Hyperspherical Harmonics: Applications in Quantum Theory

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where d 3 3)2 ( L x - -- i3x j3x j i i>j Thus the Gegenbauer polynomials play a role in the theory of hyper spherical harmonics which is analogous to the role played by Legendre polynomials in the familiar theory of 3-dimensional spherical harmonics; and when d = 3, the Gegenbauer polynomials reduce to Legendre polynomials. The familiar sum rule, in 'lrlhich a sum of spherical harmonics is expressed as a Legendre polynomial, also has a d-dimensional generalization, in which a sum of hyper spherical harmonics is expressed as a Gegenbauer polynomial (equation (3-27»: The hyper spherical harmonics which appear in this sum rule are eigenfunctions of the generalized angular monentum 2 operator A , chosen in such a way as to fulfil the orthonormality relation: VIe are all familiar with the fact that a plane wave can be expanded in terms of spherical Bessel functions and either Legendre polynomials or spherical harmonics in a 3-dimensional space. Similarly, one finds that a d-dimensional plane wave can be expanded in terms of HYPERSPHERICAL HARMONICS xii "hyperspherical Bessel functions" and either Gegenbauer polynomials or else hyperspherical harmonics (equations ( 4 - 27) and ( 4 - 30) ) : 00 ik·x e = (d-4)!!A~oiA(d+2A-2)j~(kr)C~(~k'~) 00 (d-2)!!I(0) 2: iAj~(kr) 2:Y~ (["2k)Y (["2) A A=O ). l). l)J where I(O) is the total solid angle. This expansion of a d-dimensional plane wave is useful when we wish to calculate Fourier transforms in a d-dimensional space.

Author(s): John Avery (auth.)
Series: Reidel Texts in the Mathematical Sciences 5
Edition: 1
Publisher: Springer Netherlands
Year: 1989

Language: English
Pages: 256
Tags: Quantum Physics;Physical Chemistry;Atomic, Molecular, Optical and Plasma Physics;Special Functions

Front Matter....Pages i-xvi
Harmonic Polynomials....Pages 1-10
Generalized Angular Momentum....Pages 11-24
Gegenbauer Polynomials....Pages 25-46
Fourier Transforms in D Dimensions....Pages 47-57
Fock’s Treatment of Hydrogenlike Atoms and its Generalization....Pages 59-76
Many-Dimensional Hydrogenlike Wave Functions in Direct Space....Pages 77-92
Solutions to the Reciprocal-Space Schrodinger Equation for the Many-Center Coulomb Problem....Pages 93-104
Matrix Representations of Many-Particle Hamiltonians in Hyperspherical Coordinates....Pages 105-125
Iteration of Integral Forms of the Schrodinger Equation....Pages 127-139
Symmetry-Adapted Hyperspherical Harmonics....Pages 141-173
The Adiabatic Approximation....Pages 175-188
Back Matter....Pages 189-255