Content: Corrosion : the most general problem of materials science / Donald Tuomi -- Electrochemical techniques in corrosion studies / Francis M. Donahue -- High-temperature corrosion / J. Bruce Wagner, Jr. -- Ionic and electronic conduction in nonmetallic phases / John W. Patterson -- Dissolution of iron / Morris Cohen -- Ferrous passivation / V. Brusic -- Corrosion of valve metals -- J.E. Draley -- The role of water in atmospheric corrosion / P.B.P. Phipps and D.W. Rice -- Corrosion inhibition and inhibitors / Rudolf H. Hausler -- Stress-corrosion cracking / J.C. Scully -- Industrial problems : cooling water and cooling-water treatment / J. Fred Wilkes -- High-temperature corrosion in coal gasification plants / V.L. Hill, D. Yates, and B.A. Humphreys
Author(s): George R. Brubaker and P. Beverley P. Phipps (Eds.)
Series: ACS Symposium Series 89
Publisher: American Chemical Society
Year: 1979
Language: English
Pages: 429
City: Washington
Title Page
......Page 1
Copyright
......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
1 Corrosion: The Most General Problem of Materials Science......Page 6
THE LEAD-ACID STORAGE BATTERY.......Page 19
Part II......Page 24
General References......Page 38
Literature Cited......Page 39
Free Enthalpy Change.......Page 40
Electrode Potential Measurements.......Page 43
Equilibrium Electrode Potentials.......Page 45
Pourbaix Diagrams.......Page 46
Properties of Electrode Reactions.......Page 53
Activation Controlled Electrode Reactions.......Page 55
Transport Controlled Electrode Reactions.......Page 58
Criteria for Control of Electrode Reactions.......Page 62
Mixed Potential Model of Corrosion.......Page 63
Two Activation Controlled Partial Processes.......Page 64
Two Partial Processes - One Under Transport Control.......Page 70
Multiple Partial Process Corrosion Systems.......Page 72
Electrochemical Polarization Systems.......Page 74
Symbols/Nomenclature......Page 78
Literature Cited......Page 79
3 High-Temperature Corrosion......Page 81
Literature Cited......Page 99
Historical Background......Page 101
Physical Processes Occurring During Parabolic Scaling......Page 104
Equivalent Circuit Description of Mixed Conduction in Solids......Page 105
Temperature and Partial Pressure Dependences of Partial Conductivities......Page 110
Capstone Comments on the Open Circuit Theory of Parabolic Oxidation......Page 112
Motivating Factors......Page 115
Fundamental Considerations and the Local Equilibrium Approach......Page 117
Steady State Migration Fluxes in Multicomponent Electrolytes and the Central Problem with Closed Circuit Theory......Page 121
Equivalent Circuit Relations......Page 123
Capstone Comments......Page 127
Acknowlegement......Page 128
Literature Cited......Page 129
Passivity......Page 131
Surface of Metal......Page 132
Application of Thermodynamics......Page 134
Electrochemistry and Corrosion......Page 135
Mechanisms of Reactions......Page 136
Kinetics of Dissolution......Page 139
Passivation of Iron......Page 142
Breakdown of Films......Page 145
Anodic Inhibitors......Page 148
Localized Corrosion......Page 152
Literature Cited......Page 157
Passivation Phenomena......Page 158
A) Thermodynamics of the Active-Passive Transition......Page 171
B) Experimental Approaches of Interest.......Page 173
C) Kinetics and Mechanism of Relevant Reactions - Quantitative Evaluation of the i-V Curve.......Page 175
LITERATURE CITED......Page 187
7 Corrosion of Valve Metals......Page 190
Literature Cited......Page 238
Acknowledgement......Page 239
8 The Role of Water in Atmospheric Corrosion......Page 240
1.0 Observations on Atmospheric Corrosion......Page 241
2.0 Water Adsorption......Page 248
3.0 The Role of Water in Atmospheric Corrosion......Page 263
Acknowledgements......Page 264
Literature Cited......Page 265
9 Corrosion Inhibition and Inhibitors......Page 267
The Corrosion Mechanism......Page 268
Systematic Classification Of Corrosion Inhibitors......Page 271
Experimental Observation of Corrosion Inhibition......Page 274
Effect Of Inhibitors On Polarization Behavior......Page 277
Inhibition By Thiourea And Quinoline Derivatives......Page 282
Acetylenic Inhibitors......Page 293
Corrosion Inhibition In The Presence Of Hydrogen Sulfide......Page 312
Corrosion Of Iron In The Presence Of Hydrogen Sulfide......Page 314
Inhibitor Interaction With The Iron Sulfide Surface......Page 319
Literature Cited
......Page 323
10 Stress-Corrosion Cracking......Page 326
General Features of Stress Corrosion Cracking......Page 327
Testing for Stress Corrosion Susceptibility......Page 329
The Importance of Repassivation......Page 339
The Mechanism of Cracking......Page 345
Preventative Measures......Page 351
Literature Cited......Page 354
11 Industrial Problems: Cooling Water and Cooling-Water Treatment......Page 356
Open Recirculating Cooling Systems......Page 357
Closed Recirculating Cooling Systems......Page 367
Literature Cited
......Page 395
12 High-Temperature Corrosion in Coal Gasification Plants......Page 396
Background......Page 397
Results......Page 398
Acknowledgments......Page 417
Literature Cited......Page 418
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E
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F
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I
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M
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P
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R
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S
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Z
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