Content: Chemically modified surfaces in catalysis / David E. Bergbreiter --
Preparation and characterization of poly(styrene-divinylbenzene)-supported catalysts / J.V. Minkiewicz, D. Milstein, J. Lieto, B.C. Gates, and R.L. Albright --
Polymeric cofactors for homogeneous rhodium(I) catalyzed alkene Hydrogenations / David E. Bergbreiter, Marian S. Bursten, Kaelyn Cook, and Gregory L. Parsons --
Reactive organic functional groups covalently bound on polymeric supports and solid surfaces / S. Mazur, P. Jayalekshmy, J.T. Andersson, and T. Matusinovic --
Chemically modified conducting polypyrrole film electrodes / M. Salmón, A. Diaz, and J. Goitia --
Simulation of the cyclic voltammetric characteristics of a second order EC catalytic mechanism / Dennis M. Dimarco, Paul A. Forshey, and Theodore Kuwana --
Chemically derivatized semiconductor photoelectrodes / Mark S. Wrighton --
Transfer of solution reactivity properties to electrode surfaces / Hector D. Abruna, Jeffrey M. Calvert, Peter Denisevich, Charles D. Ellis, Thomas J. Meyer, William R, Murphy, Jr., Royce R. Murray, Brian P. Sullivan, and Jerry L. Walsh --
Reductive chloride ion loss and electropolymerization techniques in preparing metallopolymer films on electrode surfaces / J.M. Calvert, B.P. Sullivan, and T.J. Meyer --
Chemical modification of TiO₂ surfaces with methylsilanes and characterization by IR absorption spectroscopy / Harry O. Finklea and R. Vithanage --
Electrochemistry of silane-derivatized iridium / C.A. Lundgren and C.E. Rice --
Improvements in photoelectrochemical and electrochromic reactions at chemically modified electrodes / N.R. Armstrong, T. Mezza, C.L. Linkous, B. Thacker, T. Klofta, and R. Cieslinski --
Derivatized layered M(IV) phosphonates / Martin B. Dines, Peter M. Digiacomo, Kenneth P. Callahan, Peter C. Griffith, Robert H. Lane, and Ricci E. Cooksey --
Intercalation of molecular catalysts in layered silicates / T.J. Pinnavaia --
Selectivity aspects of the Fischer-Tropsch synthesis with supported iron clusters / François Hugues, Bernard Besson, Paul Bussiere, Jean-Alain Dalmon, Michel Leconte, Jean-Marie Basset, Yves Chauvin, and Dominique Commereuc --
Reactivity of catalysts derived from organometallics directly deposited on supports / T.J. Thomas, Dennis A. Hucul, and Alan Brenner --
Silacrowns, a new class of immobilizable phase transfer catalysts / Barry Arkles, William R. Peterson, Jr., and Kevin King.
Author(s): Joel S. Miller (Eds.)
Series: ACS Symposium Series 192
Publisher: American Chemical Society
Year: 1982
Language: English
Pages: 298
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 Chemically Modified Surfaces in Catalysis......Page 8
Literature Cited......Page 14
2 Preparation and Characterization of Poly(styrene-divinylbenzene)-Supported Catalysts......Page 16
Membranes......Page 17
Macroporous Beads......Page 20
Sulfonation......Page 23
Lithiation......Page 25
Phosphination......Page 26
DIOP......Page 27
Phosphitation......Page 28
Amination......Page 29
Thiol Groups......Page 30
Attachment of Metal Complexes......Page 31
Characterization......Page 33
Conclusions......Page 34
Literature Cited......Page 35
3 Polymeric Cofactors for Homogeneous Rhodium(I) Catalyzed Alkene Hydrogenations......Page 37
Results and Discussion......Page 38
Conclusions......Page 45
Literature Cited......Page 46
4 Reactive Organic Functional Groups Covalently Bound on Polymeric Supports and Solid Surfaces......Page 48
Reactive Functional Groups on Polystyrene......Page 51
Reactions of Olefins with Oxide-Free Carbon Surfaces......Page 58
Literature Cited......Page 68
5 Chemically Modified Conducting Polypyrrole Film Electrodes......Page 69
LITERATURE CITED......Page 73
6 Simulation of the Cyclic Voltammetric Characteristics of a Second Order EC Catalytic Mechanism......Page 75
The ec Mechanism......Page 79
DEMONSTRATION......Page 80
Effects of kf......Page 84
Effects of ks,M......Page 86
Effects of Scanrate......Page 89
Concentration Ratio Effects......Page 91
The Catalysis of Oxygen Electro-reduction......Page 93
ACKNOWLEDGEMENTS......Page 99
Literature Cited......Page 101
7 Chemically Derivatized Semiconductor Photoelectrodes......Page 102
Suppression of Photoanodic Corrosion of N-Type Semiconductors......Page 104
Catalysis of H2 Generation from P-Type Semiconductor Photocathodes......Page 107
Improvement of Kinetics for Photoreduction of Horseheart Ferricytochrome c: A Prototype Example of Superior Properties from Molecular Derivatization......Page 124
Measurement of Electron Transfer Rate Constants Involving Surface-Confined Redox Reagents......Page 125
Alteration of Interface Energetics and Surface States by Chemical Modification......Page 127
Acknowledgements......Page 132
LITERATURE CITED......Page 133
8 Transfer of Solution Reactivity Properties to Electrode Surfaces......Page 136
Background Chemistry......Page 137
Conclusions and Final Comments......Page 157
References Cited......Page 159
9 Reductive Chloride Ion Loss and Electropolymerization Techniques in Preparing Metallopolymer Films on Electrode Surfaces......Page 162
Experimental......Page 163
Results and Discussion......Page 166
Literature Cited......Page 184
10 Chemical Modification of TiO2 Surfaces with Methylsilanes and Characterization by IR Absorption Spectroscopy......Page 187
Results and Discussion......Page 188
Literature Cited......Page 198
11 Electrochemistry of Silane-Derivatized Iridium......Page 199
Results and Discussion......Page 200
Conclusions......Page 205
Literature Cited......Page 206
12 Improvements in Photoelectrochemical and Electrochromic Reactions at Chemically Modified Electrodes......Page 207
Light-Assisted Electrochemical Reactions at Phthalocyanine Modified Surfaces.......Page 208
Electrochromic Reactions at Chemically Modified and Ion-Beam Modified Electrode Surfaces.......Page 219
Literature Cited......Page 223
13 Derivatized Layered M(IV) Phosphonates......Page 225
Surface Area and Crystallinity......Page 227
Mixed Component Phases......Page 230
Pillared Phases......Page 234
Anchored Catalysts......Page 237
Transmission Electron Microscopy......Page 239
Literature Cited......Page 242
14 Intercalation of Molecular Catalysts in Layered Silicates......Page 243
Acknowledgements......Page 254
Literature Cited......Page 255
15 Selectivity Aspects of the Fischer-Tropsch Synthesis with Supported Iron Clusters......Page 256
LITERATURE CITED......Page 262
16 Reactivity of Catalysts Derived from Organometallics Directly Deposited on Supports......Page 267
Experimental Section......Page 268
Static Characterization......Page 269
Reactive Characterization......Page 273
Acknowledgement......Page 278
Literature Cited......Page 279
17 Silacrowns, a New Class of Immobilizable Phase Transfer Catalysts......Page 280
Results and Discussion......Page 282
Experimental......Page 287
Immobilization of Methoxymethylsila-17-Crown-6......Page 289
Conclusions......Page 290
LITERATURE CITED......Page 291
C......Page 292
E......Page 293
H......Page 294
N......Page 295
P......Page 296
T......Page 297
Z......Page 298
