Catalysis for Enabling Carbon Dioxide Utilization, Volume 70 in the Advances in Catalysis series highlights new advances in the field, with this new volume presenting interesting chapters on a variety of topics, including Catalytic nonreductive CO2 conversions to facilitate fine chemical synthesis, Electrochemical transformation of CO2 into methanol, Electrocatalytic routes towards Carbon Dioxide Activation and Utilization, Visible-light photoredox-catalyzed organic transformations with CO2, Heterogeneous catalysis for the conversion of CO2into cyclic and polymeric carbonates, and Catalytic synthesis of biosourced organic carbonates and sustainable hybrid materials from CO2.
Author(s): Montserrat Diéguez, Arjan Kleij
Series: Advances in Catalysis, 70
Publisher: Academic Press
Year: 2022
Language: English
Pages: 245
City: London
Front Cover
Catalysis for Enabling Carbon Dioxide Utilization
Copyright
Contents
Contributors
Preface
Chapter One: Functional CO2 based heterocycles as precursors in organic synthesis
1. General introduction
2. Ring-opening functionalization of cyclic carbonates
3. Conversion of vinyl cyclic carbonates by transition metal catalysis
4. Transformation of alkynyl cyclic carbonates
5. Miscellaneous uses of cyclic carbonates
6. Conclusion and outlook
References
About the author
Chapter Two: Recent strategies for the electrochemical reduction of CO2 into methanol
1. Introduction
2. Mechanism of electroreduction of CO2 to methanol
2.1. Illustration of the reaction mechanism
2.2. Performances´ indicators
2.2.1. Onset potential and overpotential
2.2.2. Partial current density and faradic efficiency
2.2.3. Electrochemical surface area (ECSA)
3. Evaluation of catalysts
3.1. Cu-based catalysts
3.1.1. Pure Cu electrode
3.1.2. Single Cu atom catalysts
3.1.3. CuxO catalysts
3.1.4. Cusubstrate
3.1.4.1. Metal-free catalysts
3.1.4.2. Cusupport catalyst
3.1.4.3. CuTiO2 catalyst
3.2. Precious metal-based catalysts and their alloys
3.2.1. Precious metals and oxides
3.2.2. Precious metal-based alloys
3.3. Transition metal-based composites
4. Future perspectives and conclusions
Acknowledgments
References
About the authors
Chapter Three: Electrosynthetic routes toward carbon dioxide activation and utilization
1. Introduction
2. Reduction of CO2 to oxalate
3. Carboxylation of C(sp) bonds
Carboxylation of C=C bonds
4.1. Insertion of two CO2H groups
4.2. Insertion of one CO2H group
Carboxylation of CC bonds
Carboxylation of conjugated C=C–C=C or CC–CC bonds
6.1. Carboxylation of 1,3-dienes
6.2. Carboxylation of 1,3-diynes
Carboxylation of C=O or C=N bonds
Carboxylation of C–X bonds
9. Concluding remarks and future outlook
References
About the author
Chapter Four: Photocatalytic carboxylation with CO2
Carboxylation of C–H bonds
Carboxylation of sp3 C–H bonds
1.1.1. UV light
1.1.2. Visible light
Carboxylation of sp2 C–H bonds
1.2.1. UV light
1.2.2. Visible light
2. Carboxyation of C-(pseudo)halide bonds
Carboxylation of C(sp2)–(pseudo)halide bonds
Carboxylation of C(sp3)–(pseudo)halide bonds
3. Carboxylation of unsaturated substrates
3.1. Carboxylation of alkenes
3.1.1. Hydrocarboxylation of alkenes
3.1.2. Difunctionalization of alkenes
3.1.2.1. α-Carboxylation of alkenes
3.1.2.2. β-Carboxylation of alkenes
3.1.2.3. Dicarboxylation of alkenes
3.2. Carboxylation of alkynes
3.3. Hydrocarboxylation of ketone, imine and hydrazone derivatives
3.3.1. Visible light
4. Miscellaneous
5. Summary
References
About the authors
Chapter Five: Heterogeneous catalysts for the conversion of CO2 into cyclic and polymeric carbonates
1. Introduction
2. Heterogeneous catalysts
2.1. Heterogeneous catalysts for the synthesis of cyclic carbonates
2.1.1. Heterogeneous catalysts based on immobilized active species
2.1.2. Metal organic frameworks
2.1.3. Porous organic polymers
2.1.4. Carbon nitride and N-doped carbon materials
2.2. Heterogeneous catalysts for the synthesis of polycarbonates
2.2.1. Zinc dicarboxylates
2.2.1.1. Synthesis
2.2.1.2. Catalytic mechanism
2.2.1.3. Structure, characterization and catalytic performance
2.2.2. Double metal cyanides
2.2.2.1. Structure and synthesis
2.2.2.2. Catalytic mechanism
2.2.2.3. Catalytic performance
3. Concluding remarks and perspectives
References
About the authors
Chapter Six: Catalytic synthesis of bio-sourced organic carbonates and sustainable hybrid materials from CO2
1. Introduction
1.1. A political view of CO2
1.2. Industrial CO2 utilization
1.2.1. Fuels
1.2.1.1. Methanol
1.2.1.2. Formic acid
1.2.1.3. Methane
1.2.2. Fine chemicals
1.2.3. Carbonates
1.2.4. Polymers
1.3. Conversion of CO2 and bio-derived feedstocks into high value-added products
2. Bio-sourced cyclic carbonates
2.1. Introduction
2.2. Synthesis of cyclic carbonates
2.3. Catalytic synthesis of bio-sourced cyclic carbonates
2.3.1. Terpene-based cyclic carbonates
2.3.2. Vegetable oils-based cyclic carbonates
2.3.3. Carbohydrate-based cyclic carbonates
3. Fully bio-renewable polymers from CO2
3.1. Introduction
3.2. Synthesis of polycarbonates
3.2.1. Synthesis of bio-poly(carbonate)s from CO2-sourced building blocks
3.2.2. Synthesis of bio-poly(carbonate)s using CO2 as a monomer
4. Outlook and conclusions
References
About the authors
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