Content: Emulsification and emulsion polymerization of styrene using mixtures of cationic surfactant and long chain fatty alcohols or alkanes as emulsifiers / A.R.M. Azad, J. Ugelstad, R.M. Fitch, and F.K. Hansen --
The effects of polyvinyl alcohols on the polymerization of vinyl acetate / Alexander S. Dunn, Christopher J. Tonge, and Samir A.B. Anabtawi --
Micellar size effect in emulsion polymerization / Irja Piirma and Pao-Chi Wang --
Interfacial phenomena in emulsion polymerization of polar monomers / V.I. Yeliseyeva and A.V. Zuikov --
Gel-effect in emulsion polymerization of vinyl monomers / N. Friis and A.E. Hamielec --
Emulsion polymerization of multifunctional monomers : preparation of reactive microgels / W. Obrecht, U. Seitz, and W. Funke --
Kinetics and mechanism of the emulsion polymerization of vinyl acetate / M. Nomura, M. Harada, W. Eguchi, and S. Nagata --
Determination of latex particle size from polymerization rates / Carlton G. Force --
Polymerization of acrylonitrile in ultracentrifugal fields / Adolf G. Parts and Enn Elbing --
Radiation induced emulsion polymerization of vinyl chloride / J. Barriac, R. Knorr, E.P. Stahel, and V. Stannett --
Aqueous-phase polymerization of butadiene initated by cobalt (III) acetylacetonate / D.C. Blackley and W.F.H. Burgar --
Emulsion redox copolymerization of vinyl ferrocene / F. Louis Floyd --
Molecular weight development in styrene and methyl methacrylate emulsion polymerization / Howard L. James, Jr. and Irja Piirma --
Molecular weight and molecular weight distribution of polystyrene obtained with suspension polymerization / V.D. Yenalyev and V.I. Melnichenko --
Redox polymerization in emulsion / Henry Warson --
Functional colloidal particles for immunoresearch / S.P.S. Yen, A. Rembaum, R.W. Molday, and W. Dreyer --
Mechanical stability of vinyl chloride homopolymer and copolymer latices / O. Palmgren --
Effect of surfactant structure on the electrodeposition of cationic latexes / E.H. Wagener, S.R. Kurowsky, D.S. Gibbs, and R.A. Wessling --
Effect of viscosity and solubility parameter of a nonreactive liquid additive on the emulsion polymerization of styrene / Donald R. Owen, Donald McLemore, Wan-Li Liu, R.B. Seymour, and William N. Tinnerman --
Viscoelastic properties of acrylic latex interpenetrating polymer networks as broad temperature span vibration damping materials / J.E. Lorenz, D.A. Thomas, and L.H. Sperling --
New developments of crosslinkable emulsion polymers / Henry Warson --
Continuous emulsion polymerization : steady state and transient experiments with vinyl acetate and methyl methacrylate / R.K. Greene, R.A. Gonzalez, and G.W. Poehlein --
Structural framework for modelling emulsion polymerization reactors / K.W. Min and W.H. Ray --
Continuous emulsion polymerization of styrene in a tubular reactor / Mainak Ghosh and T.H. Forsyth --
Modification of polystyrene with polybutadiene and the method of studying morphology of the obtained multiphase high impact systems / V.D. Yenalyev, N.A. Noskova, and B.V. Kravchenko.
Author(s): Irja Piirma and John L. Gardon (Eds.)
Series: ACS Symposium Series 24
Publisher: American Chemical Society
Year: 1976
Language: English
Pages: 413
City: Washington, DC
Title Page
......Page 1
Copyright
......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
1 Emulsification and Emulsion Polymerization of Styrene Using Mixtures of Cationic Surfactant and Long Chain Fatty Alcohols or Alkanes as Emulsifiers......Page 7
Experimental part......Page 8
Results and discussion......Page 9
Acknowledgements......Page 28
Literature cited......Page 29
2 The Effects of Polyvinyl Alcohols on the Polymerization of Vinyl Acetate......Page 30
Results......Page 31
Discussion......Page 36
Literature Cited......Page 38
3 Micellar Size Effect in Emulsion Polymerization......Page 40
I. Micellar Size Measurements.......Page 46
IV. Particle Size Analysis.......Page 47
I. Rates of Polymerization with Recipes of Identical Size of Micelles.......Page 48
II. Rates of Polymerization with Recipes of Constant Surfactant Concentrations but Varying Micellar Size.......Page 53
III. Rates of Polymerization with Recipes of Constant Number of Micelles but Varying Micellar Size.......Page 56
IV. Hypothesis of Micellar Size Effect on Nucleation. Confirmation of the Hypothesis.......Page 60
Conclusions......Page 65
Literature Cited......Page 66
4 Interfacial Phenomena in Emulsion Polymerization of Polar Monomers......Page 68
Experimental procedure......Page 70
Results and Discussion......Page 72
Abstract......Page 85
Literature Cited......Page 86
5 Gel-Effect in Emulsion Polymerization of Vinyl Monomers......Page 88
Emulsion Polymerization Kinetics......Page 89
