The concept of nanoarchitechtonics was introduced to describe the correct manipulation of nanoscale materials in the creation of nano-devices and applications. Nanoarchitectonics has begun to spread into many fields including nanostructured materials synthesis, supramolecular assembly, nanoscale structural fabrications, materials hybridizations, materials and structures for energy and environmental sciences, device and physical application, and bio- and medical applications. Following on from the 2012 title Manipulation of Nanoscale Materials, Concepts and Design of Materials Nanoarchitectonics covers the introductory features underlying the field, presenting a unifying overview of the theoretical aspects and emerging applications that are changing the capability to understand and design advanced functional materials. Edited by pioneers of the field, this book will appeal to researchers working in nanoscience, materials science, supramolecular chemistry, physical chemistry and organic chemistry, as well as graduate students in these areas.
Author(s): Omar Azzaroni, Katsuhiko Ariga
Series: Nanoscience & Nanotechnology Series
Publisher: Royal Society of Chemistry
Year: 2022
Language: English
Pages: 607
City: London
Cover
Concepts and Design of Materials Nanoarchitectonics
Preface
Contents
Chapter 1 - What is Nanoarchitectonics: Origin and Task
1.1 Nanotechnology Comes First
1.2 Nanoarchitectonics Initiated – Integrated Molecular Systems from Scratch
1.3 How Nanoarchitectonics Works
1.4 Nanoarchitectonics at Work
1.5 Conclusions
Acknowledgements
References
Chapter 2 - Design of Halloysite Based Core–Shell Nanosystems
2.1 Introduction
2.2 Structure and Physicochemical Properties of Halloysite
2.3 Modification of Halloysite Nanotubes
2.3.1 Outer Surface or Non-selective Modification
2.3.2 Selective Lumen Modification
2.3.3 Intercalation
2.4 Core–Shell Metal-containing Halloysite Systems
2.4.1 External Surface Coating
2.4.1.1 Metallic Nanoparticles
2.4.1.2 Bimetallic Nanoparticles
2.4.1.3 Metal Oxide Nanoparticles
2.4.1.4 Ordered Metal Oxide Nanostructures
2.4.1.5 Insoluble Metal Salts
2.4.2 Halloysite with a Metal-containing Core
2.4.2.1 Metallic Core
2.4.2.2 Bimetallic Nanoparticles
2.4.2.3 Metal Oxide Core
2.4.2.4 Insoluble Metal Salts
2.4.3 Hybrid Core–Shell Nanostructures
2.5 Halloysite Core–Shell Micro- and Macrosystems
2.6 Conclusion
Acknowledgements
References
Chapter 3 - Biomimetic Nanoarchitectonics: Natural Cellulose Based Nanocomposites as High Performance Catalysts
3.1 Introduction
3.2 Natural Cellulose Derived Catalytic Membranes
3.3 Natural Cellulose Derived Nanomaterials as Photocatalysts for the Degradation of Dyes
3.3.1 Titania Based Photocatalysts
3.3.2 Titania/Carbon Photocatalysts
3.3.3 Titania Based Composite Photocatalysts
3.4 Natural Cellulose Derived Nanomaterials as Photocatalysts for Hydrogen Production
3.5 Summary and Outlook
References
Chapter 4 - Nanoarchitectonics Based on S-layer Proteins: Design of Noble Metal Nanoparticle Arrangements and Nanostructured Materials
4.1 Introduction: from the S-layer to Metal Nanoparticle Arrays
4.2 S-layer and S-layer Proteins
4.3 Metal Nanoparticles on S-layer Protein Assemblies in Suspension
4.4 Metal Nanoparticles on Supported S-layer Protein Assemblies
4.4.1 Preformed MNPs
4.4.2 MNPs Obtained on Supported SLP Assemblies
4.5 Applications and Perspective
4.5.1 Bionanocatalysts for the Reduction of p-Nitrophenol
4.5.1.1 Platinum-based Nanobiocatalysts
4.5.1.2 Silver-based Nanobiocatalysts
4.5.2 Fabrication of Silicon Nanopillar Structures
4.6 Conclusions
References
Chapter 5 - Surface Engineering Towards Better Material Performance
5.1 Introduction
5.2 Surface Engineering Strategies
5.2.1 Surface Pretreatment
