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This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. Key Features * In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves. Read more... Abstract: This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. Key Features * In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves

Author(s): F. Gordon A. Stone and Robert West (Eds.)
Series: Advances in Organometallic Chemistry 42
Publisher: Academic Press
Year: 1998

Language: English
Pages: iii-vii, 1-422
City: New York

Content:
Edited by
Page iii

Copyright page
Page iv

Contributors
Page vii

Main Group-Transition Metal Cluster Compounds of the Group 15 Elements Original Research Article
Pages 1-145
Kenton H. Whitmire

Transition-Metal Complexes of Arynes, Strained Cyclic Alkynes, and Strained Cyclic Cumulenes Original Research Article
Pages 147-221
William M. Jones, Jerzy Klosin

Bridged Silylene and Germylene Complexes Original Research Article
Pages 223-290
Hiroshi Ogino, Hiromi Tobita

Organometallic Complexes in Nonlinear Optics I: Second-Order Nonlinearities Original Research Article
Pages 291-362
Ian R. Whittall, Andrew M. McDonagh, Mark G. Humphrey, Marek Samoc

Catalytic Dehydrocoupling: A General Strategy for the Formation of Element-Element Bonds Original Research Article
Pages 363-405
François Gauvin, John F. Harrod, Hee Gweon Woo

Index
Pages 407-415

Cumulative List of Contributors for Volumes 1-36
Pages 417-420

Cumulative Index for Volumes 37-42
Pages 421-422