Content: Manner of sorption and form of the sorption isotherm in gas, liquid, and ion-exchange chromatography / R.J. Laub --
Characterization of bonded high-performance liquid chromatographic stationary phases / S.D. Fazio, J.B. Crowther, and R.A. Hartwick --
Column-packing structure and performance / Vladimir Rehák --
Differences in selectivity of reversed-phase columns for high-performance liquid chromatography / I. Wouters, S. Hendrickx, E. Roets, J. Hoogmartens, and H. Vanderhaeghe --
Selectivity of poly(styrene-divinylbenzene) columns / John M. Joseph --
Chromatographic separation of enantiomers on rationally designed chiral stationary phases / William H. Pirkle --
Nonoptical noise sources in high-performance liquid chromatographic optical absorbance detectors / Seth R. Abbott and Herman H. Kelderman --
Applications of laser fluorimetry to microcolumn liquid chromatography / V.L. McGuffin and R.N. Zare --
Recent advances in new and potentially novel detectors in high-performance liquid chromatography and flow injection analysis / Ira S. Krull --
Microcomputer-assisted retention prediction in reversed-phase liquid chromatography / Kiyokatsu Jinno and Kazuya Kawasaki --
Calculation of retention for complex gradient elution high-performance liquid chromatographic experiments : a universal approach / Sterling A. Tomellini, Shih-Hsien Hsu, R.A. Hartwick, and Hugh B. Woodruff --
Manipulation of stationary-phase acid-base properties by a surface-buffering effect : boronic acid-saccharide complexation / C.H. Lochmüller and Walter B. Hill --
Cyclodextrin mobile-phase and stationary-phase liquid chromatography / L.J. Cline Love and Manop Arunyanart --
High-resolution, two-dimensional, gel electrophoresis of proteins : basic concepts and recent advances / Russell P. Tracy --
Capillary supercritical fluid chromatography and supercritical fluid chromatography-mass spectrometry / R.D. Smith, B.W. Wright, and H.R. Udseth.
Author(s): Satinder Ahuja (Eds.)
Series: ACS Symposium Series 297
Publisher: American Chemical Society
Year: 1986
Language: English
Pages: 311
City: Washington, DC
Title Page......Page 1
Copyright......Page 2
ACS Symposium Series......Page 3
FOREWORD......Page 4
PdftkEmptyString......Page 0
PREFACE......Page 5
1 Manner of Sorption and Form of the Sorption Isotherm in Gas, Liquid, and Ion-Exchange Chromatography......Page 7
The Langmuir Model......Page 8
Extension of the Langmuir Model to Include Equation 6......Page 9
Comprehensive Isotherm Relation......Page 10
Generalized Representation of Retentions with Blended Sorbents......Page 11
Non-Interactive Solute Solution with Non-Interactive Solvents......Page 12
Interactive-Solute Solution with Non-Interactive Solvdents......Page 13
Non-Interactive Solute Solution with Interactive Solvents......Page 15
Interactive-Solute Solution with Interactive Solvents......Page 24
APPLICATION OF EQUATION 10 TO LIQUID CHROMATOGRAPHY......Page 28
APPLICATION OF EQUATION 10 TO ION EXCHANGE CHROMATOGRAPHY......Page 30
Test of Equation 39......Page 32
Test of Equations 41 and 42......Page 34
Acknowledgments......Page 37
Literature Cited......Page 38
2 Characterization of Bonded High-Performance Liquid Chromatographic Stationary Phases......Page 40
Fluoride Derivatization Technique......Page 49
Literature Cited......Page 59
Experimental......Page 62
Literature Cited......Page 73
Samples......Page 74
Results and Discussion......Page 75
Literature Cited......Page 87
5 Selectivity of Poly(styrene-divinylbenzene) Columns......Page 89
Experimental......Page 90
Results and Discussion......Page 91
Acknowledgments......Page 103
Literature Cited......Page 106
6 Chromatographic Separation of Enantiomers on Rationally Designed Chiral Stationary Phases......Page 107
Literature Cited......Page 111
Noise Categories......Page 113
Category I Noise Sources.......Page 115
Category II Noise Sources.......Page 117
Category III Noise Sources.......Page 118
Variable Wavelength UV Absorbance Detector Noise Summary......Page 119
Fixed Wavelength Detector Noise Summary......Page 121
Photodiode Array UV Absorbance Detector Noise Summary......Page 122
Summary......Page 123
Literature Cited......Page 125
8 Applications of Laser Fluorimetry to Microcolumn Liquid Chromatography......Page 126
Experimental Section......Page 128
Results and Discussion......Page 132
Acknowledgments......Page 140
Literature Cited......Page 141
9 Recent Advances in New and Potentially Novel Detectors in High-Performance Liquid Chromatography and Flow Injection Analysis......Page 143
Element Selective Detectors for HPLC and FIA......Page 147
The Photoionization Detector in HPLC or FIA......Page 152
Post-Column, On-Line, Continuous Photolytic Derivatizations in HPLC-Electrochemical Detection (EC) and FIA-EC......Page 157
The Photoconductivity Detector in HPLC (HPLC-PCD)......Page 160
A New Photoelectrochemical Detector for HPLC and FIA (HPLC-PED)......Page 161
Conclusions and Future Advances in Selective and Sensitive Detectors for HPLC and FIA......Page 166
Literature Cited......Page 167
10 Microcomputer-Assisted Retention Prediction in Reversed-Phase Liquid Chromatography......Page 173
Results and Discussion......Page 175
Conclusion......Page 190
Literature Cited......Page 192
11 Calculation of Retention for Complex Gradient Elution High-Performance Liquid Chromatographic Experiments: A Universal Approach......Page 194
Theory......Page 195
Single Column Experiments......Page 200
Single Column Experiments......Page 202
Literature Cited......Page 214
12 Manipulation of Stationary-Phase Acid-Base Properties by a Surface-Buffering Effect Boronic Acid-Saccharide Complexation......Page 216
EXPERIMENTAL......Page 217
Chromatography......Page 219
Results and Discussion......Page 222
Acknowledgments......Page 228
Literature Cited......Page 229
13 Cyclodextrin Mobile-Phase and Stationary-Phase Liquid Chromatography......Page 232
Experimental......Page 234
Cyclodextrin Mobile Phases......Page 235
Cyclodextrin Stationary Phases......Page 241
Acknowledgment......Page 247
Literature Cited......Page 248
14 High-Resolution, Two-Dimensional, Gel Electrophoresis of Proteins Basic Concepts and Recent Advances......Page 250
Background......Page 251
Sample Preparation......Page 253
IEF/SDS-PAGE......Page 254
Visualization......Page 256
Interpretation......Page 257
Ancillary Techniques......Page 259
Acknowledgments......Page 262
Literature Cited......Page 263
15 Capillary Supercritical Fluid Chromatography and Supercritical Fluid Chromatography-Mass Spectrometry......Page 266
Future Directions......Page 293
Literature Cited......Page 297
Author Index......Page 300
A......Page 301
C......Page 302
D......Page 303
G......Page 304
I......Page 305
M......Page 306
P......Page 307
R......Page 308
S......Page 309
U......Page 310
Z......Page 311
