Content: The solution theory modeling of gas adsorption on zeolites / Arthur W. Woltman and William H. Hartwig --
Mathematical modeling of adsorption in multicomponent systems / Alexander P. Mathews and Walter J. Weber, Jr. --
Study of mixture equilibria of methane and krypton on 5A zeolite / K.F. Loughlin and G.D. Roberts --
Apparent surface diffusion effects for carbon dioxide/air and carbon dioxide/nitrogen mixtures with pelleted zeolite beds / Richard T. Maurer --
Influence of presorbed water on the sorption of nitrogen by zeolites at ambient temperatures / Donald Peterson --
Selective sorption properties of zeolites / R.M. Dessau --
Four crystal structures of BaxNa₁₂₂x-A (1[less than or equal to] x [less than or equal to] 6) relating to the instability of barium-exchanged zeolite A toward dehydration / Yang Kim, V. Subramanian, Roger L. Firor, and Karl Seff --
The effect of oxygen of photoluminescence and resonance energy transfer in copper (I) Y zeolite / D.H. Strome and K. Klier --
Preparation of copper(II)-exchanged Y zeolites from sodium and ammonium Y zeolites / Richard G. Herman and John B. Bulko --
Lead and cadmium ion exchange of zeolite NaA / Elliot P. Hertzenberg and Howard S. Sherry --
Liquid phase drying applications of zeolites / George W. Young, Joseph R. Kiovsky, and Pramod B. Koradia --
Separation of n-paraffins from wax distillate with supercritical fluids and molecular sieves / Paul Barton and David F. Hajnik --
Polybed pressure-swing adsorption hydrogen processing / R.T. Cassidy --
Separation of hydrogen sulfide-hydrogen mixtures by heatless adsorption / M.D. Whitley and C.E. Hamrin, Jr. / A new process for adsorption separation of gas streams --
George E. Keller, II and Russell L. Jones.
Author(s): William H. Flank (Eds.)
Series: ACS Symposium Series 135
Publisher: American Chemical Society
Year: 1980
Language: English
Pages: 287
City: Washington, D.C
Title Page......Page 1
Half Title Page......Page 3
Copyright......Page 4
ACS Symposium Series......Page 5
FOREWORD......Page 6
PdftkEmptyString......Page 0
PREFACE......Page 7
Derivation of a Lattice Solid Solution Model......Page 9
Development of the Adsorption Equation Parameters......Page 12
Adsorption Isotherms of Argon on Synthetic Zeolite LiX......Page 16
Adsorption Isotherms of Nitrogen on Synthetic Zeolite NaX......Page 21
Adsorption Isotherms of Ammonia on Na X......Page 23
Adsorption Isotherms of Nitrous Oxide on NaY......Page 27
Summary......Page 28
Literature Cited......Page 30
2 Mathematical Modeling of Adsorption in Multicomponent Systems......Page 32
Mathematical Development......Page 33
Adsorption Equilibria in Multicomponent Systems......Page 35
Estimation of Rate Parameters......Page 40
Method of Solution of Multicomponent Model Equations......Page 43
Experimental Methods......Page 45
Experimental Results......Page 46
List of Symbols......Page 56
Literature Cited......Page 57
3 Study of Mixture Equilibria of Methane and Krypton on 5A Zeolite......Page 59
Theory......Page 60
Results and Discussion......Page 62
Theoretical Studies......Page 68
Greek......Page 73
Literature Cited......Page 74
4 Apparent Surface Diffusion Effects for Carbon Dioxide/Air and Carbon Dioxide/Nitrogen Mixtures with Pelleted Zeolite Beds......Page 76
Theoretical Considerations......Page 77
Experimental......Page 89
Results and Discussion......Page 91
Conclusions......Page 101
Nomenclature......Page 103
Subscripts......Page 105
Abstract......Page 106
Literature Cited......Page 107
5 Influence of Presorbed Water on the Sorption of Nitrogen by Zeolites at Ambient Temperatures......Page 108
Experimental......Page 109
Results......Page 114
Discussion......Page 118
Conclusion......Page 121
Literature Cited......Page 122
Materials......Page 123
Competitive Sorption Studies......Page 125
Selective Sorption of Alcohols from Aqueous Solution......Page 126
Selective Sorption Properties of ZSM-5 and ZSM-11......Page 127
Counterdiffusion Studies......Page 128
Effect of n-Paraffin Chain Length......Page 130
Preferential Sorption of n-Paraffins Relative to Branched Cyclic Hydrocarbons......Page 131
Separation of Aromatic Isomers......Page 132
Separation of Functionally Substituted Hydrocarbons......Page 133
ACKNOWLEDGEMENTS......Page 134
LITERATURE CITED......Page 135
7 Four Crystal Structures of BaxNa12-2x-A (1 ≤ x ≤ 6) Relating to the Instability of Barium-Exchanged Zeolite A Toward Dehydration......Page 136
Experimental Section......Page 138
Structure Determination......Page 139
Description of the Structures......Page 147
Discussion......Page 150
Abstract......Page 151
Literature Cited......Page 152
8 The Effect of Oxygen of Photoluminescence and Resonance Energy Transfer in Copper (I) Y Zeolite......Page 153
Experimental......Page 155
Results......Page 157
Discussion......Page 160
ABSTRACT......Page 172
Literature Cited......Page 173
Experimental......Page 175
Results......Page 176
Discussion......Page 180
Literature Cited......Page 183
Experimental Section......Page 185
Results and Discussion......Page 186
Literature Cited......Page 196
11 Liquid Phase Drying Applications of Zeolites......Page 197
Experimental......Page 198
Static Testing.......Page 201
Regeneration Testing.......Page 203
Dynamic Testing.......Page 207
Practical Drier Design......Page 212
Literature Cited......Page 215
Volatility Amplification with Supercritical Fluids......Page 216
Molecular Sieve Separations......Page 220
Experimental Procedures......Page 222
Results and Discussion......Page 226
Future Studies......Page 236
Subscripts......Page 239
Literature Cited......Page 240
13 Polybed1 Pressure-Swing Adsorption Hydrogen Processing......Page 242
Pressure-Swing Adsorption......Page 243
The POLYBED PSA System......Page 246
Hydrogen Recovery Steps......Page 247
Integration of Process Steps......Page 249
Integration into Hydrogen Plant......Page 250
Commercial Operation......Page 252
Conclusion......Page 253
Literature Cited......Page 254
Process Description......Page 255
Theory......Page 256
Experimental Apparatus and Procedure......Page 257
Results and Discussion......Page 260
Breakthrough Runs......Page 265
Literature Cited......Page 267
15 A New Process for Adsorption Separation of Gas Streams......Page 269
Process Description......Page 271
Process Performance......Page 273
Applications of Pressure-Swing Parametric Pumping......Page 277
Summary......Page 279
Literature Cited......Page 280
B......Page 281
D......Page 282
I......Page 283
M......Page 284
P......Page 285
T......Page 286
Z......Page 287
