Asymmetric Reactions and Processes in Chemistry

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Content: Approaches for asymmetric synthesis as directed toward natural products / Barry M. Trost --
Synthetic control leading to natural products / Teruaki Mukaiyama --
Asymmetric synthesis of chiral tertiary alcohols in high enantiomeric excess / Ernest L. Eliel, Jorma K. Koskimies, Bruno Lohri, W. Jack Frazee, Susan Morris-Natschke, Joseph E. Lynch, and Kenso Soai --
Acyclic stereoselection via the aldol condensation / Clayton H. Heathcock --
Asymmetric carbon-carbon bond forming reactions via chiral chelated intermediates : diastereoselective asymmetric synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes / Kenji Koga --
Asymmetric carbon-carbon bond forming reactions via chiral oxazolines / Albert I. Meyers --
Highly selective synthesis with novel metallic reagents / Hitosi Nozaki, Tamejiro Hiyama, Koichiro Oshima, and Kazuhiko Takai --
Novel approaches to the asymmetric synthesis of peptides / Iwao Ojima --
Asymmetric carbon-carbon bond formation using enantiomerically pure vinylic sulfoxides / Gary H. Posner, John P. Mallamo, Kyo Miura, and Martin Hulce --
Asymmetric reactions : a challenge to the industrial chemist / Gabriel Saucy and Noal Cohen --
Stereochemistry of heterogeneous asymmetric catalytic hydrogenation / Kaoru Harada --
Asymmetric Grignard cross-coupling catalyzed by chiral phosphine-nickel and phosphine-palladium complexes / Tamio Hayashi --
Rhodium(I) catalyzed enantioselective hydrogen migration of prochiral allylamines / K. Tani, T. Yamagata, S. Otsuka, S. Akutagawa, H. Kumobayashi, T. Taketomi, H. Takaya, A. Miyashita, and R. Noyori --
Application of immobilized enzymes for asymmetric reactions / Ichiro Chibata --
Asymmetric synthesis using cofactor-requiring enzymes / George M. Whitesides, Chi-Huey Wong, and Alfred Pollak --
Mechanistic considerations of biomimetic asymmetric reductions / Atsuyoshi Ohno --
Stereochemistry of one-carbon transfer reactions / Heinz G. Floss --
A useful and conveniently accessible chiral stationary phase for the liquid chromatographic separation of enantiomers / William H. Pirkle, John M. Finn, Bruce C. Hamper, James Schreiner, and James R. Pribish --
New asymmetric reactions using (S)-2-aminomethylpyrrolidine derivatives / Masatoshi Asami --
Liquid chromatographic resolution of enantiomeric [alpha]-amino acid derivatives employing a chiral diamide phase / Shoji Hara, Akira Dobashi, and Masakatzu Eguchi --
Asymmetric reduction with chiral NADH model compounds / Yuzo Inouye --
Asymmetric hydrogenation of cyclic dipeptides containing [alpha], [beta]-dehydroamino acid residues and subsequent preparation of optically pure [alpha]-amino acids / Nobuo Izumiya.

Author(s): Ernest L. Eliel and Sei Otsuka (Eds.)
Series: ACS Symposium Series 185
Publisher: American Chemical Society
Year: 1982

Language: English
Pages: 275
City: Washington, D.C