Amsterdam-London-New York: Elservier Publ. Comp., 1966. — 290 p.Contents
Tribute to A. Prince by T. Chart and B. Legendre
Preface
Acknowledgements.
Introductory thermodynamics .
Equilibrium
Internal energy
Heat content or enthalpy
Entropy
Free energy
Thermodynamics of solutions
Solutions
Heterogenous equilibrium-the phase rule
Free energy of solutions
The free energy of phase mixtures
Variation of solubility with temperature
Binary phase diagrams
Two-phase equilibrium
Introduction
Two phase equilibrium. Complete solubility of the
components in both the liquid and the solid state .
Binary phase diagrams
Three-phase equilibrium involving limited solubility of the components in the solid state but complete solubility in the liquid state
Structural factors
Three-phase equilibrium-eutectic reactions
Three-phase equilibrium-peritectic reactions
Congruent transformations
Binary phase diagrams
Limited solubility in both the liquid and solid state
Introductory thermodynamics
Monotectic reactions
Syntectic reactions
Binary phase diagrams
Reactions in the solid state
Solid state reactions
Eutectoïd reactions
Monotectoïd reactions
Peritectoïd reactions
Binary phase diagrams
Allotropy of the components
Systems in which one phase is in equilibrium with the liquid phase
Systems in which two phases are in equilibrium with the liquid phase
Ternary phase diagrams
Two-phase equilibrium
Introduction
Representation of ternary systems
Tie lines and tie triangles
Two-phase equilibrium. Complete solubility of the components in both the liquid and the solid state
Ternary phase diagrams
Three-phase equilibrium
Properties of three-phase tie triangles
Three-phase equilibrium produced by the coalescence of miscibility gaps
Three-phase equilibrium involving eutectic reactions
Three-phase equilibrium involving peritectic reactions
Ternary phase diagrams
Four-phase equilibrium
The eutectic equilibrium l = α+β+γ
Variants of the ternary eutectic diagram
The quasi-peritectic equilibrium l+α = β+γ
T he ternary peritectic equilibrium l+α + β = γ
Ternary phase diagrams
Intermediate phases
Congruently-melting intermediate phases
Incongruently-melting intermediate phases
Ternary phase diagrams
Liquid immiscibilty
Two binary systems are monotectic
One binary system is monotectic
None of the binaries contain liquid miscibility gaps but
true ternary liquid immiscibility appears .
Ternary phase diagrams
Four-phase equilibrium involving allotropy of one component
The association of phase regions .
Law of adjoining phase regions
Degenerate phase regions
Two-dimensional sections of phase diagrams
The cross rule
Non-regular two-dimensional sections
Critical points
Association of phase regions in multi-components systems
Quaternary phase diagrams .
Representation of quaternary systems
Two-phase equilibrium
Three-phase equilibrium
Four-phase equilibrium
Five-phase equilibrium
Two-dimensional polythermal sections
Complex quaternary systems
Appendix
Selected bibliography
Index
