Surface Science is understood as a relatively young scientific discipline, concerned with the physical and chemical properties of phenomena on clean and covered solid surfaces, studied under a variety of conditions. The adsorption of atoms and molecules on solid surfaces is, for example, such a condition, connected with more or less drastic changes of all surface properties. An adsorption event is frequently observed in nature and found to be of technical importance in many industrial processes. For this reason, Surface Science is interdisciplinary by its very nature, and as such an important intermediary between fundamental and applied research.
Author(s): K. Christmann, H. J. Freund, J. Kim, B. Koel, H. Kuhlenbeck, M. Morgenstern, C. Panja, G. Pirug, G. Rupprechter, E. Samano, G.A. Somorjai
Series: Landolt-Börnstein: Numerical Data and Functional Relationships in Science and Technology - New Series / Condensed Matter
Edition: 1
Publisher: Springer
Year: 2006
Language: English
Pages: 418
Title Page......Page 2
3.9.1 Introduction - 3.9.11 NiO......Page 0
Preface......Page 4
Contributors......Page 5
Table of Contents Vol. III/42A......Page 14
3.4.1.1 Introduction......Page 19
3.4.1.2 Some general principles of the hydrogen - surface interaction......Page 21
3.4.1.3.1 Adsorption kinetics......Page 24
3.4.1.3.2 Kinetics of hydrogen desorption......Page 36
3.4.1.3.3 The energetics of hydrogen adsorption and desorption......Page 47
3.4.1.3.4 The diffusion of adsorbed hydrogen......Page 61
3.4.1.3.5 The structure of adsorbed hydrogen phases......Page 64
3.4.1.3.6 Vibrational modes of adsorbed hydrogen......Page 84
3.4.1.3.7 Electronic states of adsorbed hydrogen and photoemission spectroscopy......Page 102
3.4.1.3.8 Hydrogen-induced work function changes......Page 111
3.4.1.4.1 General remarks......Page 117
3.4.1.4.2 General theories for hydrogen adsorption......Page 119
3.4.1.4.3 Theories covering specific interaction systems......Page 120
3.4.1.5 List of acronyms......Page 126
3.4.1.6 References for 3.4.1......Page 128
3.8.1.1 Introduction......Page 149
3.8.1.2.1 Valence band orbitals and core levels......Page 151
3.8.1.2.2 Molecular vibrations......Page 152
3.8.1.2.3 Work function changes......Page 153
3.8.1.4.1 Adsorption geometry......Page 154
3.8.1.4.2 Binding energy and desorption temperatures......Page 155
3.8.1.4.3 Trapping and sticking......Page 156
3.8.1.4.5 Ice bilayer......Page 157
3.8.1.5 Tables for 3.8.1......Page 159
3.8.1.6 Figures for 3.8.1......Page 173
3.8.1.7 References for 3.8.1......Page 178
3.8.4.1 Introduction......Page 185
3.8.4.2.1 Structure and bonding of CO2......Page 186
3.8.4.2.2 CO2 adsorption on metal surfaces......Page 187
3.8.4.2.3 CO2 adsorption on chemically modified metal surfaces......Page 189
3.8.4.3.1 Structure and bonding of NO2......Page 191
3.8.4.3.2 NO2 adsorption on metal surfaces......Page 192
3.8.4.3.3 NO2 adsorption on alloy surfaces......Page 194
3.8.4.4.1 Structure and bonding of SO2......Page 195
3.8.4.4.2 SO2 adsorption on metal surfaces......Page 196
3.8.4.4.3 SO2 adsorption on metals with coadsorbed alkali metals......Page 200
3.8.4.5.2 OCS adsorption on metal surfaces......Page 201
3.8.4.6.2 Adsorption of N2O on metal surfaces......Page 202
3.8.4.7.1 Structure and bonding of O3......Page 205
3.8.4.7.3 O3 adsorption on alloy surfaces......Page 206
3.8.4.8 Tables for 3.8.4......Page 207
3.8.4.9 Figures for 3.8.4......Page 232
3.8.4.10 References for 3.8.4......Page 250
3.8.6.1.1 General considerations......Page 257
3.8.6.1.2 Experimental aspects......Page 258
3.8.6.1.3 List of symbols and abbreviations......Page 259
3.8.6.2 Reviews......Page 260
3.8.6.3.1 Methane CH4......Page 262
3.8.6.3.2 Ethane C2H6......Page 268
3.8.6.3.3 Propane C3H8......Page 270
3.8.6.3.4 Butane C4H10......Page 271
3.8.6.3.5 Pentanes C5H12 and higher alkanes......Page 272
3.8.6.3.6 Various (Hydrocarbon fragments, Radicals, etc)......Page 273
3.8.6.4 Alkenes......Page 276
3.8.6.4.1 Ethylene C2H4 and Ethylidyne C2H3......Page 278
3.8.6.4.2 Propene C3H6......Page 290
3.8.6.4.3 Butenes C4H10......Page 292
3.8.6.4.4 Pentenes C5H10 and Hexenes C6H12......Page 296
3.8.6.5.2 Butadiene C4H6......Page 297
3.8.6.6 Alkynes......Page 299
3.8.6.6.1 Acetylene C2H2......Page 300
3.8.6.6.2 Propyne C3H4......Page 306
3.8.6.7 Tables for 3.8.6......Page 309
3.8.6.8 References for 3.8.6......Page 334
3.9.2 Abbreviations used in the text......Page 345
3.9.3 Al2O3......Page 347
3.9.4 CaO......Page 348
3.9.5 CeO2......Page 349
3.9.5.2 H2O and D2O adsorption on CeO2(001) and CeO2(111)......Page 350
3.9.6 alpha-Cr2O3......Page 351
3.9.6.1 CO adsorption......Page 352
3.9.6.4 O2 adsorption......Page 353
3.9.7 CoO......Page 354
3.9.7.3 H2O adsorption......Page 355
3.9.8 Cu2O......Page 356
3.9.8.4 O2 adsorption......Page 357
3.9.9 FeO, Fe3O4 and alpha-Fe2O3......Page 358
3.9.9.1 Ethylbenzene, water and styrene adsorption......Page 360
3.9.10 MgO......Page 363
3.9.10.1 H2O adsorption......Page 366
3.9.10.3 CO2 adsorption......Page 367
3.9.11 NiO......Page 368
3.9.11.2 NO adsorption......Page 372
3.9.11.3 H2O adsorption......Page 374
3.9.11.4 HCOOH adsorption on NiO(111)......Page 375
3.9.11.7 CO2 adsorption on NiO(111)......Page 376
References......Page 377
3.9.12 RuO2......Page 386
3.9.12.1 CO adsorption......Page 387
3.9.13 SnO2......Page 388
3.9.14 TiO2......Page 389
3.9.14.1 CO adsorption......Page 393
3.9.14.3 HCOOH adsorption......Page 395
3.9.14.4 CH3COOH adsorption......Page 398
3.9.15.2 H2O adsorption......Page 399
3.9.16.2 H2 and H adsorption......Page 400
3.9.17 ZnO......Page 401
3.9.17.1 CO adsorption......Page 403
3.9.17.3 CH3OH adsorption......Page 404
3.9.18 Tables of selected adsorbate properties......Page 405
References......Page 412
