Bio-inorganic Hybrid Nanomaterials - Strategies Syntheses Characterization and Applications

Cover Page......Page 1
Further Reading......Page 3
Title: Bio-inorganic Hybrid Nanomaterials - Strategies, Syntheses, Characterization and Applications......Page 4
ISBN 978-3527317189......Page 5
Contents (with page links)......Page 6
Preface......Page 14
Contributors......Page 16
1.1 Introduction: The Assembly of Biological Species to Inorganic Solids......Page 20
1.2 Bio-nanohybrids Based on Silica Particles and Siloxane Networks......Page 23
1.3 Calcium Phosphates and Carbonates in Bioinspired and Biomimetic Materials......Page 28
1.4 Clay Minerals and Organoclay Bio-nanocomposites......Page 32
1.5 Bio-Nanohybrids Based on Metal and Metal Oxide Nanoparticles......Page 39
1.6 Carbon-based Bio-nanohybrids......Page 41
1.7 Bio-nanohybrids Based on Layered Transition Metal Solids......Page 47
1.8 Trends and Perspectives......Page 50
Acknowledgements......Page 51
2.1 Introduction......Page 60
2.2 Monolayer on Solid Support......Page 64
2.3 Layered Alkylsiloxane......Page 72
2.4 Organic—Inorganic Hybrid Vesicle ‘‘Cerasome’’......Page 78
2.5 Mesoporous Silica Prepared by the Lizard Template Method......Page 84
2.6 Future Perspectives......Page 88
Acknowledgment......Page 90
3.1 Introduction......Page 94
3.2 Sol—Gel Processes......Page 96
3.3 Biocompatible Approaches......Page 103
3.4 One-Stage Approach Based on a Silica Precursor with Ethylene Glycol Residues......Page 107
Notes......Page 121
4.1 Introduction......Page 132
4.2 Immobilization of Protein on Mesoporous Silica......Page 135
4.3 Immobilization of Protein on Mesoporous Carbon and Related Materials......Page 143
4.4 Immobilization of Other Biopolymers on Mesoporous Materials......Page 152
4.5 Immobilization of Small Biomolecules on Mesoporous Materials......Page 156
4.6 Advanced Functions of Nanohybrids of Biomolecules and Mesoporous Materials......Page 160
Acknowledgment......Page 168
5.1 Introduction......Page 178
5.2 Biomimetic Approaches......Page 179
5.3 In vitro Synthesis of Hybrid Nanomaterials......Page 184
5.4 Perspectives: Towards a ‘‘Green Nanochemistry’’......Page 202
6.1 Introduction......Page 212
6.2 Fundamental Concept of Bioinspired Approach......Page 216
6.3 Alternate Soaking Process for Biomineralization and their Bio-functions......Page 218
6.4 Electrophoresis Process for Biomineralization......Page 222
6.5 Conclusions......Page 225
7.2 Porous Materials......Page 228
7.3 LbL Assembly......Page 232
7.4 LbL Assembly on MS Substrates......Page 233
7.5 LbL Assembly on Macroporous Substrates......Page 244
7.6 Summary and Outlook......Page 251
References......Page 252
8.1 Introduction......Page 258
8.2 Synthesis and Characterization of Organically Functionalized 2:1 Magnesium Phyllosilicates......Page 259
8.3 Magnesium Organophyllosilicates with Higher-order Organization......Page 262
8.4 Intercalation of Biomolecules within Organically Modi.ed Magnesium Phyllosilicates......Page 265
8.5 Hybrid Nanostructures Based on Organoclay Wrapping of Single Biomolecules......Page 273
8.6 Functional Mesolamellar Bio-inorganic Nanocomposite Films......Page 279
References......Page 281
9.1 Introduction......Page 290
9.2 Nano-structure Development......Page 291
9.3 Control of Nanostructure Properties......Page 301
9.4 Physicochemical Phenomena......Page 309
9.5 Foam Processing using Supercritical CO......Page 315
9.6 Porous Ceramic Materials via Nanocomposites......Page 326
9.7 Future Prospects......Page 328
References......Page 329
10.1 Introduction......Page 332
10.2 Molecular Recognition-based Hybrid Membranes......Page 333
10.3 Self-organized Hybrid Membrane Materials......Page 337
10.4 Dynamic Site Complexant Membranes......Page 349
Acknowledgement......Page 352
References......Page 353
11.1 Introduction......Page 358
11.2 Composite of Bioactive Ceramic Particles and Polymers......Page 359
11.3 Bone-bonding Mechanism of Bioactive Materials......Page 360
11.4 Sol—Gel-derived Bioactive Nano-hybrids......Page 364
11.5 Nano-hybrid Consisting of Bone-like Hydroxyapatite and Polymer......Page 373
11.6 Nano-hybrid Consisting of Hydroxyapatite and Protein......Page 379
References......Page 380
12.1 Introduction......Page 386
12.2 Bone: A Biological Hybrid Nanostructured Material......Page 388
12.3 Biomimetic Materials for Bone Repair. The Hybrid Approach......Page 391
12.4 Synthesis and Properties of Organic—Inorganic Hybrid Materials for Bone and Dental Applications......Page 394
12.5 Conclusion......Page 411
References......Page 412
13.1 Introduction......Page 420
13.2 Synthesis of Bio-inorganic Conjugates......Page 422
13.3 Bio-inorganic Conjugate for Efficient Gene Delivery......Page 426
13.4 Bio-inorganic Conjugate for Efficient Drug Delivery......Page 428
13.5 Cellular Uptake Mechanism of LDH......Page 431
References......Page 434
14.1 Halloysite Structural Characterization......Page 438
14.2 Macromolecule Loading and Sustained Release......Page 441
14.3 Nanoassembly on Tubules and at the Lumen Opening......Page 447
14.4 Catalysis in a Nanoconstrained Volume of the Tubule Lumen......Page 450
14.5 Multilayer Halloysite Assembly for Organized Nano.lms. Forming Low Density Tubule Nanoporous Materials......Page 455
14.6 Applications: Current and Potential......Page 457
References......Page 458
15.1 Introduction......Page 462
15.2 Enzymes versus Inorganic Host Properties......Page 464
15.3 Immobilization Strategy......Page 465
15.4 Bioinorganic Nanohybrids......Page 473
15.5 Enzyme—Host Structure Interactions......Page 490
References......Page 495
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R......Page 518
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Y,Z......Page 522