3rd World Congress on Oxidation Catalaysis, Proceedings of the 3rd World Congress on Oxidation Catalysis

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The overall theme of these papers - taken from the 3rd World Congress - is "Atom Efficient Catalytic Oxidations for Global Technologies". The contributors report their findings with an emphasis on conserving valuable material in their catalytic transformations, as well as conserving energy in an environmentally responsible manner. The subjects presented span a wide range of oxidation reactions and catalysts. These include the currently important area of lower alkane oxidation to the corresponding olefins, unsaturated aldehydes, acids and nitriles. The four featured lectures and seven plenary lectures constitute the general background and overview of the subject matter at hand. The 104 contributed papers and 13 poster manuscripts summarized probe a variety of avenues to achieve catalytically efficient oxidation reactions for the future needs of mankind in a glogal environment.

Author(s): R.K. Grasselli, S.T. Oyama, A.M. Gaffney and J.E. Lyons (Eds.)
Series: Studies in Surface Science and Catalysis 110
Publisher: Elsevier Science Ltd
Year: 1997

Language: English
Pages: 1-1248

Content:
Preface
Pages v-vi
Robert K. Grasselli, S. Ted Oyama, Anne M. Gaffney, James E. Lyons

Molecular mechanism of heterogeneous oxidation — organic and solid state chemists' views Original Research Article
Pages 1-17
Jerzy Haber

The multifunctional properties of heterogeneous catalysts, active and selective in the oxidation of light paraffins Original Research Article
Pages 19-34
F. Cavani, F. Trifirò

Selective oxidation of hydrocarbons catalyzed by heteropoly compounds Original Research Article
Pages 35-42
Makoto Misono, Noritaka Mizuno, Kei Inumaru, Gaku Koyano, Xin-Hong Lu

The future of industrial oxidation catalysis spurred by fundamental advances Original Research Article
Pages 43-59
B. Delmon

Molecular approach to active sites on metallic oxides for partial oxidation reactions Original Research Article
Pages 61-76
Jacques C. Védrine

In situ electrochemically controlled promotion of complete and partial oxidation catalysts Original Research Article
Pages 77-92
Constantinos G. Vayenas, Symeon I. Bebelis

Reductive and oxidative activation of oxygen for selective oxygenation of hydrocarbons Original Research Article
Pages 93-102
Kiyoshi Otsuka

The selective oxidation of methanol: A comparison of the mode of action of metal and oxide catalysts Original Research Article
Pages 103-122
D. Herein, H. Werner, Th. Schedel-Niedrig, Th. Neisius, A. Nagy, S. Bernd, R. Schlögl

Gold as a low-temperature oxidation catalyst: factors controlling activity and selectivity Original Research Article
Pages 123-134
M. Haruta

The selective epoxidation of non-allylic olefins over supported silver catalysts Original Research Article
Pages 135-149
John R. Monnier

Redox molecular sieves as heterogeneous catalysts for liquid phase oxidations Original Research Article
Pages 151-175
R.A. Sheldon

Synergistic effects in multicomponent catalysts for selective oxidation Original Research Article
Pages 177-184
P. Courtine, E. Bordes

Synergetic effects promoted by in operandi surface reconstructions of oxides Original Research Article
Pages 185-196
Eric M. Gaigneaux, J. Naud, P. Ruiz, B. Delmon

Further study on the synergetic effects between MoO3 and SnO2 Original Research Article
Page 197
E.M. Gaigneaux, S.R.G. Carrazán, L. Ghenne, A. Moulard, U. Roland, P. Ruiz, B. Delmon

The nature of the active/selective phase in VPO catalysts and the kinetics of n-butane oxidation Original Research Article
Pages 199-208
D. Dowell, J.T. Gleaves, Y. Schuurman

Understanding the microstructural transformation mechanism which takes place during the activation of vanadium phosphorus oxide catalysts Original Research Article
Pages 209-218
Graham J. Hutchings, Andrew Burrows, Sujata Sajip, Christopher J. Kiely, Kossi E Bere, Jean-Claude Volta, Alain Tuel, Michel Abon

Structural and catalytic aspects of some NASICON - based mixed metal phosphates Original Research Article
Pages 219-226
P.A. Agaskar, R.K. Grasselli, D.J. Buttrey, B. White