Simulation of Emulsion Polymerization......Page 94
Limiting Conversions......Page 95
Literature Cited......Page 97
2. Preparation of reactive microgels......Page 98
4. Emulsion polymerization of 1,4-DVB......Page 99
Literature cited......Page 107
Experimental......Page 108
Characteristics of vinyl acetate emulsion polymerization.......Page 110
The role of polymer particles.......Page 115
Proposed reaction model......Page 120
Comparison of experimental and calculated results......Page 122
To conclude......Page 125
Appendix I......Page 126
Literature Cited......Page 127
8 Determination of Latex Particle Size from Polymerization Rates......Page 128
Experimental......Page 129
Results......Page 130
Symbols......Page 132
Calculations......Page 133
Abstract......Page 137
Literature Cited......Page 138
9 Polymerization of Acrylonitrile in Ultracentrifugal Fields......Page 139
Discussion of Coagulation......Page 140
Literature Cited......Page 146
10 Radiation Induced Emulsion Polymerization of Vinyl Chloride......Page 148
Experimental......Page 149
Results......Page 150
Discussion......Page 160
Abstract......Page 165
Literature Cited......Page 167
11 Aqueous-Phase Polymerization of Butadiene Initated by Cobalt (III) Acetylacetonate......Page 168
Materials......Page 170
Experimental Procedure For Polymerisations......Page 171
Results of Polymerisation Experiments......Page 172
Other Experiments......Page 181
Possible Mechanisms for Initiation of Polymerisation......Page 188
Literature Cited......Page 192
12 Emulsion Redox Copolymerization of Vinyl Ferrocene......Page 194
Experimental......Page 195
Characterization of Latices......Page 196
Chromatography......Page 197
Summary......Page 200
Literature Cited......Page 202
13 Molecular Weight Development in Styrene and Methyl Methacrylate Emulsion Polymerization......Page 203
Experimental......Page 204
Results and Discussion......Page 206
Acknowledgements......Page 215
References......Page 216
14 Molecular Weight and Molecular Weight Distribution of Polystyrene Obtained with Suspension Polymerization......Page 217
Thermal polymerization.......Page 218
Initiated polymerization of styrene .......Page 220
LITERATURE CITED:......Page 232
THEORETICAL TRENDS......Page 234
Chloroformic Ester with a Peroxide or a Persulfate......Page 236
DIAZONIUM SALTS IN REDOX SYSTEMS......Page 238
Literature Cited......Page 239
16 Functional Colloidal Particles for Immunoresearch......Page 242
Experimental......Page 243
Methods.......Page 244
Results......Page 253
Conclusions......Page 259
References......Page 262
Experimental......Page 264
Results and discussion......Page 266
Literature cited......Page 279
18 Effect of Surfactant Structure on the Electrodeposition of Cationic Latexes......Page 282
Results......Page 285
Discussion and Conclusions......Page 293
Experimental......Page 297
References......Page 304
Experimental......Page 305
Results and Discussions......Page 306
Literature Cited......Page 311
20 Viscoelastic Properties of Acrylic Latex Interpenetrating Polymer Networks as Broad Temperature Span Vibration Damping Materials......Page 312
Theory of Wide Temperature Span Viscoelastic Damping Materials......Page 313
Creep Behavior of Bulk and Emulsion Polymerized IPN's......Page 314
Damping Material Syntheses......Page 315
DMS Behavior......Page 317
"Millar" IPN's......Page 325
Modeling of DMS Behavior......Page 328
Latex VS Bulk IPN Creep Behavior......Page 329
Conclusions......Page 331
Abstract......Page 334
References......Page 335
Derivatives of Acrylamide......Page 336
Diacetoneacrylamide.......Page 340
The Aminimides.......Page 341
Miscellaneous Nitrogen Compounds.......Page 342
Acrolein.......Page 343
Literature Cited......Page 344
Background......Page 347
Experimental System......Page 349
Experimental Results......Page 350
Discussion of Results......Page 359
Acknowledgements......Page 363
Literature Cited......Page 364
The Mathematical Model......Page 365
Some Example Calculations......Page 369
Literature Cited......Page 372
Experimental......Page 373
Mathematical Model......Page 374
Results and Discussion......Page 376
Conclusions......Page 381
Literature Cited......Page 384
25 Modification of Polystyrene with Polybutadiene and the Method of Studying Morphology of the Obtained Multiphase High Impact Systems......Page 385
Investigation of HIPS morphology.......Page 386
Definition of the residual internal microtension in HIPS.......Page 389
The investigation of mechanism of HIPS microstructure formation.
......Page 392
LITERATURE CITED......Page 401
C
......Page 403
E
......Page 405
I
......Page 406
L
......Page 407
M
......Page 408
P
......Page 409
S
......Page 411
T
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W
......Page 413
