Calibration in Analytical ScienceDesigned to help analytical chemists save time and money by selecting the best calibration method in a quality control, substance monitoring, or research setting
Univariate analytical calibration is a vital step in every chemical procedure that involves determining the identity or concentration of a particular substance. Depending on the type of instrument and measurement, analytical chemists need to follow different calibration strategies and protocols to ensure their instruments yield accurate readings.
Calibration in Analytical Science systematically classifies and describes a wide range of calibration methods and procedures based on mathematical and empirical models for use in qualitative and quantitative analysis. Focusing on the chemical aspects of analytical calibration, this much-needed reference uses a set of equipment-independent terms and definitions that are easily transferable to the calibration strategies of any analytical process. The theoretical basis for calibration of each analytical mode is described and applied to common analytical tasks of increasing levels of difficulty and complexity. Throughout the book, the author illustrates how to combine different calibration approaches to create new calibration strategies with extended capabilities.
- Describes different calibration methods and procedures for determining the nature and quantity of sample components in different ways
- Classifies various calibration methods in both qualitative and quantitative analysis
- Demonstrates how the random and systematic errors of an analytical method can be minimized by the proper calibration strategy
- Discusses current theoretical and methodological questions in calibration research
- Highlights how calibration approaches can diagnose, evaluate, and eliminate analytical errors
- Includes a concluding chapter on the contribution of calibration to the greening of analytical chemistry
Calibration in Analytical Science: Methods and Procedures is a must-have reference for analytical chemists working in academia and industry, chemists of various specialties involved in chemical analysis, and advanced undergraduate and graduate students taking courses in advanced analytical chemistry.
Author(s): Paweł Kościelniak
Publisher: Wiley-VCH
Year: 2023
Language: English
Pages: 385
City: Weinheim
Cover
Title Page
Copyright
Contents
Preface
Chapter 1 Calibration Fundamentals
1.1 Analytical Context
1.2 Principles of Analytical Calibration
1.3 Calibration Standards and Models
1.4 Calibration Procedures and Methods
1.5 Calibration in the Context of Measurement Errors
1.5.1 Uncontrolled Analytical Effects
1.5.2 Elimination and Compensation of Uncontrolled Effects
1.6 Calibration in Qualitative Analysis
1.7 Calibration in Quantitative Analysis
1.8 General Rules for Correct Calibration
References
Chapter 2 “Calibration‐Free” Analysis
2.1 Novel Approach
2.2 Empirical Calibration
2.3 Theoretical Calibration
2.3.1 Fixed Models
2.3.2 Flexible Models
References
Chapter 3 Calibration Methods in Qualitative Analysis
3.1 Classification
3.2 External Calibration Methods
3.2.1 External Standard Method
3.2.2 Reference Sample Method
3.3 Internal Calibration Methods
3.3.1 Internal Standard Method
3.3.2 Indirect Method
3.4 Standard Addition Method
References
Chapter 4 Introduction to Empirical Calibration in Quantitative Analysis
4.1 Classification
4.2 Formulation of Model Functions
4.3 Examination of Interference Effect
4.4 Mathematical Modeling of Real Function
References
Chapter 5 Comparative Calibration Methods
5.1 External Calibration Methods
5.1.1 External Standard Method
5.1.1.1 Modified Procedures
5.1.2 Dilution Method
5.2 Internal Calibration Methods
5.2.1 Internal Standard Method
5.2.2 Indirect Method
References
Chapter 6 Additive Calibration Methods
6.1 Basic Aspects
6.2 Standard Addition Method
6.2.1 Extrapolative Variant
6.2.1.1 Modified Procedures
6.2.2 Interpolative Variants
6.2.3 Indicative Variant
6.3 Titration
6.4 Isotope Dilution Method
6.4.1 Radiometric Isotope Dilution
6.4.2 Isotope Dilution Mass Spectrometry
6.4.2.1 Modified Procedures
References
Chapter 7 Calibration in Nonequilibrium Conditions
7.1 Flow Injection Analysis
7.1.1 Manipulation Techniques
7.1.2 Gradient Technique
7.2 Kinetic Analysis
References
Chapter 8 Complex Calibration Approaches
8.1 Extrapolative Methods
8.1.1 Extrapolative Indirect Method
8.1.2 Extrapolative Internal Standard Method
8.1.3 Extrapolative Dilution Method
8.2 Mixed Methods
8.3 Combined Methods
8.3.1 Integrated Calibration Methods
8.3.1.1 Simple Integrated Method
8.3.1.2 Complementary Dilution Method
8.3.2 Generalized Calibration Strategy
8.3.2.1 Versatile Flow Injection Calibration Module
8.3.3 Standard Dilution Analysis
References
Chapter 9 Calibration Approaches for Detection and Examination of Interference Effects
9.1 Introduction
9.2 Simple Procedures for Detection and Examination of Interference Effects
9.3 Detection and Compensation of Additive Interference Effect
9.3.1 Interpolative Procedure
9.3.2 Extrapolative Procedure
9.3.3 Integrated Procedure
References
Chapter 10 Calibration‐Based Procedures for Correction of Preparative Effects
10.1 Introduction
10.2 Specific Procedures
10.3 Surrogate Recovery Method
10.3.1 Reliability of the Method
10.3.2 Interpretations of the Method
10.3.3 Recovery vs. Interference Effect
10.3.4 Recovery vs. Speciation Effect
References
Chapter 11 Calibration‐Related Applications of Experimental Plans
11.1 Introduction
11.2 Examination of Interference Effects
11.3 Modeling of Real Functions
11.4 Multicomponent Analysis
References
Chapter 12 Final Remarks
References
Index
EULA
