Analysis of Reaction and Transport Processes in Zinc Air Batteries

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This book contains a novel combination of experimental and model-based investigations, elucidating the complex processes inside zinc air batteries. The work presented helps to answer which battery composition and which air-composition should be adjusted to maintain stable and efficient charge/discharge cycling. In detail, electrochemical investigations and X-ray transmission tomography are applied on button cell zinc air batteries and in-house set-ups. Moreover, model-based investigations of the battery anode and the impact of relative humidity, active operation, carbon dioxide and oxygen on zinc air battery operation are presented. The techniques used in this work complement each other well and yield an unprecedented understanding of zinc air batteries. The methods applied are adaptable and can potentially be applied to gain further understanding of other metal air batteries.

Author(s): Daniel Schröder (auth.)
Edition: 1
Publisher: Springer Vieweg
Year: 2016

Language: English
Pages: XXXVII, 231
Tags: Energy Technology; Appl.Mathematics/Computational Methods of Engineering; Engineering Thermodynamics, Heat and Mass Transfer

Front Matter....Pages I-XXXVII
Introduction....Pages 1-16
Motivation and Scope of this Thesis....Pages 17-19
Front Matter....Pages 21-21
Basics of the Experimental Methods Applied....Pages 23-38
Experimental Set-Ups and Measurement Details....Pages 39-50
Experimental Results and Discussion....Pages 51-82
Detailed One-Dimensional Air Electrode Model....Pages 83-94
Front Matter....Pages 95-95
Theoretical Considerations on Air-Composition Impact....Pages 97-108
Model Approach to Reveal Air-Composition Impact....Pages 109-133
Simulation Results and Discussions for Air-Composition Impact....Pages 135-171
Back Matter....Pages 173-231