Content: Biologically active synthetic anionic polymers / David S. Breslow --
Temperature dependence of cyclization ratios in cyclopolymerization / Marino Guaita --
Intramolecular addition modes in radical cyclopolymerization of some unconjugated dienes / Akira Matsumoto, Kunio Iwanami, Takao Kitamura, Masayoshi Oiwa, and George B. Butler --
Styrene-methyl methacrylate copolymers derived from styrene-methacrylic anhydride copolymers / Daniel L. Neumann and H. James Harwood --
N, N-dimethyl-3,4-dimethylenepyrrolidinium bromide polymer / Raphael M. Ottenbrite --
Radical cyclopolymerization of divinyl formal : polymerization conditions and polymer structure / Mitsuo Tsukino and Toyoki Kunitake --
Divinyl ether-maleic anhydride copolymer and its derivatives : toxicity and immunological and endocytic behavior / L. Gros, H. Ringsdorf, R. Schnee, J.B. Lloyd, E. Rüde, H.U. Schorlemmer, and H. Stötter --
Radical polymerization of exo and endo N-phenyl-5-norbornene-2,3-dicarboximides as models for addition-curing norbornene end-capped polyimides / Norman G. Gaylord and Michael Martan --
Cyclization reaction of N-substituted dimethacrylamides in the crystalline and glassy states at 77 K / T. Kodaira, M. Taniguchi, and M. Sakai --
Mössbauer studies of polymers from 1,1'-divinylferrocene / G.C. Corfield, J.S. Brooks, and S. Plimley --
New phase transfer catalysts containing oxyethylene oligomers / L.J. Mathias and J.B. Canterberry --
Synthesis of macrocyclic ring-containing polymers via cyclopolymerization and cyclocopolymerization / George B. Butler and Qcheng S. Lien --
Radiation-induced loss of unsaturation in 1,2-polybutadiene / Morton A. Golub and Robert D. Cormia --
C3 cyclopolymerization : cationic cyclopolymerization of 1,3-bis(p-vinylphenyl)propane and its derivatives / Jun Nishimura and Shinzo Yamashita --
Free radical polymerization of 2,5-diphenyl-1,5-hexadiene / Luigi Costa and Marino Guaita --
Synthesis and cationic polymerization of 1,4-dimethylenecyclohexane / L.E. Ball, A. Sebenik, and H.J. Harwood --
Acetylene-terminated fluorocarbon ether bibenzoxazole oligomers / Robert C. Evers, George J. Moore, and Jerald L. Burkett --
Initiation of an acetylene-terminated phenyl quinoxaline / M.A. Lucarelli, W.B. Jones, Jr., L.G. Picklesimer, and T.E. Helminiak --
Fracture behavior of an acetylene-terminated polyimide / W.B. Jones, Jr., T.E. Helminiak, C.C. Kang, M.A. Lucarelli, and L.G. Picklesimer --
Synthesis and characteristics of poly(bisdichloromaleimides) / Indra K. Varma, George M. Fohlen, and John A. Parker --
Thermally stable polyimides from pyrrole dicarboxylic acid anhydride monomers / R.W. Stackman --
Triazine ring cross-linked polyimides and refractory materials derived from them / Li-Chen Hsu and Warren H. Philipp --
Heat and water resistant polyphenyl-as-triazines from terephthalamidrazone / Feng-Cai Lu, Lan-Min Xing, and Yu-Lan Wang --
Polycocyclotrimerization of isocyanates / K.H. Hsieh and J.E. Kresta --
Polymerization of bisphthalonitriles : metal free phthalocyanine formation / N.P. Marullo and Arthur W. Snow --
Characterization of the cure of diether-linked phthalonitrile resins / R.Y. Ting, T.M. Keller, T.R. Price, and C.F. Poranski, Jr. --
Polyamides via the phosphorylation reaction : poly-p-benzamide (PBA) and N-methyl PBA copolymers / J. Preston, W.R. Krigbaum, and J. Asrar --
Polymers and fibers of para- and meta-phenylene oxadiazole-N-methyl hydrazide copolymers : high strength-high modulus materials of increased molecular flexibility / Hartwig C. Bach and Helmuth E. Hinderer --
Free radical copolymerization of 4,7-dihydro-1,3-dioxepins with maleic anhydride and maleimides : preparation of head-to-head poly(4-hydroxycrotonic acid) and poly([gamma]-crotonolactone) / B.M. Culbertson and A.E. Aulabaugh --
Synthesis of polyspiroketals containing five-, six-, seven-, and eight-membered rings / William J. Bailey, Charles F. Beam, Jr., Edmund D. Cappuccilli, Ibrahim Haddad, and Angelo A. Volpe --
Hydrogen bonding ring containing polymers : poly(enamine-ketones) / Samuel J. Huang, Brian Benicewicz, and Joseph A. Pavlisko --
Cyclopolymerization of carbon suboxide : mechanism and polymer properties / Nan-Loh Yang, H. Haubenstock, and A. Snow.
