Washington, D.C.: U.S. Dept. of Commerce, National Bureau of Standards, 1968. 54 p.Contents
Foreword
Preface
Acknowledgment
Complex processes and elementary reactions
Neutral oxygen species
Complex chemical system
Shock lube experiment
Thermal decompositions of ozone in static systems
Photolysis of ozone
Electrical discharges
Surface reactions of oxygen atoms sad of ozone
Production of oxygen atoms by other methods
sotopic exchange
Elementary physical reactions
Elementary chemical-physical reactions
Elementary chemical reactions
Definition
List of cases considered in this review.
Side reactions
Purpose of this review
Decomposition of oxygen molecules and recombination of oxygen atoms
Decomposition of molecular oxygen
Recombination of atomic oxygen
Equilibrium constants and rate constant
Recommended values of rate factor
Decomposition of ozone
Mechaniema
a. Other reviews
b. Jahn mechanism
c. Bimolecular mechanism
d. Unimolecular mechanism
e. Benson and Axworthy mechanism
f. Energy chains
g. Photolysis in red light
Observed data
a. Relative efficiency of foreign gases
b. Rate constants for Reaction 1
c. Jahn’s rate constant and the ratio k2/ks3
d. Kate constants for Reaction 2
e. Rate constants for Reaction 3
Interpretation of observed data
a. Equilibrium constants from kinetic data
b. Extended values of k1 and k3
Self-consistent set of elementary rate constants
Isotopic exchange between oxygen species
Discussion
Why does K1=k1/k2 at the low-pressure limit of a unimolecular reaction?
a Mathematical models
b. Physical model as derived from rate of exchange
Summary
References
