Fundamentals and Applications of Chemical Sensors

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Content: Recent advances in chemically sensitive electronic devices / Jay N. Zemel, Jan Van der Spiegel, Thomas Fare, and Jein C. Young --
Recent advances in gas sensors in Japan / Tetsuro Seiyama and Noboru Yamazoe --
Tin oxide microsensors / Shih-Chia Chang and David B. Hicks --
Oxygen desorption and conductivity change of palladium-doped tin(IV) oxide gas sensor / Makoto Egashira, Masayo Nakashima, and Shohachi Kawasumi --
Oxygen sensor using perovskite-type oxides : measurements of electrical characteristics / Yasuhiro Shimizu, Yoshiki Fukuyama, Hiromichi Arai, and Tetsuro Seiyama --
Principles and development of a thick-film zirconium oxide oxygen sensor / Shinji Kimura, Shigeo Ishitani, and Hiroshi Takao --
A solid electrolyte for sulfur dioxide detection : sodium sulfate mixed with rare earth sulfates and silicon dioxide / Nobuhito Imanaka, Gin-ya Adachi, and Jiro Shiokawa --
High-temperature oxygen sensors based on electrochemical oxygen pumping / E.M. Logothetis and R.E. Hetrick --
Microsensor vapor detectors based on coating films of phthalocyanine and several of its metal complexes / W.R. Barger, Hank Wohltjen, Arthur W. Snow, John Lint, and Neldon L. Jarvis --
Chemical microsensors based on surface impedance changes / Stephen D. Senturia --
Schottky-barrier diode and metal-oxide-semiconductor capacitor gas sensors : comparison and performance / S.J. Fonash and Zheng Li --
Amperometric proton-conductor sensor for detecting hydrogen and carbon monoxide at room temperature / Norio Miura, Hiroshi Kato, Noboru Yamazoe, and Tetsuro Seiyama --
Advances in atmospheric gas composition determinations using IR spectroscopy : a fast-response, high-resolution, in situ, CO₂ sensor and a rocket-borne, emission-measurement system / Gail E. Bingham and Allan J. Steed --
Chemically modified electrode sensors / Richard A. Durst and Elmo A. Blubaugh --
Coated-wire ion-selective electrodes / L. Cunningham and H. Freiser --
Chemical sensing using near-IR reflectance analysis / David L. Wetzel --
Electrochemical sensors, sensor arrays, and computer algorithms for detection and identification of airborne chemicals / Joseph R. Stetter --
Amidoxime-functionalized coatings for surface acoustic wave detection of simulant vapors / Neldon L. Jarvis, John Lint, Arthur W. Snow, and Hank Wohltjen --
Selective response of polymeric-film-coated optical waveguide devices to water and toxic volatile compounds / J.F. Giuliani, Neldon L. Jarvis, and Arthur W. Snow --
Microbial sensors for process and environmental control / I. Karube --
Langmuir-Blodgett technology and receptor action in stabilized lipid membranes / U.J. Krull, M. Thompson, and H.E. Wong --
Design of sensitive drug sensors : principles and practice / R.P. Buck and V.V. Cosofret --
Development of subcutaneous-type glucose sensors for implantable or portable artificial pancreas / Kaname Ito, Shoichiro Ikeda, Kaori Asai, Hirotoshi Naruse, Kunitoshi Ohkura, Hidehito Ichihashi, Hideo Kamei, and Tatsuhei Kondo.

Author(s): Dennis Schuetzle and Robert Hammerle (Eds.)
Series: ACS Symposium Series 309
Publisher: American Chemical Society
Year: 1986