Author(s): George B. Butler and Jiri E. Kresta (Eds.)
Series: ACS Symposium Series 195
Publisher: American Chemical Society
Year: 1982
Language: English
Pages: 448
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
Dedication......Page 7
PdftkEmptyString......Page 0
PREFACE......Page 10
Structure......Page 12
Biological Activity......Page 16
Narrow Molecular Weight Distribution Polymer......Page 17
Literature Cited......Page 19
Interaction across the space between reacting groups.......Page 21
Effect of a large substituent at the active chain end.......Page 26
Difference between intra- and intermolecular chain propagation reactions.......Page 27
Comparison between calculated differences ΔSc - ΔSp and experimental differences ΔS≠c - ΔS≠p.......Page 34
Literature cited......Page 37
3 Intramolecular Addition Modes in Radical Cyclopolymerization of Some Unconjugated Dienes......Page 39
Cyclopolymerization of Diallyl and Dimethallyl Dicarboxylates......Page 41
Cyclopolymerization of Allyl ∝-Substituted Acrylates......Page 44
Cyclopolymerization of Acrylic Anhydride......Page 45
Cyclopolymerization of Methacrylic Anhydride......Page 49
Literature Cited......Page 51
4 Styrene-Methyl Methacrylate Copolymers Derived from Styrene-Methacrylic Anhydride Copolymers......Page 53
Experimental......Page 55
Theoretical Aspects......Page 60
Results and Discussion......Page 63
Literature Cited......Page 69
5 N,N-Dimethyl-3,4-Dimethylenepyrrolidinium Bromide Polymer......Page 71
Cyclic Quaternary Ammonium Polymers......Page 72
Polymerization Studies of N,N-dimethyl-3,4-dimethylenepyrrolidinium Bromide......Page 75
Literature Cited......Page 81
6 Radical Cyclopolymerization of Divinyl Formal: Polymerization Conditions and Polymer Structure......Page 83
Experimental......Page 84
Results and Discussion......Page 86
Literature Cited......Page 92
7 Divinyl Ether-Maleic Anhydride Copolymer and Its Derivatives: Toxicity and Immunological and Endocytic Behavior......Page 93
Acute Toxicity of DIVEMA and two DIVEMA Derivatives......Page 94
Effects of DIVEMA and DIVEMA Derivatives on the Immune System.......Page 97
Endocytic Behaviour of DIVEMA and Derivatives......Page 103
Literature Cited......Page 105
8 Radical Polymerization of exo and endo N-Phenyl-5-norbornene-2,3-dicarboximides as Models for Addition-Curing Norbornene End-Capped Polyimides1......Page 107
Results and Discussion......Page 110
Literature Cited......Page 114
9 Cyclization Reaction of N-Substituted Dimethacrylamides in the Crystalline and Glassy States at 77 Κ......Page 116
Experimental......Page 118
Results and Discussion......Page 120
Conclusion......Page 128
Literature Cited......Page 130
10 Mössbauer Studies of Polymers from 1,1'-Divinylferrocene......Page 131
Results and Discussion......Page 133
Literature Cited......Page 144
11 New Phase Transfer Catalysts Containing Oxyethylene Oligomers......Page 146
Experimental......Page 147
Results and Discussion......Page 149
Literature Cited......Page 155
12 Synthesis of Macrocyclic Ring-Containing Polymers Via Cyclopolymerization and Cyclocopolymerization......Page 156
The Synthesis of 1,7-Dienes......Page 157
The Synthesis and Structural Determination of Model Compounds......Page 158
Cyclopolymerization of 1,7-Dienes......Page 160
Cyclopolymerization of 1,13-Dienes......Page 162
Cyclocopolymerization of 1,7-Dienes with Maleic Anhydride......Page 163
Cyclocopolymerization of a 1,13-Diene with MA......Page 166
Experimental......Page 167
Synthesis of Model Compounds......Page 169
Polymerization Studies......Page 170
Literature Cited......Page 172
13 Radiation-Induced Loss of Unsaturation in 1,2-Polybutadiene......Page 173
Experimental......Page 175
Results and Discussion......Page 177
Literature Cited......Page 182
14 C3 Cyclopolymerization: Cationic Cyclopolymerization of 1,3-Bis(p-vinylphenyl)propane and Its Derivatives......Page 183
