Advances in Inorganic Chemistry

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Advances in Inorganic Chemistry presents timely, informative and comprehensive reviews of the current progress in all areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. . The latest volume in this highly successful series is dedicated to redox-active metal complexes . Comprehensive reviews written by leading experts in the field . An indispensable reference to advanced researchers. Read more... Content: Synergy between theory and experiment as applied to H/D exchange activity assays in [Fe]H₂ase active site models / Jesse W. Tye ... [et al.] -- Electronic structure and spectroscopic properties of molybdenum and tungsten N₂, NNH, NNH₃ complexes with diphosphine co-ligands: insights into the end-on terminal reduction pathway of dinitrogen / Felix Tuczek. -- Quantum chemical investigations into the problem of biological nitrogen fixation: sellmann-type metal-sulfur model complexes / Markus Reiher and Bernd A. Hess. -- Proton and electron transfers in [NiFe] hydrogenase / Per E.M. Siegbahn. -- Heterolytic splitting of H-H, Si-H, and other [sigma] bonds on electrophilic metal centers / Gregory J. Kubas. -- Tetrapodal pentadentate nitrogen ligands: aspects of complex structure and reactivity / Andreas Grohmann. -- Efficient, ecologically benign, aerobic oxidation of alcohols / István E. Markó ... [et al.] -- Visible light photocatalysis by a titania transition metal complex / Horst Kisch, Gerald Burgeth and Wojciech Macyk. Abstract: Advances in Inorganic Chemistry presents timely, informative and comprehensive reviews of the current progress in all areas within inorganic chemistry ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced. . The latest volume in this highly successful series is dedicated to redox-active metal complexes . Comprehensive reviews written by leading experts in the field . An indispensable reference to advanced researchers

Author(s): R. van Eldik (Eds.)
Series: Advances in Inorganic Chemistry 56
Publisher: AP
Year: 2004

Language: English
Pages: 1-273
City: Amsterdam ; Boston

Content:
CONTENTS
Pages v-vii

Preface
Pages ix-x

SYNERGY BETWEEN THEORY AND EXPERIMENT AS APPLIED TO H/D EXCHANGE ACTIVITY ASSAYS IN [Fe]H2ase ACTIVE SITE MODELS Review Article
Pages 1-26
JESSE W. TYE, MICHAEL B. HALL, IRENE P. GEORGAKAKI, MARCETTA Y. DARENSBOURG

ELECTRONIC STRUCTURE AND SPECTROSCOPIC PROPERTIES OF MOLYBDENUM AND TUNGSTEN N2, NNH, NNH2, AND NNH3 COMPLEXES WITH DIPHOSPHINE CO-LIGANDS: INSIGHTS INTO THE END-ON TERMINAL REDUCTION PATHWAY OF DINITROGEN Review Article
Pages 27-53
FELIX TUCZEK

QUANTUM CHEMICAL INVESTIGATIONS INTO THE PROBLEM OF BIOLOGICAL NITROGEN FIXATION: SELLMANN-TYPE METAL–SULFUR MODEL COMPLEXES Review Article
Pages 55-100
MARKUS REIHER, BERND A. HESS

PROTON AND ELECTRON TRANSFERS IN [NiFe] HYDROGENASE Review Article
Pages 101-125
PER E.M. SIEGBAHN

HETEROLYTIC SPLITTING OF HH, SiH, AND OTHER σ BONDS ON ELECTROPHILIC METAL CENTERS Review Article
Pages 127-177
GREGORY J. KUBAS

TETRAPODAL PENTADENTATE NITROGEN LIGANDS: ASPECTS OF COMPLEX STRUCTURE AND REACTIVITY Review Article
Pages 179-210
ANDREAS GROHMANN

EFFICIENT, ECOLOGICALLY BENIGN, AEROBIC OXIDATION OF ALCOHOLS Review Article
Pages 211-240
ISTVÁN E MARKÓ, PAUL R GILES, MASAO TSUKAZAKI, ISABELLE CHELLÉ-REGNAUT, ARNAUD GAUTIER, RAPHAEL DUMEUNIER, FREDDI PHILIPPART, KANAE DODA, JEAN-LUC MUTONKOLE, STEPHEN M BROWN, CHRISTOPHER J URCH

VISIBLE LIGHT PHOTOCATALYSIS BY A TITANIA TRANSITION METAL COMPLEX Review Article
Pages 241-259
HORST KISCH, GERALD BURGETH, WOJCIECH MACYK

Index
Pages 261-267

CONTENTS OF PREVIOUS VOLUMES
Pages 269-273