Language: English
Pages: 393
City: Washington, DC

Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Recent Advances in Chemically Sensitive Electronic Devices......Page 9
Literature Cited......Page 42
2 Recent Advances in Gas Sensors in Japan......Page 46
The present state of gas sensors in Japan......Page 47
Examples of recently developed sensors......Page 50
Future scope......Page 59
Literature Cited......Page 62
3 Tin Oxide Microsensors......Page 63
Experimental......Page 64
Device Characteristics and Discussion......Page 67
Literature Cited......Page 74
4 Oxygen Desorption and Conductivity Change of Palladium-Doped Tin(IV) Oxide Gas Sensor......Page 76
Oxygen Adsorbates......Page 77
Variation of the TPD Spectrum of Oxygen with Repetition of Heating and Cooling......Page 79
Relation between Oxygen Desorption and Conductivity Change......Page 81
Literature Cited......Page 86
5 Oxygen Sensor Using Perovskite-Type Oxides Measurements of Electrical Characteristics......Page 88
Modification of redox properties......Page 89
Results and discussion......Page 90
Conclusion......Page 103
Literature Cited......Page 105
6 Principles and Development of a Thick-Film Zirconium Oxide Oxygen Sensor......Page 106
Thick Film Zirconia Oxygen Sensor and Measurements......Page 107
Zirconia Oxygen Sensor Model......Page 111
Calculated Results......Page 114
Sensor voltage characteristics of the thick film oxygen sensor.......Page 116
Thick film oxygen sensor with catalytic electrode (when I > 0 ) .......Page 119
Conclusions......Page 123
Legend of Symbols......Page 124
Literature Cited......Page 125
7 A Solid Electrolyte for Sulfur Dioxide Detection Sodium Sulfate Mixed with Rare Earth Sulfates and Silicon Dioxide......Page 126
Experimental......Page 127
Electrical conductivity, phases, and thermal properties.......Page 128
EMF measurements.......Page 131
Literature Cited......Page 139
8 High-Temperature Oxygen Sensors Based on Electrochemical Oxygen Pumping......Page 141
Oxygen Pumping......Page 142
Sensor Designs......Page 146
Concluding Remarks......Page 156
Literature Cited......Page 158
9 Microsensor Vapor Detectors Based on Coating Films of Phthalocyanine and Several of Its Metal Complexes......Page 160
Experimental......Page 161
Results and Discussion......Page 164
Acknowledgments......Page 168
Literature Cited......Page 170
10 Chemical Microsensors Based on Surface Impedance Changes......Page 171
The Floating-Gate Charge-Flow Transistor (CFT)......Page 173
Application to Moisture Measurement with Hydrated Aluminum Oxide Films......Page 176
Discussion......Page 178
Acknowledgments......Page 179
Literature Cited......Page 180
11 Schottky-Barrier Diode and Metal-Oxide-Semiconductor Capacitor Gas Sensors Comparison and Performance......Page 182
Structures and Principles of Operation......Page 183
Performance of Diode-type Structures......Page 190
Performance of Capacitor-type Structures......Page 197
Comparison of Diode-type and Capacitor-type Sensors......Page 204
Summary......Page 205
Literature Cited......Page 207
12 Amperometric Proton-Conductor Sensor for Detecting Hydrogen and Carbon Monoxide at Room Temperature......Page 208
Experimental......Page 209
Results and Discussion......Page 210
Acknowledgments......Page 216
Literature Cited......Page 219
13 Advances in Atmospheric Gas Composition Determinations Using IR Spectroscopy A Fast-Response, High-Resolution, In Situ, CO2 Sensor and a Rocket-Borne, Emission-Measurement System......Page 220
History......Page 221
Absorption-Based Spectroscopy Systems......Page 222
Emission Based Spectroscopy Systems......Page 232
Conclusions......Page 243
Literature Cited......Page 244
14 Chemically Modified Electrode Sensors......Page 248
Surface Immobilization Techniques......Page 249
Mediated Electrocatalysis......Page 251
Polymer-Film Electrodes......Page 252
Bioanalytical Sensors......Page 254
Literature Cited......Page 257
15 Coated-Wire Ion-Selective Electrodes......Page 259
EMF and Selectivity Measurements......Page 265
Literature Cited......Page 273
16 Chemical Sensing Using Near-IR Reflectance Analysis......Page 274
Comparison of Near-Infrared Reflectance Analysis with Classical Spectroscopic Techniques......Page 276
Correlation Techniques For Wavelength Selection......Page 278
Instrumentation For Near-Infrared Sensors......Page 279
Sample Presentation......Page 282
Process Analysis......Page 283
On-Line Monitoring of Granular Materials......Page 284
KSU System of Near-Infrared Reflectance Monitoring in a Pilot Flour Mill......Page 285
Literature Cited......Page 298
17 Electrochemical Sensors, Sensor Arrays, and Computer Algorithms For Detection and Identification of Airborne Chemicals......Page 300
Electrochemical Sensors......Page 301
Sensor Arrays......Page 303
Algorithms......Page 306
Acknowledgments......Page 308
Literature Cited......Page 309
18 Amidoxime-Functionalized Coatings for Surface Acoustic Wave Detection of Simulant Vapors......Page 310
Experimental......Page 311
Results and Discussion......Page 312
Conclusions......Page 318
Literature Cited......Page 320
19 Selective Response of Polymeric-Film-Coated Optical Waveguide Devices to Water and Toxic Volatile Compounds......Page 321
Experimental Results......Page 322
Conclusions......Page 329
Literature Cited......Page 330
20 Microbial Sensors for Process and Environmental Control......Page 331
Microbial Sensors for Fermentation Process......Page 332
Microbial Sensors for Environmental Control......Page 341
Literature Cited......Page 348
21 Langmuir-Blodgett Technology and Receptor Action in Stabilized Lipid Membranes......Page 350
Experimental......Page 351
Results and Discussion......Page 354
Literature Cited......Page 360
22 Design of Sensitive Drug Sensors: Principles and Practice......Page 362
Equilibrium Theory......Page 363
Potential Theory......Page 366
Sensitivity and Selectivity......Page 367
Experimental: Reagents......Page 368
Experimental: Construction of Electrodes......Page 369
Results......Page 370
Literature Cited......Page 371
23 Development of Subcutaneous-Type Glucose Sensors for Implantable or Portable Artificial Pancreas......Page 372
Experimental......Page 373
Results and Discussion......Page 376
Literature Cited......Page 381
Author Index......Page 382
A......Page 383
C......Page 384
D......Page 385
Ε......Page 386
I......Page 387
M......Page 388
O......Page 389
Ρ......Page 390
S......Page 391
Τ......Page 392
Ζ......Page 393