Content: The study of the structure and chain dynamics of polysulfones by carbon-13 NMR / F.A. Bovey and R.E. Cais --
Polysaccharide branching and carbon-13 NMR / F.R. Seymour --
A reinvestigation of the structure of poly(dichlorophenylene oxides) using carbon-13 NMR spectroscopy / John F. Harrod and Patrick Van Gheluwe --
Carbon-13 NMR in organic solids : the potential for polymer characterization / A.N. Garroway, W.B. Moniz, and H.A. Resing --
Carbon-13 NMR studies of model anionic polymerization systems / S. Bywater and D.J. Worsfold --
Carbon-13 NMR high-resolution characterization of elastomer systems / Charles J. Carman --
Characterization of carbohydrate polymers by carbon-13 NMR spectroscopy / Arthur S. Perlin and Gordon K. Hamer --
Relaxation studies in the system poly(ethyl methacrylate)-chloroform by carbon-13 and proton NMR / Lenas J. Hedlund, Robert M. Riddle, and Wilmer G. Miller --
The use of carbon-13 NMR to study binding of hormones to model receptor membranes : the opioid peptide enkephalin / Harold C. Jarrell, P. Tancrede, Roxanne Deslauriers, Ian C.P. Smith, and W. Herbert McGregor --
Carbon-13 spin relaxation parameters of semicrystalline polymers / D.E. Axelson and L. Mandelkern --
Use of carbon-13 NMR analysis in the characterization of alternating copolymers prepared by chemical modifications of 1,4-polydienes / R. Lacas, G. Maurice, and J. Prud'homme --
Carbon-13 NMR studies on the cationic polymerization of cyclic ethers / G. Pruckmayr and T.K. Wu --
A comparison of models and model parameters for the interpretation of carbon-13 relaxation in common polymers / Alan Anthony Jones, Gary L. Robinson, and Fredric E. Gerr --
Carbon-13 NMR and polymer stereochemical configuration / James C. Randall.
Author(s): Wallace M. Pasika (Eds.)
Series: ACS Symposium Series 103
Publisher: American Chemical Society
Year: 1979
Language: English
Pages: 333
Title Page
......Page 1
Half Title Page
......Page 3
Copyright
......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
1 The Study of the Structure and Chain Dynamics of Polysulfones by Carbon-13 NMR......Page 8
LITERATURE CITED......Page 30
Discussion......Page 31
2 Polysaccharide Branching and Carbon-13 NMR......Page 33
Dextrans......Page 35
Synthetically branched amylose......Page 44
Extracellular mannans......Page 46
Levans and β-D-fructofuranosyl compounds......Page 50
Resonance relaxation measurements......Page 51
General conclusions......Page 55
Literature cited......Page 56
Results......Page 58
Discussion......Page 63
Experimental......Page 70
Literature cited.......Page 71
MAGIC ANGLE SPINNING......Page 72
DIPOLAR DECOUPLING......Page 74
SPECTRAL RESOLUTION, SPECTRAL FIDELITY AND MOLECULAR MOTION IN CURED EPOXIES......Page 75
SPIN-LATTICE RELAXATION IN THE ROTATING FRAME......Page 85
CONCLUSIONS......Page 88
LITERATURE CITED......Page 89
Discussion......Page 91
Experimental......Page 93
Results......Page 94
Discussion......Page 95
Discussion......Page 100
Results and Discussion......Page 101
Abstract......Page 120
Literature Cited......Page 121
Discussion......Page 122
Characteristic Chemical Shifts.......Page 126
Differentiation of Polymers. Mucopolysaccharides......Page 127
Chemical Shift Correlations.......Page 130
Enzymic Applications. Agarose.......Page 133
Uses of 1H-coupled Spectra.......Page 135
Stereochemistry of 13C-1H coupling in oligosaccharide models.......Page 138
Literature Cited.......Page 141
Discussion
......Page 143
8 Relaxation Studies in the System Poly(ethyl methacrylate)-Chloroform by Carbon-13 and Proton NMR......Page 145
Results......Page 146
Discussion......Page 155
References......Page 158
9 The Use of Carbon-13 NMR to Study Binding of Hormones to Model Receptor Membranes: The Opioid Peptide Enkephalin......Page 161
Materials and Methods......Page 162
Results and Discussion......Page 163
Conclusions......Page 180
References......Page 181
10 Carbon-13 Spin Relaxation Parameters of Semicrystalline Polymers......Page 183
Experimental......Page 184
Results......Page 186
Discussion......Page 198
Conclusion......Page 210
Literature Cited......Page 211
Discussion......Page 214
11 Use of Carbon-13 NMR Analysis in the Characterization of Alternating Copolymers Prepared by Chemical Modifications of 1,4-Polydienes......Page 217
Preparation and 220 MHz 1H NMR Characterization of the Materials......Page 218
13C NMR Characterization of the Materials......Page 224
Discussion......Page 236
EXPERIMENTAL......Page 238
I. Polymerization of Cyclic Ethers......Page 239
II. Quantitative Applications of 13C-NMR......Page 250
III. Application to Copolymerizations......Page 259
ACKNOWLEDGMENT......Page 264
APPENDIX......Page 265
Literature Cited......Page 269
Discussion......Page 270
Survey of Interpretational Models......Page 272
Lattice Models......Page 274
Comparison of Polymer Dynamics......Page 279
Summary......Page 285
Abstract......Page 286
Literature Cited......Page 287
Discussion......Page 288
14 Carbon-13 NMR and Polymer Stereochemical Configuration......Page 292
REFERENCES......Page 313
DISCUSSION......Page 315
C
......Page 320
E
......Page 324
H
......Page 325
L
......Page 326
M
......Page 327
P
......Page 328
Q
......Page 330
S
......Page 331
T
......Page 332
Z
......Page 333