5.2.2 Surface Modification
5.2.3 Surface Deposition
5.2.3.1 Liquid Phase Deposition (LPD)
5.2.3.2 Physical Vapor Deposition (PVD)
5.2.3.3 Chemical Vapor Deposition (CVD)
5.2.4 Surface Coating
5.2.4.1 Dip-coating
5.2.4.2 Spay-coating
5.2.4.3 Spin-coating
5.2.4.4 Layer-by-layer (LbL) Assembly
5.2.5 Surface Structuring
5.2.5.1 Etching
5.2.5.2 Templating
5.2.5.3 Phase Separation
5.2.6 Electrochemical Surface Engineering
5.3 Examples in Surface Engineering Strategies
5.3.1 Enhancement of Optical Properties
5.3.2 Anticorrosion
5.3.3 Self-cleaning Properties
5.3.4 Thermochromic Properties
5.3.5 Detection
5.3.6 Fog Collection
5.4 Summary and Outlook
Acknowledgements
References
Chapter 6 - Nanostructured Biocompatible Materials
6.1 Introduction
6.2 DNA Nanostructures
6.3 Biodegradable Polymers
6.4 Gold Nanoparticles (AuNPs)
6.5 Dendrimers Nanosystems
6.6 Fullerene Nanostructures
6.7 Hydroxyapatite
6.8 Conclusion and Prospects
Acknowledgements
References
Chapter 7 - Self-assembling Nanoarchitectonics for Oral Drug Delivery
7.1 Introduction to the Oral Delivery of Poorly Soluble Drugs
7.2 Concept of Self-assembling Nanoarchitectonics
7.2.1 Non-equilibrium Dynamics of the Supersaturated Solution
7.2.2 Stabilization of the Concentrated Phase as Nanoarchitectures
7.2.3 Nanoarchitectures as Drug Reservoirs
7.2.4 Improvement of the Oral Absorption of Poorly Soluble Drugs
7.3 Summary
References
Chapter 8 - Atomic-scale Characterization of Platinum Nanoparticles Deposited on C60 Fullerene Nanowhiskers and Related Carbon Nanomaterials
8.1 Introduction
8.2 Experimental
8.2.1 Synthesis of C60FNWs
8.2.2 Deposition of Pt NPs on Carbon Substrates Using CAPD
8.2.3 Cross-sectional Sample Preparation for HRTEM Observations
8.2.4 HRTEM Observations and the Measurement of Particle Diameters
8.3 Results and Discussion
8.3.1 Pt NPs Deposited on C60FNWs by CAPD
8.3.2 Pt NPs Deposited on Graphite Particles by CAPD
8.3.3 Pt NPs Deposited on the GC Substrate by CAPD
8.3.4 Pt NPs Deposited on CB Particles
8.4 Summary
Acknowledgements
References
Chapter 9 - Shedding a Light on the Colloidal Architectures of a Metal-free Polymeric Semiconductor Graphitic Carbon Nitride
9.1 Introduction
9.2 Carbon Nitride Formation
9.2.1 Carbon Nitride Synthesis – Simplified
9.2.2 Carbon Nitride Synthesis – Advanced
9.3 Carbon Nitride Composites
9.3.1 g-CN Metal Composites
9.3.2 g-CN Organic Composites
9.4 g-CN Applications at a Glance
9.4.1 Photocatalytic Water Splitting
9.4.2 CO2 Photoreduction
9.4.3 Pollutant Degradation
9.4.4 Organic Synthesis
9.4.5 Sanitization
9.4.6 Photovoltaic Devices
9.4.7 Batteries
9.4.8 Polymer Chemistry
9.4.9 Ion Transport
9.5 Conclusion and Outlook
References
Chapter 10 - Crystalline Coordination Polymers Nanoarchitectonics by Epitaxial Growth and Etching
10.1 Introduction
10.2 Epitaxial Growth
10.2.1 Layer-by-layer Growth
10.2.2 Continuous Growth
10.3 Etching
10.3.1 Thermodynamic Effects
10.3.1.1 Diversity in Component Stability
10.3.1.2 Diversity in Linker Stability
10.3.2 Kinetic Effects
10.3.2.1 Surface Protection
10.3.2.2 Spatial Preferential Etching
10.3.2.3 Competitive Coordination Etching
10.3.2.4 X-ray and Electron-beam Etching
10.4 Conclusion
References
Chapter 11 - Structure–function Relationship in Conjugated Porous Polymers
11.1 Introduction
11.1.1 Design and Synthesis of CPPs
11.1.1.1 Design Rules of CPPs
11.1.1.2 Synthetic Reactions
11.1.1.3 Post Synthetic Modification
11.2 Surface Area and Nanoscale Architectural Control
11.2.1 Inorganic Templates
11.2.2 Templating Using Polymers
11.2.3 Templating Using High Internal Phase Emulsions
11.2.4 Templating Using Removable Functional Groups
11.2.5 Templating via Molecular Imprinting
