Deactivation and Testing of Hydrocarbon-Processing Catalysts

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Content: Philosophical overview of testing / Paul O'Connor, Geoffrey L. Woolery, and Toru Takatsuka --
Advantages, possibilities, and limitations of small-scale testing of catalysts for fixed-bed processes / S.T. Sie --
Evaluating pore structure and morphology of hydrocarbon-conversion catalysts / R. Mann, K. Khalaf, and A. Al-Lamy --
Deactivation of zeolite catalysts by coke / T. Masuda and K. Hashimoto --
Modes of coking and deactivation of acid zeolite catalysts / M. Guisnet, P. Magnoux, and K. Moljord --
Catalyst coking, activation, and deactivation / P.A. Sermon, M.S.W. Vong, and M. Matheson --
NMR techniques for studying the coking of zeolite-based catalysts / J.L. Bonardet, M.C. Barrage, and J. Fraissard --
Characterization of fluid catalytic cracking catalyst coke by ¹³C NMR and mass spectrometry / B.J. McGhee, J.M. Andresen, C.E. Snape, R. Hughes, C.L. Koon, and G. Hutchings --
Catalyst decay as a side reaction of the chain processes of catalytic cracking / B.W. Wojciechowski and N.M. Rice --
Catalyst deactivation in fluid catalytic cracking : a review of mechanisms and testing methods / Paul O'Connor, E. Brevoord, A.C. Pouwels, and H.N.J. Wijngaards --
Sodium deactivation of fluid catalytic cracking catalyst / Xinjin Zhao and Wu-Cheng Cheng --
Contaminant-metal deactivation and metal-dehydrogenation effects during cyclic propylene steaming of fluid catalytic cracking catalysts / Lori T. Boock, Thomas F. Petti, and John A. Rudesill --
Catalyst deactivation in adiabatic prereforming : experimental methods and models for prediction of performance / Thomas S. Christensen and Jens Rostrup-Nielsen --
Mechanism of deactivation in reforming catalysts at start of run / Yaofang Liu, Guoqing Pan, and Jiujin Yang --
Catalyst deactivation in commercial residue hydrodesulfurization / Hiroki Koyama, Eiichi Nagai, and Hideaki Kumagai --
Deactivation of light naphtha aromatization catalyst / S. Fukase, N. Igarashi, K. Aimoto, and K. Kato --
Effect of process conditions and catalyst properties on catalyst deactivation in residue hydroprocessing / M. Absi-Halabi and A. Stanislaus --
Catalyst deactivation in hydrodemetallization / J.P. Janssens, A.D. van Langeveld, S.T. Sie, and J.A. Moulijn --
Activity and coking rate of catalysts deactivated by fast-coking species added to the feed / Dady B. Dadyburjor, Zhenyu Liu, Shigeki Matoba, Shinichi Osanai, and Tetsuya Shirooka --
Pilot reactor testing of the effect of naphtha boiling point in catalytic reforming / K. Moljord, K. Grande, I. Tanem, and A. Holmen --
Vanadium mobility in fluid catalytic cracking / Richard F. Wormsbecher, Wu-Cheng Cheng, Gwan Kim, and Robert H. Harding --
Improved methods for testing and assessing deactivation from vanadium interaction with fluid catalytic cracking catalyst / Bruce Lerner and Michel Deeba --
Riser simulator: testing of adsorption effects / Jacek Pruski, Ahmet Pekediz, and Hugo de Lasa --
Development of a bench-scale fluid catalytic cracking microriser / M.P. Helmsing, M. Makkee, and J.A. Moulijn --
Evaluation of coke selectivity of fluid catalytic cracking catalysts / E. Brevoord, A.C. Pouwels, F.P.P. Olthof, H.N.J. Wijngaards, and Paul O'Connor --
Correlation of catalyst performance between laboratory tests and commercial units for hydrotreating residual oil / Yoshimitsu Miyauchi, Takeshi Hashiguchi, Naoto Kimbara, and Katsuhisa Fujita --
Life testing of light hydrocarbon aromatization catalysts / K. Hirabayashi, F. Igarashi, and T. Kondou --
Performance testing of hydroconversion catalysts / W.H.J. Stork --
Development of a test procedure to evaluate fluid catalytic cracking catalyst regenerability / V.L.N. Murthy, S. Debnath, M. Rama Rao, S.K. Ray, A.K. Das, and S. Ghosh --
A catalyst deactivation model for residual oil hydrodesulfurization and application to deep hydrodesulfurization of diesel fuel / Toru Takatsuka, Yukitaka Wada, and Shin-ichi Inoue --
Modeling catalytic deactivation of benzene hydrogenation / Paul F. Meier and Marvin M. Johnson.