Preparation of St-C3-St and its Derivatives......Page 184
Structure of Cyclopolymer from St-C3-St or VN-C3-VN......Page 185
Several Effects on the Cyclopolymerization......Page 189
Literature Cited......Page 199
15 Free Radical Polymerization of 2,5-Diphenyl-1,5-hexadiene1......Page 202
Experimental......Page 203
Results and discussion......Page 204
Literature cited......Page 210
16 Synthesis and Cationic Polymerization of 1,4-Dimethylenecyclohexane......Page 212
Polymerization Studies......Page 213
Polymer Characterization......Page 214
Discussion......Page 218
Experimental......Page 223
Literature Cited......Page 225
17 Acetylene-Terminated Fluorocarbon Ether Bibenzoxazole Oligomers......Page 227
Results and Discussion......Page 228
Experimental......Page 235
Literature Cited......Page 239
18 Initiation of an Acetylene-Terminated Phenyl Quinoxaline......Page 240
Influence of Initiator Concentration......Page 241
Residual Exotherm......Page 243
Literature Cited......Page 246
19 Fracture Behavior of an Acetylene-Terminated Polyimide......Page 247
Fracture Testing......Page 248
Literature Cited......Page 254
20 Synthesis and Characteristics of Poly(bisdichloromaleimides)1......Page 255
Experimental......Page 257
Results and Discussion......Page 258
Literature Cited......Page 273
21 Thermally Stable Polyimides from Pyrrole Dicarboxylic Acid Anhydride Monomers......Page 274
Discussion......Page 276
Literature Cited......Page 285
Processable Aromatic Nitrile-Modified Imide Precursors......Page 286
Cyclopolymerization or Polycyclotrimerization......Page 287
TSTR Polyimides with Ring-Chain Structures......Page 288
Experimental......Page 292
Results and Discussion......Page 293
Conclusion......Page 295
Literature Cited......Page 296
23 Heat and Water Resistant Polyphenyl-as-triazines from Terephthalamidrazone......Page 297
Experimental......Page 299
Results and Discussion......Page 302
Literature Cited......Page 309
24 Polycocyclotrimerization of Isocyanates......Page 310
Experimental......Page 311
Characterization of Polycocyclotrimers......Page 312
Results and Discussion......Page 313
Literature Cited......Page 322
25 Polymerization of Bisphthalonitriles: Metal Free Phthalocyanine Formation......Page 324
Discussion and Results......Page 325
Experimental......Page 331
References......Page 334
26 Characterization of the Cure of Diether-Linked Phthalonitrile Resins......Page 335
Experimental......Page 336
Results and Discussion......Page 338
Literature Cited......Page 347
27 Polyamides Via the Phosphorylation Reaction: Poly-p-benzamide (PBA) and N-Methyl PBA Copolymers......Page 349
Discussion and Results......Page 352
Experimental......Page 359
Literature Cited......Page 360
28 Polymers and Fibers of para- and meta-Phenylene Oxadiazole-N-Methyl Hydrazide Copolymers: High Strength-High Modulus Materials of Increased Molecular Flexibility......Page 361
Acknowledgment......Page 366
Literature Cited......Page 367
29 Free Radical Copolymerization of 4,7-Dihydro-1,3-dioxepins with Maleic Anhydride and Maleimides: Preparation of Head-to-Head Poly(4-hydroxycrotonic acid) and Poly(γ-crotonolactone)......Page 368
Literature Cited......Page 386
30 Synthesis of Polyspiroketals Containing Five-, Six-, Seven-, and Eight-Membered Rings......Page 388
Experimental......Page 395
Literature Cited......Page 399
31 Hydrogen Bonding Ring Containing Polymers: Poly(enamine-Ketones)......Page 400
EXPERIMENTAL......Page 401
Monomeric Models......Page 403
Poly(enamine-ketones)......Page 406
Literature Cited......Page 412
32 Cyclopolymerization of Carbon Suboxide: Mechanism and Polymer Properties......Page 414
Experimental......Page 415
Results and Discussion......Page 418
Polymerization......Page 431
Conclusions......Page 434
Literature Cited......Page 435
B......Page 437
C......Page 438
D......Page 440
H......Page 442
K......Page 443
M......Page 444
P......Page 445
S......Page 447
Z......Page 448
