Aquatic Redox Chemistry

Content: PREFACE ; 1. INTRODUCTION TO AQUATIC REDOX CHEMISTRY ; TIMOTHY J. GRUNDL, STEFAN HADERLEIN, JAMES T. NURMI, AND PAUL G. TRATNYEK ; 2. THERMODYNAMIC REDOX CALCULATIONS FOR ONE AND TWO ELECTRON TRANSFER STEPS: IMPLICATIONS FOR HALIDE OXIDATION AND HALOGEN ENVIRONMENTAL CYCLING ; GEORGE W. LUTHER, III ; 3. ONE-ELECTRON REDUCTION POTENTIALS FROM CHEMICAL STRUCTURE THEORY CALCULATIONS ; ERIC J. BYLASKA, ALEXANDRA J. SALTER-BLANC, AND PAUL G. TRATNYEK ; 4. THERMODYNAMIC CONTROL ON TERMINAL ELECTRON TRANSFER AND METHANOGENESIS ; CHRISTIAN BLODAU ; 5. REDOX CHEMISTRY AND NATURAL ORGANIC MATTER (NOM): GEOCHEMISTS' DREAM, ANALYTICAL CHEMISTS>' NIGHTMARE ; DONALD L. MACALADY AND KATHERINE WALTON-DAY ; 6. ELECTRON SHUTTLING BY NATURAL ORGANIC MATTER: TWENTY YEARS AFTER ; GARRISON SPOSITO ; 7. ELECTROCHEMISTRY OF NATURAL ORGANIC MATTER ; JAMES T. NURMI AND PAUL G. TRATNYEK ; 8. PATHWAYS CONTRIBUTING TO THE FORMATION AND DECAY OF FERROUS IRON IN SUNLIT NATURAL WATERS ; SHIKHA GARG, ANDREW L. ROSE, AND T. DAVID WAITE ; 9. THE ROLE OF IRON COORDINATION IN THE PRODUCTION OF REACTIVE OXIDANTS FROM FERROUS IRON OXIDATION BY OXYGEN AND HYDROGEN PEROXIDE ; CHRISTINA KEENAN REMUCAL AND DAVID L. SEDLAK ; 10. TIO2 PHOTOCATALYSIS FOR THE REDOX CONVERSION OF AQUATIC POLLUTANTS ; JAESANG LEE, JUNGWON KIM, AND WONYONG CHOI ; 11. CHLORINE BASED OXIDANTS FOR WATER PURIFICATION AND DISINFECTION ; GREGORY V. KORSHIN ; 12. REMEDIATION OF CHEMICALLY-CONTAMINATED WATERS USING SULFATE RADICAL REACTIONS: KINETIC STUDIES ; STEPHEN P. MEZYK, KIMBERLY A. RICKMAN, GARRETT MCKAY, CHARLOTTE M. HIRSCH, XUEXIANG HE, AND DIONYSIOS D. DIONYSIOU ; 13. VOLTAMMETRY OF SULFIDE NANOPARTICLES AND THE FES(AQ) PROBLEM ; G. R. HELZ, I. CIGLENECKI, D. KRZNARIC, AND E. BURA-NAKIC ; 14. REDOX REACTIVITY OF ORGANICALLY COMPLEXED IRON(II) SPECIES WITH AQUATIC CONTAMINANTS TIMOTHY J. STRATHMANN ; 15. FE2+ SORPTION AT THE FE OXIDE-WATER INTERFACE: A REVISED CONCEPTUAL FRAMEWORK ; CHRISTOPHER A. GORSKI AND MICHELLE M. SCHERER ; 16. REDOX DRIVEN STABLE ISOTOPE FRACTIONATION ; JAY R. BLACK, JEFFREY A. CRAWFORD, SETH JOHN, AND ABBY KAVNER ; 17. REDOX PROPERTIES OF STRUCTURAL FE IN SMECTITE CLAY MINERALS ; ANKE NEUMANN, MICHAEL SANDER, AND THOMAS B. HOFSTETTER ; 18. REACTIVITY OF ZEROVALENT METALS IN AQUATIC MEDIA: EFFECTS OF ORGANIC SURFACE COATINGS ; PAUL G. TRATNYEK, ALEXANDRA J. SALTER-BLANC, JAMES T. NURMI, JAMES E. AMONETTE, JUAN LIU, CHONGMIN WANG, ALICE DOHNALKOVA, AND DONALD R. BAER ; 19. CURRENT PERSPECTIVES ON THE MECHANISMS OF CHLOROHYDROCARBON DEGRADATION IN SUBSURFACE ENVIRONMENTS: INSIGHT FROM KINETICS, PRODUCT FORMATION, PROBE MOLECULES, AND ISOTOPE FRACTIONATION ; MARTIN ELSNER AND THOMAS B. HOFSTETTER ; 20. DEGRADATION ROUTES OF RDX IN VARIOUS REDOX SYSTEMS ; ANNAMARIA HALASZ AND JALAL HAWARI ; 21. ROLE OF COUPLED REDOX TRANSFORMATIONS IN THE MOBILIZATION AND SEQUESTRATION OF ARSENIC ; JANET G. HERING, STEPHAN J. HUG, CLAIRE FARNSWORTH, AND PEGGY A. O>'DAY ; 22. REDOX PROCESSES AFFECTING THE SPECIATION OF TECHNETIUM, URANIUM, NEPTUNIUM, AND PLUTONIUM IN AQUATIC AND TERRESTRIAL ENVIRONMENTS ; EDWARD J. O'LOUGHLIN, MAXIM I. BOYANOV, DIONYSIOS A. ANTONOPOULOS, AND KENNETH M. KEMNER ; 23. RATE CONTROLLING PROCESSES IN THE TRANSFORMATION OF TETRACHLOROETHYLENE AND CARBON TETRACHLORIDE UNDER IRON REDUCING AND SULFATE REDUCING CONDITIONS ; ELIZABETH C. BUTLER, YIRAN DONG, LEE R. KRUMHOLZ, XIAOMING LIANG, HONGBO SHAO, AND YAO TAN ; 24. THE USE OF CHEMICAL PROBES FOR THE CHARACTERIZATION OF THE PREDOMINANT ABIOTIC REDUCTANTS IN ANAEROBIC SEDIMENTS ; HUICHUN (JUDY) ZHANG, DALIZZA COLON, JOHN F. KENNEKE, AND ERIC J. WEBER ; 25. THE ROLE OF TRANSPORT IN AQUATIC REDOX CHEMISTRY ; WOLFGANG KURTZ AND STEFAN PEIFFER ; 26. EVOLUTION OF REDOX PROCESSES IN GROUNDWATER ; PETER B. MCMAHON, FRANCIS H. CHAPELLE, AND PAUL M. BRADLEY ; EDITORS' BIOGRAPHIES ; INDEXES ; AUTHOR INDEX ; SUBJECT INDEX