11.2.6 Nanoscale Architectural Control – Growing CPPs on Surfaces
11.3 Non-covalent Interactions Involving CPPs
11.3.1 Adsorption of Metal Ions and Organic Molecules
11.3.2 Adsorption of Gases
11.3.2.1 Carbon Dioxide
11.3.2.2 Hydrogen
11.4 The Host–Guest Chemistry of CPPs
11.5 Conclusions
11.5.1 Limitations of CPPs
11.5.2 Technology Facilitated Design and Synthesis
11.5.3 Perspective Outlook
References
Chapter 12 - Polymer–Clay Hybrids; General Overviews and Recent Trends
12.1 Introduction
12.2 General Background
12.2.1 Classification of Clay Minerals
12.2.2 Surface Modification of Clay Minerals
12.2.3 Preparation of Polymer–Clay Hybrids
12.2.4 Possible Structure Types of Polymer–Clay Hybrids
12.3 Applications
12.3.1 Gas Barrier
12.3.1.1 Polymer–Layered Clay Mineral Hybrids
12.3.1.2 Polymer–Fibrous (and Tubular) Clay Mineral Hybrids
12.3.2 Anticorrosion
12.3.2.1 Polymer–Layered Clay Mineral Hybrids
12.3.2.2 Polymer–Tubular Clay Mineral Hybrids
12.3.3 Flame Retardancy
12.3.3.1 Polymer–Layered Clay Mineral Hybrids
12.3.3.2 Polymer–Tubular Clay Mineral Hybrids
12.3.4 Mechanical Properties of Polymer–Clay Hybrids for Medical Applications
12.3.4.1 Polymer–Layered Clay Mineral Hybrids
12.3.4.2 Polymer–Tubular Clay Mineral Hybrids
12.3.5 Polymer–Clay Hybrids for Drug (Gene) Delivery
12.3.5.1 Polymer–Layered Clay Mineral Hybrids
12.3.5.2 Polymer–Tubular Clay Mineral Hybrids
12.3.6 Polymer Hydrogel
12.3.6.1 Polymer–Layered Clay Mineral Hybrid Hydrogel
12.3.6.2 Polymer–Tubular Clay Mineral Hybrid Hydrogel
12.3.7 Electrolytes
12.3.7.1 Hybridization of Layered Clay Minerals with Polymer Electrolyte
12.3.7.2 Hybridization of Tubular Clay with Polymer Electrolyte
12.4 Conclusions
List of Abbreviations
Acknowledgements
References
Chapter 13 - Concepts and Design of Water Dispersive Hydrophobic Supracrystals: Specific Properties
13.1 Introduction
13.2 Concept and Design of Water Dispersive Hydrophobic Supracrystals
13.2.1 “Clustered” Structures16,17
13.2.2 Colloidosomes and Supraballs22
13.2.3 “Egg” Structures22
13.3 Specific Properties
13.3.1 Fingerprint of the Supracrystals Building Blocks and Collective Modes17
13.3.2 Nanoheaters46
13.3.3 Magnetic Cells56
13.4 Conclusions
Acknowledgements
References
Chapter 14 - Developments on Supramolecular Thin Films to Sensing Applications
14.1 Introduction – Supramolecular Thin Films
14.2 Langmuir–Blodgett and Langmuir–Schaefer
14.3 Electrodeposition – General Aspects
14.4 Introduction to the Layer-by-Layer Technique
List of Abbreviations
Acknowledgements
References
Chapter 15 - Biomolecules-guided Molecular Architectonics to Nanoarchitectonics
15.1 Introduction
15.1.1 Biomolecules as Functional Auxiliaries
15.2 Modular Building Blocks
15.3 Cα-functionality in Amino Acids
15.4 Multicomponent Architectonics
15.5 Conclusion
Acknowledgements
References
Chapter 16 - Designed Amphiphiles for Cell Membrane Mimetic Nanoarchitecture
16.1 Introduction
16.2 Molecular Design of Membrane-forming Lipid
16.3 Architecture and Features of Membrane Mimetic Supramolecular Assembly
16.3.1 Vesicles
16.3.2 Lipid Nanodiscs
16.3.3 Lipid Cubic Phase
16.4 Conclusion
Acknowledgements
References
Chapter 17 - Design of Nanostructured Lipid Carriers and Hybrid Lipid Nanoparticles
17.1 Introduction
17.2 Solid Lipid Nanoparticles
17.2.1 Application of SLNs
17.3 Nanostructured Lipid Carriers
17.3.1 Applications of Nanostructured Lipid Carriers
17.4 Hybrid NLC Systems
17.4.1 Structural Hybrid NLC
17.4.1.1 Essential Oil Compounds in NLC
17.4.1.2 NLC – Polymers
17.4.1.3 NLC – Peptides and Proteins
17.4.1.4 NLC-Organic Compounds
17.4.1.5 Inorganic Hybrid Lipid Nanoparticles
17.5 Concluding Remarks
Acknowledgements
References
Chapter 18 - Transition Metal Dichalcogenides: Properties, Synthetic Routes and Applications
