Content: Filamentous carbon formation over iron surfaces / R.T.K. Baker, D.J.C. Yates, and J.A. Dumesic --
Inhibition of coke formation in ethylene steam cracking / D.E. Brown, J.T.K. Clark, A.I. Foster, J.J. McCarroll, and M.L. Sims --
Surface effects on the steam cracking of propane / A. Holmen, O.A. Lindvaag, and D.L. Trimm --
Oxidation of an ethylene steam cracker pyrolysis tube deposit in water vapor and its enhancement by inorganic catalysts / M.J. Bennett and J.B. Price --
Effect of hydrogen on the iron- and nickel-catalyzed formation of carbon from benzene / Alberto I. Lacava, E. Daniel Fernandez-Raone, Leslie L. Isaacs, and Maritza Caraballo --
Mechanism of surface carbon formation during the pyrolysis of benzene in the presence of hydrogen / Alberto I. Lacava, E. Daniel Fernandez-Raone, and Maritza Caraballo --
Formation and removal of coke deposited on stainless steel and vycor surfaces from acetylene and ethylene / James C. Marek and Lyle F. Albright --
Surface phenomena during pyrolysis : the effects of treatments with various inorganic gases / James C. Marek and Lyle F. Albright --
Growth and initiation mechanism of filamentous coke / Albert Sacco, Jr. and John C. Caulmare --
The characterization of carbon deposit morphologies using in situ scanning electron microscopy / A.M. Brown and M.P. Hill --
Inhibition by sulfur poisoning of the heterogeneous decomposition of acetone / M.J. Bennett, G.H. Chaffey, B.L. Myatt, and D.R.V. Silvester --
Influence of total pressure and hydrogen : hydrocarbon ratio on coke formation over naphtha-reforming catalyst / Nora S. Fígoli, Jorge N. Beltramini, Amado F. Barra, Eloy E. Martinelli, Mario R. Sad, and José M. Parera --
Reactivity of surface carbon on nickel catalysts : temperature-programmed surface reaction with hydrogen and water / J.G. McCarty, P.Y. Hou, D. Sheridan, and H. Wise --
Reaction of steam with coke on solid substrates / T.Y. Yan and M.P. Rosynek --
Process of coke formation in delayed coking / C.A. Audeh and T.Y. Yan.
Author(s): Lyle F. Albright and R. T. K. Baker (Eds.)
Series: ACS Symposium Series 202
Publisher: American Chemical Society
Year: 1983
Language: English
Pages: 316
City: Washington, D. C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Filamentous Carbon Formation over Iron Surfaces......Page 8
Experimental......Page 15
RESULTS......Page 20
Discussion......Page 23
Literature Cited......Page 27
2 Inhibition of Coke Formation in Ethylene Steam Cracking......Page 29
ESC Plant Materials Investigation......Page 30
Surface Passivation of ESC Radiant Coil Alloys......Page 32
Silica Coating of Steel Alloys......Page 33
Coke Inhibition in a Laboratory ESC Reactor......Page 40
Conclusion......Page 44
Literature Cited......Page 49
3 Surface Effects on the Steam Cracking of Propane......Page 50
EXPERIMENTAL......Page 51
RESULTS......Page 53
DISCUSSION......Page 55
Literature Cited......Page 62
4 Oxidation of an Ethylene Steam Cracker Pyrolysis Tube Deposit in Water Vapor and Its Enhancement by Inorganic Catalysts......Page 64
Experimental......Page 65
Results......Page 66
Discussion......Page 88
Conclusions......Page 91
Literature Cited......Page 92
5 Effect of Hydrogen on the Iron- and Nickel-Catalyzed Formation of Carbon from Benzene......Page 93
Experimental......Page 95
Results......Page 97
Discussion......Page 103
Mechanism of Carbon Formation on Nickel......Page 104
Mechanism of Carbon Formation on Iron......Page 107
Nomenclature......Page 110
Literature Cited......Page 111
6 Mechanism of Surface Carbon Formation During the Pyrolysis of Benzene in the Presence of Hydrogen......Page 112
Results......Page 114
Discussion......Page 116
Benzene Concentration Along the Reactor......Page 119
Concentration of Intermediate Along the Reactor......Page 120
Temperature Dependence of b and t*......Page 121
Nomenclature......Page 123
Literature Cited......Page 124
7 Formation and Removal of Coke Deposited on Stainless Steel and Vycor Surfaces from Acetylene and Ethylene......Page 125
EXPERIMENTAL DETAILS......Page 126
RESULTS......Page 127
DISCUSSION......Page 147
LITERATURE CITED......Page 150
8 Surface Phenomena During Pyrolysis: The Effects of Treatments with Various Inorganic Gases......Page 152
Experimental Details......Page 153
Experimental Results......Page 154
Discussion of Results......Page 173
Acknowledgment......Page 175
Literature Cited......Page 176
9 Growth and Initiation Mechanism of Filamentous Coke......Page 177
Experimental......Page 178
Method of Analysis......Page 180
Results and Discussion......Page 183
Literature Cited......Page 191
10 The Characterization of Carbon Deposit Morphologies Using In Situ Scanning Electron Microscopy......Page 193
Experimental......Page 195
Results......Page 197
Discussion......Page 217
Literature Cited......Page 221
11 Inhibition by Sulfur Poisoning of the Heterogeneous Decomposition of Acetone......Page 223
Experimental......Page 224
Results......Page 227
Discussion......Page 235
Conclusions......Page 237
Literature Cited......Page 238
12 Influence of Total Pressure and Hydrogen:Hydrocarbon Ratio on Coke Formation over Naphtha-Reforming Catalyst......Page 239
Experimental......Page 240
Results......Page 242
Discussion......Page 245
Literature Cited......Page 252
13 Reactivity of Surface Carbon on Nickel Catalysts: Temperature-Programmed Surface Reaction with Hydrogen and Water......Page 253
Experimental Details......Page 254
Results......Page 258
Carbon Formation on Nickel Catalysts......Page 270
Literature Cited......Page 281
14 Reaction of Steam with Coke on Solid Substrates......Page 283
Experimental Methods......Page 284
Results and Discussion......Page 286
Literature Cited......Page 294
15 Process of Coke Formation in Delayed Coking......Page 295
Results and Discussion......Page 297
Literature Cited......Page 308
C......Page 309
F......Page 312
I......Page 313
Ρ......Page 314
S......Page 315
Z......Page 316
