Content: Elastomer-modified epoxy resins in coatings applications / R.S. Drake, D.R. Egan, and W.T. Murphy -- Elastomeric polysiloxane modifiers for epoxy networks : synthesis of functional oligomers and network formation studies / J.S. Riffle, I. Yilgor, C. Tran, G.L. Wilkes, J.E. McGrath, and A.K. Banthia -- Synthesis and analysis of saturated, reactive n-butyl acrylate polymers for use in epoxy resin toughening / S. Gazit and James P. Bell -- Impact performance of epoxy resins with poly(n-butyl acrylate) as the reactive liquid rubber modifier / S. Gazit and James P. Bell -- Synthesis, morphology, and thermal stability of elastomer-modified epoxy resins / William A. Romanchick, John E. Sohn, and Jon F. Geibel -- Polyfunctional chelating agents for improved durability of epoxy adhesion to steel / Anthony J. Denicola, Jr. and James P. Bell -- High performance tris(hydroxyphenyl)methane-based epoxy resins / K.L. Hawthorne and F.C. Henson -- Fast curing epoxy-episulfide resin for uses at room temperature / Wenhsiung Ku and James P. Bell -- Influence of physical aging on the time-dependent properties of network epoxies and epoxy-matrix composites / Eric S.W. Kong -- Effects of impurities on hydrolytic stability and curing behavior / Gary L. Hagnauer and Peter J. Pearce -- Structure-property relations of polyethertriamine-cured bisphenol-A-diglycidyl ether epoxies / Fung-Ming Kong, Connie M. Walkup, and Roger J. Morgan -- Isothermal cure kinetics of an epoxy resin prepreg / Gary L. Hagnauer, Bernard R. Laliberte, and David A. Dunn -- Branching of high molecular weight polyhydroxyethers based on bisphenol-A / S.A. Zahir and S. Bantle -- Characterization and moldability analysis of epoxy reaction injection molding resins / J.S. Osinski and L.T. Manzione -- Water dispersible epoxy-g-acrylic copolymer for container coating / James T.K. Woo, Vincent Ting, James Evans, Carlos Ortiz, Gary Carlson, and Richard Marcinko
Author(s): Ronald S. Bauer (Eds.)
Series: ACS Symposium Series 221
Publisher: American Chemical Society
Year: 1983
Language: English
Pages: 310
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Elastomer-Modified Epoxy Resins in Coatings Applications......Page 9
Elastomer-Modified Epoxy Resin Preparation......Page 10
Elastomer-Modified Epoxy Resin Applications......Page 16
Elastomer-Modified Epoxy Resins - Coatings Background......Page 17
Elastomer Modification......Page 19
Impact Strength......Page 20
Summary......Page 24
Literature Cited......Page 26
2 Elastomeric Polysiloxane Modifiers for Epoxy Networks Synthesis of Functional Oligomers and Network Formation Studies......Page 29
Preparation of the Siloxanolate Equilibration Catalyst......Page 32
Equilibration of Aminopropyl Terminated Disiloxanes......Page 33
Synthesis of Piperazine Terminated Disiloxanes from the Reaction of Carboxy Functional Disiloxane and Aminoethyl Piperazine (AEP)......Page 34
Synthesis of the Modified Epoxy Networks......Page 35
Gel Permeation Chromatography (GPC)......Page 36
ATR-FTIR Investigations......Page 37
Synthesis of Functional Polydimethylsiloxane Oligomers......Page 38
Network Formation Studies......Page 48
ESCA......Page 53
Synthesis of Linear Copolymers......Page 60
Literature Cited......Page 61
3 Synthesis and Analysis of Saturated, Reactive n-Butyl Acrylate Polymers for Use in Epoxy Resin Toughening......Page 63
Background Calculations......Page 65
Results and Discussion......Page 67
Appendix A......Page 72
Appendix C......Page 73
Literature Cited......Page 75
4 Impact Performance of Epoxy Resins with Poly(n-butyl acrylate) as the Reactive Liquid Rubber Modifier......Page 76
Experimental......Page 78
Results and Discussion......Page 79
Conclusions......Page 89
Literature Cited......Page 90
Synthesis......Page 91
Proposed Mechanisms......Page 92
Morphology......Page 95
Thermal Stability......Page 103
Literature Cited......Page 123
6 Polyfunctional Chelating Agents for Improved Durability of Epoxy Adhesion to Steel......Page 125
Coupling Agents......Page 128
Literature Cited......Page 140
7 High Performance Tris(hydroxyphenyl)methane-Based Epoxy Resins......Page 141
Experimental......Page 142
8 Fast Curing Epoxy-Episulfide Resin for Uses at Room Temperature......Page 158
Experimental......Page 159
Results and Discussion......Page 165
Literature Cited......Page 173
Experimental......Page 175
Results and Discussion......Page 178
Conclusion......Page 188
Synopsis......Page 193
Literature Cited......Page 194
10 Effects of Impurities on Hydrolytic Stability and Curing Behavior......Page 196
Experimental......Page 197
Results and Discussion......Page 198
Literature Cited......Page 212
11 Structure—Property Relations of Polyethertriamine-Cured Bisphenol-A-diglycidyl Ether Epoxies......Page 213
Experimental......Page 215
Results and Discussion......Page 217
Conclusions......Page 227
Literature Cited......Page 228
12 Isothermal Cure Kinetics of an Epoxy Resin Prepreg......Page 230
Experimental......Page 231
Results......Page 233
Conclusions......Page 242
Literature Cited......Page 245
13 Branching of High Molecular Weight Polyhydroxyethers Based on Bisphenol-A......Page 246
Experimental......Page 251
Results......Page 253
Discussion......Page 256
Literature Cited......Page 262
14 Characterization and Moldability Analysis of Epoxy Reaction Injection Molding Resins......Page 263
Resin Characterization......Page 266
Resin Moldability......Page 274
List of Symbols......Page 280
Literature Cited......Page 281
15 Water Dispersible Epoxy-g-Acrylic Copolymer for Container Coating......Page 283
Particle Size Data......Page 287
MECHANISM OF GRAFTING......Page 289
Emulsion polymerization using the Epoxy-g-(methacrylic acid-styrene) copolymer as emulsifier.......Page 295
Literature Cited......Page 298
B......Page 301
C......Page 302
E......Page 303
F......Page 304
K......Page 305
P......Page 306
S......Page 308
W......Page 309
X......Page 310