18.1 Introduction
18.2 Properties of TMDs
18.2.1 Structure
18.2.2 Electronic Structure
18.2.3 Optical Properties
18.3 Synthesis Methods
18.3.1 Top-down Methods – Exfoliation
18.3.1.1 Mechanical Exfoliation
18.3.1.2 Chemical Exfoliation
18.3.2 Bottom-up Methods
18.3.2.1 Synthesis in Liquids
18.3.2.2 Chemical Vapor Deposition
18.3.2.3 Atomic Layer Deposition
18.3.2.4 Molecular Beam Epitaxy
18.3.2.5 Physical Vapor Deposition
18.4 Applications
18.4.1 Microelectronics
18.4.2 Optoelectronics
18.5 Gas Sensing Devices
18.6 Electrochemical Water Splitting
18.7 Conclusion
References
Chapter 19 - Optimal Silicon-based Nanomaterials for Biological Applications
19.1 Semiconductor Silicon Nanostructures – Their Importance
19.2 SiNM Synthesis
19.3 SiNM Functionalization for Biological Uses
19.4 Reactive Oxygen Species Generation by Surface Modified SiNPs
19.5 Photoluminescence in Silicon Nanostructures
19.5.1 Origin of the S-band Emission
19.5.2 Origin of the F-band Emission
19.6 Metal–Si Nanocomposites
19.6.1 Silicon Nanoparticles
19.6.2 Porous Silicon
19.7 Conclusions
List of Abbreviations
References
Chapter 20 - Synergic Properties in Crystals: Implication of Motion at the Molecular Level
20.1 Introduction
20.2 Molecular Motion and Optical Properties
20.2.1 Fluorescence, Phosphorescence, and Birefringence in Crystals with Moving Elements
20.3 Molecular Motion in Polarizable Crystals
20.3.1 Ferroelectricity and Molecular Motion
20.3.1.1 Molecular Motion in Perovskite-type Ferroelectrics
20.3.1.2 Molecular Motion in Ionic Ferroelectrics
20.3.1.3 Molecular Motion in Hydrogen-bonded Ferroelectrics
20.3.1.4 Molecular Motion in Charge-transfer Ferroelectrics
20.4 Salient Crystals with Molecular Motion
20.4.1 Salient Crystals Involving Rotational Components
20.5 The Influence of Molecular Motion on the Porosity of Crystals
20.6 Final Remarks
Acknowledgements
References
Chapter 21 - Tailoring Colloidal Core–Shell Quantum Dots for Optoelectronics
21.1 Introduction
21.2 Classification of Core–Shell QDs
21.3 Synthesis and Optical Properties of Core–Shell QDs
21.3.1 Type I Core–Shell QDs
21.3.2 Type II Core–Shell QDs
21.3.3 Quasi-type II Core–Shell QDs
21.4 Applications of Core–Shell QDs
21.4.1 Solar Cells
21.4.2 Photoelectrochemical Cells
21.4.3 Luminescent Solar Concentrators
21.4.4 Photodetectors
21.4.5 Light Emitting Diodes
21.4.6 Laser
21.5 Conclusions
References
Chapter 22 - Nanoarchitectonics of Stretchable Organic Electronics Materials
22.1 Introduction
22.2 Stretchable Organic Conducting Material-polymer Composites
22.2.1 Metal Nanomaterial-based Composites
22.2.2 Carbon Nanomaterial-based Composites
22.2.3 Liquid Metal-based Composites
22.3 Stretchable Organic Conducting Polymers
22.3.1 Traditional Conducting Polymers
22.3.2 Polymer Hydrogels
22.3.3 Ionic Conducting Elastomers
22.4 Conclusions and Prospects
References
Chapter 23 - Materials Nanoarchitectonics Here, There, Everywhere: Looking Back and Leaping Forward
23.1 Introduction
23.2 Building Blocks for Nanoarchitectonics – Important Emerging Actors for Relevant Applications
23.2.1 Polymer Brushes
23.2.2 Metal–Organic Frameworks
23.2.3 Mesoporous Materials
23.2.4 Colloidal Particles, Nanocrystals and Quantum Dots
23.2.5 Colloidal Supraparticles
23.2.6 Polyelectrolyte-surfactant Complexes
23.3 Nanoarchitectonics in Our Modern Societies – Health, Environment and Energy
23.3.1 Layer-by-layer Nanoarchitectonics for Clean Energy and Sustainable Environment
23.3.1.1 Basics of Layer-by-layer (LbL) Assembly
23.3.1.2 Application of Layer-by-layer (LbL) Assembly for Energy and Environment
23.3.2 Nanoarchitectonics for Biological and Medical Applications
23.4 Conclusions
Acknowledgements
References
Subject Index
