Content: Molecular secondary ion mass spectrometry / Steven J. Pachuta and R. Graham Cooks --
Particle bombardment as viewed by molecular dynamics / Barbara J. Garrison --
Role of intermolecular interactions in the desorption of molecular ions from surfaces / Ronald D. Macfarlane --
Processes of laser-induced ion formation in mass spectrometry / F. Hillenkamp, M. Karas, and J. Rosmarinowsky --
Angle-resolved secondary ion mass spectrometry / Nicholas Winograd --
Secondary ion mass spectrometer design considerations for organic and inorganic analysis / C.W. Magee --
Liquid metal ion sources / Douglas F. Barofsky --
Fast atom bombardment mass spectrometry technique and ion guns / Julius Perel --
Fast atom bombardment secondary ion mass spectrometry surface analysis / J.A. Leys --
Secondary ion mass spectrometry : a multidimensional technique / Richard J. Colton, David A. Kidwell, George O. Ramseyer, and Mark M. Ross --
Fast atom bombardment combined with tandem mass spectrometry for the study of collisionally induced remote charge site decompositions / Nancy J. Jensen, Kenneth B. Tomer, Michael L. Gross, and Philip A. Lyon --
Analysis of reactions in aqueous solution using fast atom bombardment mass spectrometry / Richard M. Caprioli --
Applications of fast atom bombardment in bioorganic chemistry / Dudley H. Williams --
Use of secondary ion mass spectrometry to study surface chemistry of adhesive bonding materials / W.L. Baun.
Author(s): Philip A. Lyon (Eds.)
Series: ACS Symposium Series 291
Publisher: American Chemical Society
Year: 1985
Language: English
Pages: 254
City: Washington, DC
Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
Acknowledgments......Page 6
1 Molecular Secondary Ion Mass Spectrometry......Page 7
Mechanism......Page 13
Tandem Mass Spectrometry (MS/MS)......Page 28
Applications......Page 31
Developing Areas......Page 41
Literature Cited......Page 46
2 Particle Bombardment as Viewed by Molecular Dynamics......Page 49
Mechanisms of Cluster Formation......Page 50
Energy Distributions......Page 52
Matrix Effects......Page 53
Molecular Orientation Effects: Benzene vs. Pyridine......Page 56
Closing Statements......Page 59
Literature Cited......Page 60
3 Role of Intermolecular Interactions in the Desorption of Molecular Ions from Surfaces......Page 62
The Energy Deposition Process......Page 63
The Energy Dispersion Process......Page 64
Polymeric Surfaces as Substrates......Page 65
The Emission-Ionization Process......Page 66
Emission of Massive Molecular Ions From Surfaces......Page 70
Conclusions......Page 72
Literature Cited......Page 73
4 Processes of Laser-Induced Ion Formation in Mass Spectrometry......Page 75
Characteristics of spectra......Page 76
Ion formation mechanisms......Page 77
Wavelength dependence of ion formation......Page 80
Formation of metastable ions......Page 81
Literature Cited......Page 87
5 Angle-Resolved Secondary Ion Mass Spectrometry......Page 89
Angular Distributions of Secondary Ions From Clean Single Crystal Surfaces......Page 90
Angular Distributions of Secondary Ions From Adsorbate Covered Surfaces......Page 92
Angular Distributions of Neutral Atoms Desorbed From Single Crystal......Page 99
Literature Cited......Page 102
6 Secondary Ion Mass Spectrometer Design Considerations for Organic and Inorganic Analysis......Page 103
Inorganic SIMS—Depth Profiling......Page 105
Organic SIMS - Solid Surfaces......Page 107
Organic SIMS - Liquid Surfaces......Page 109
Secondary Ion Optics......Page 110
Future Trends in SIMS Instrumentation......Page 115
Summary......Page 116
Literature Cited......Page 117
7 Liquid Metal Ion Sources......Page 119
Fabrication and operation......Page 120
Investigation of secondary ionization processes......Page 124
Analytical applications......Page 127
Literature cited......Page 128
Background......Page 131
Guns That Produce the Primary Beams......Page 132
Geometry and Mass Spectrometer Limitations......Page 136
Spectrometer Tests......Page 142
Some New and Old Techniques......Page 145
Literature Cited......Page 149
9 Fast Atom Bombardment Secondary Ion Mass Spectrometry Surface Analysis......Page 151
Experimental......Page 152
Results and Discussion......Page 155
Conclusion......Page 162
Literature Cited......Page 165
10 Secondary Ion Mass Spectrometry: A Multidimensional Technique......Page 166
Inorganic SIMS......Page 168
Organic SIMS......Page 179
Literature Cited......Page 196
11 Fast Atom Bombardment Combined with Tandem Mass Spectrometry for the Study of Collisionally Induced Remote Charge Site Decompositions......Page 200
Description of the Phenomenon......Page 201
Literature Cited......Page 213
12 Analysis of Reactions in Aqueous Solution Using Fast Atom Bombardment Mass Spectrometry......Page 215
Acid Dissociation Constants......Page 216
Enzyme Reactions......Page 218
Enzyme Kinetics......Page 219
Literature Cited......Page 222
13 Applications of Fast Atom Bombardment in Bioorganic Chemistry......Page 223
Literature Cited......Page 231
Discussion......Page 233
Chemistry of Adherends......Page 234
Chemistry and Structure of Adhesives......Page 241
SUMMARY......Page 243
Literature Cited......Page 247
Author Index......Page 248
C......Page 249
F......Page 250
L......Page 251
P......Page 252
S......Page 253
T......Page 254