Author(s): Paul O'Connor, Toru Takatsuka, and Geoffrey L. Woolery (Eds.)
Series: ACS Symposium Series 634
Publisher: American Chemical Society
Year: 1996

Language: English
Pages: 464
City: Washington, DC

Foreword......Page 5
Contents......Page 6
Preface......Page 10
1. Philosophical Overview of Testing......Page 13
2. Advantages, Possibilities, and Limitationsof Small-Scale Testing of Catalystsfor Fixed-Bed Processes......Page 17
3. Evaluating Pore Structure and Morphology of Hydrocarbon-Conversion Catalysts......Page 52
4. Deactivation of Zeolite Catalysts by Coke......Page 73
5. Modes of Coking and Deactivation of Acid Zeolite Catalysts......Page 88
6. Catalyst Coking, Activation, and Deactivation......Page 102
7. NMR Techniques for Studying the Cokingof Zeolite-Based Catalysts......Page 110
8. Characterization of Fluid Catalytic Cracking Catalyst Coke by 13C NMR and Mass Spectrometry......Page 128
9. Catalyst Decay as a Side Reactionof the Chain Processes of Catalytic Cracking......Page 145
10. Catalyst Deactivation in Fluid Catalytic Cracking......Page 158
11. Sodium Deactivation of Fluid Catalytic Cracking Catalyst......Page 170
12. Contaminant-Metal Deactivation and Metal Dehydrogenation Effects During Cyclic Propylene Steaming of Fluid Catalytic Cracking Catalysts......Page 182
13. Catalyst Deactivation in Adiabatic Prereforming: Experimental Methods and Models for Prediction of Performance......Page 196
14. Mechanism of Deactivation in Reforming Catalysts at Start of Run......Page 211
15. Catalyst Deactivation in Commercial Residue Hydrodesulfurization......Page 218
16. Deactivation of Light Naphtha Aromatization Catalyst......Page 229
17. Effect of Process Conditions and Catalyst Properties on Catalyst Deactivation in Residue Hydroprocessing......Page 239
18. Catalyst Deactivation in Hydrodemetallization......Page 248
19. Activity and Coking Rate of Catalysts Deactivated by Fast-Coking Species Added to the Feed......Page 264
20. Pilot Reactor Testing of the Effect of Naphtha Boiling Point in Catalytic Reforming......Page 278
21. Vanadium Mobility in Fluid Catalytic Cracking......Page 293
22. Improved Methods for Testing and Assessing Deactivation from Vanadium Interaction with Fluid Catalytic Cracking Catalyst......Page 306
23. Riser Simulator: Testing of Adsorption Effects......Page 322
24. Development of a Bench- Scale Fluid Catalytic Cracking Microriser......Page 332
25. Evaluation of Coke Selectivity of Fluid Catalytic Cracking Catalysts......Page 350
26. Correlation of Catalyst Performance Between Laboratory Tests and Commercial Units for Hydrotreating Residual Oil......Page 364
27. Life Testing of Light Hydrocarbon Aromatization Catalysts......Page 377
28. Performance Testing of Hydroconversion
Catalysts......Page 389
29. Development of a Test Procedure To Evaluate Fluid Catalytic Cracking Catalyst Regenerability......Page 411
30. A Catalyst Deactivation Model for Residual Oil Hydrodesulfurization and Applicationto Deep Hydrodesulfurization of Diesel Fuel......Page 424
31. Modeling Catalytic Deactivation of Benzene Hydrogenation......Page 438
Author Index......Page 449
Subject Index......Page 450