Fly Ash Zeolites: Innovations, Applications, and Directions

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This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike.
In view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.

Author(s): Bhagwanjee Jha, Devendra Narain Singh (auth.)
Series: Advanced Structured Materials 78
Edition: 1
Publisher: Springer Singapore
Year: 2016

Language: English
Pages: XXX, 211
Tags: Characterization and Evaluation of Materials; Industrial Chemistry/Chemical Engineering; Geoengineering, Foundations, Hydraulics; Geotechnical Engineering & Applied Earth Sciences

Front Matter....Pages i-xxx
Introduction....Pages 1-3
Basics of Zeolites....Pages 5-31
Conventional Methods for Synthesis of Fly Ash Zeolites....Pages 33-51
Mechanism of Zeolitization of Fly Ash....Pages 53-62
Novel Techniques for Synthesis and Characterization of Fly Ash Zeolites....Pages 63-137
Major Findings of the Three-Step Activation Technique....Pages 139-189
Applications of Fly Ash Zeolites: Case Studies....Pages 191-202
Path Ahead....Pages 203-205
Back Matter....Pages 207-211