page 96
Chemical Utilization of the Photoproducts in the Photodecomposition of Water......Page 98
Literature Cited......Page 100
6 Photochemistry on Colloidal Silica Solutions......Page 102
Experimental......Page 103
Kinetic Data: RuII System......Page 104
Kinetic Studies, PN+ System......Page 108
Intermediates Produced (PN+) System......Page 111
Conclusion......Page 115
Literature Cited......Page 116
7 Efficient Water Cleavage by Visible Light in Colloidal Solutions of Bifunctional Redox Catalysts......Page 117
Light Harvesting Units in Artificial Water Splitting Systems......Page 121
Development of Highly Efficient Hydrogen Producing Catalysts......Page 124
Development of Highly Efficient Oxygen Generating Catalysts......Page 127
Cyclic Water Cleavage by Visible Light......Page 129
Cleavage of Hydrogen Sulfide by Visible Light......Page 136
LITERATURE CITED......Page 139
General Use of Additives......Page 143
The Surfactant Film on the Surface of the Electrode......Page 144
Oxidation of Organic Compounds on the Filmed Surface......Page 145
Electrochemical Synthesis......Page 151
Iodide Oxidation......Page 153
Acknowledgment......Page 156
Literature Cited......Page 158
Acidato Complexes......Page 160
Hydrolysis of Acidato Complexes......Page 161
Discussion......Page 162
Literature Cited......Page 166
10 Chemical Reactions in Water-in-Oil Microemulsions......Page 167
Interfacial Effects......Page 171
Microemulsions in Chemical Synthesis......Page 174
Literature Cited......Page 178
11 Inorganic Reactions in Microemulsions......Page 180
Results and Discussion......Page 181
Acknowledgement......Page 194
Literature Cited......Page 195
Introduction......Page 196
Background......Page 197
Metallation and Transmetallation Reactions......Page 201
Results and Discussion......Page 203
Literature Cited......Page 211
13 Reactions on Solid Potassium Permanganate Surfaces......Page 214
Literature Cited......Page 225
Zeolite Photochemistry......Page 226
Experimental Procedure......Page 228
Results......Page 229
Discussion......Page 234
Literature Cited......Page 238
C......Page 240
E......Page 242
G......Page 243
I......Page 244
M......Page 245
O......Page 246
P......Page 247
Q......Page 248
R......Page 249
S......Page 250
T......Page 251
W......Page 252
Z......Page 253
