Specialist Periodical Reports provide systematic and critical review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject, the series creates a unique service for the active research chemist with regular critical in-depth accounts of progress in particular areas of chemistry. Subject coverage of all volumes is very similar and publication is on an annual or biennial basis. As EPR continues to find new applications in virtually all areas of modern science, including physics, chemistry, biology and materials science, this series caters not only for experts in the field, but also those wishing to gain a general overview of EPR applications in a given area. Read more... Abstract: Specialist Periodical Reports provide systematic and critical review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject, the series creates a unique service for the active research chemist with regular critical in-depth accounts of progress in particular areas of chemistry. Subject coverage of all volumes is very similar and publication is on an annual or biennial basis. As EPR continues to find new applications in virtually all areas of modern science, including physics, chemistry, biology and materials science, this series caters not only for experts in the field, but also those wishing to gain a general overview of EPR applications in a given area
Author(s): B C Gilbert; Damien M Murphy; Victor Chechik;
Series: Specialist periodical reports
Publisher: Royal Society of Chemistry
Year: 2012
Language: English
Pages: 323
City: Cambridge
Tags: Физика;Практикумы, экспериментальная физика и физические методы исследования;
CONTENTS......Page 8
Preface......Page 6
1. Introduction......Page 12
2. Non-LC nitroxide spin probes in diamagnetic LC hosts......Page 13
3. LC nitroxide spin probes in diamagnetic LC hosts......Page 15
4. Magnetic properties of second-generation of rod-like LC nitroxide radical materials......Page 18
5. Conclusions......Page 30
References......Page 31
1. Introduction......Page 33
2. New and improved methods......Page 34
3. Small open-shell inorganic molecules......Page 35
4. Group 2 elements......Page 38
5. Boron......Page 39
7. Carbon......Page 43
8. Silicon - Lead......Page 44
9. Phosphorus radicals......Page 48
10. Arsenic - Bismuth......Page 52
11. Nitrogen chalcogenides......Page 53
References......Page 61
Introduction......Page 69
Conclusions......Page 87
References......Page 88
1. Areas in which protein disorder is relevant......Page 90
2. Methods......Page 93
3. Examples from the recent literature......Page 99
4. Case studies......Page 101
References......Page 106
1. Introduction......Page 114
2. Quinone processing sites in proteins......Page 116
3. Spectroscopic background......Page 128
4. Interactions of SQ with protons in model systems and proteins......Page 136
5. 14N and 15N 1D and 2D ESEEM spectra......Page 152
6. 13C and 17O labeling in the study of SQ conformation and spin density distribution......Page 169
7. Exploring the spectroscopic data in structural models of SQ-protein interactions......Page 172
References......Page 180
1. Introduction......Page 191
2. Principles of EPR......Page 192
3. Principles of oximetry......Page 193
4. Spin probes......Page 194
6. Principles of imaging......Page 198
7. Biomedical applications of oxygen imaging......Page 207
8. Problems of oximetry......Page 209
Conclusion......Page 213
References......Page 214
1. Introduction......Page 220
2. Background on HFEPR instrumentation......Page 221
3. Background on HFEPR theory......Page 224
4. HFEPR studies of mononuclear transition metal (d Block) coordination complexes......Page 226
5. HFEPR studies of dinuclear transition metal (d block) coordination complexes......Page 241
6. HFEPR studies of polynuclear metal clusters......Page 250
References......Page 261
References and notes......Page 273
1. Introduction......Page 275
2. Spin Hamiltonian......Page 276
3. Overview of current electronic structure methods......Page 277
4. Calculation of SH parameters – the machinery......Page 286
5. Benchmarking studies and applications......Page 298
References......Page 316