Selective reactivity of oxygen adatoms on Mo(112) for methanol oxidation Original Research Article
Pages 227-234
Ken-ichi Fukui, Katsuya Motoda, Yasuhiro Iwasawa

Mechanistic studies of alkane partial oxidation reactions on nickel oxide by modern surface science techniques Original Research Article
Pages 235-244
Nancy R. Gleason, Francisco Zaera

Structure and catalysis of LixNi2−xO2 oxide systems for oxidative coupling of methane Original Research Article
Pages 245-254
T. Miyazaki, T. Doi, T. Miyamae, I. Matsuura

Reaction induced spreading of metal oxides: in situ Raman spectroscopic studies during oxidation reactions Original Research Article
Pages 255-264
Y. Cai, C.-B. Wang, I.E. Wachs

Temperature programmed desorption of ethylene and acetaldehyde on uranium oxides. Evidence of furan formation from ethylene Original Research Article
Pages 265-274
H. Madhavaram, H. Idriss

Active sites of vanadium-molybdenum-containing catalyst for allyl alcohol oxidation: ESR study in situ Original Research Article
Pages 275-284
O.V. Krylov, Nguen Tien Tai, B.V. Rozentuller

Oxidative dehydrogenation of ethane over vanadium and niobium oxides supported catalysts Original Research Article
Pages 285-294
P. Ciambelli, L. Lisi, G. Ruoppolo, G. Russo, J.C. Volta

Partial oxidation of ethane over monolayers of vanadium oxide. effect of the support and surface coverage Original Research Article
Pages 295-304
Miguel A. Bañares, Xingtao Gao, José L.G. Fierro, Israel E. Wachs

The ethane oxidative chlorination process and efficient catalyst for it Original Research Article
Pages 305-313
M.R. Flid, I.I. Kurlyandskaya, Yu.A. Treger, T.D. Guzhnovskaya

Oxidative conversion of LPG to olefins with mixed oxide catalysts: Surface chemistry and reactions network Original Research Article
Pages 315-326
M.V. Landau, M.L. Kaliya, A. Gutman, L.O. Kogan, M. Herskowitz, P.F. van den Oosterkamp

Free radicals as intermediates in oxidative transformations of lower alkanes Original Research Article
Pages 327-335
M.Yu. Sinev, L.Ya. Margolis, V.Yu. Bychkov, V.N. Korchak

Alternative methods to prepare and modify vanadium-phosphorus catalysts for selective oxidation of hydrocarbons Original Research Article
Pages 337-346
V.A. Zazhigalov, J. Haber, J. Stoch, A.I. Kharlamov, I.V. Bacherikova, L.V. Bogutskaya

Active species and working mechanism of silica supported MoO3 and V2O5 catalysts in the selective oxidation of light alkanes Original Research Article
Pages 347-356
A. Parmaliana, F. Arena, F. Frusteri, G. Martra, S. Coluccia, V. Sokolovskii

Mechanistic aspects of propane oxidation over Ni-Co-molybdate catalysts Original Research Article
Pages 357-365
David L. Stern, Robert K. Grasselli

Oxidative dehydrogenation of propane by non-stoichiometric nickel molybdates Original Research Article
Pages 367-373
Doron Levin, Jackie Y. Ying

Selective oxidation of propane into oxygenated compounds over promoted nickel-molybdenum catalysts Original Research Article
Pages 375-382
J. Barrault, C. Batiot, L. Magaud, M. Ganne

Oxidative dehydrogenation of propane on CeNiXOY (0 ≤ x ≤ 1) mixed oxides hydrogen acceptors Original Research Article
Pages 383-392
L. Jalowiecki-Duhamel, A. Ponchel, Y. Barbaux

The role of adsorption in the oxidation of α,β-unsaturated aldehydes on Mo-V-oxide based catalysts Original Research Article
Pages 393-402
B. Stein, C. Weimer, J. Gaube

A new catalyst for propane ammoxidation: the Sn/V/Sb mixed oxide Original Research Article
Pages 403-412
S. Albonetti, G. Blanchard, P. Burattin, S. Masetti, F. Trifirò

Formation of active phases in the Sb-V-, Al-Sb-V-, and Al-Sb-V-W-oxide systems for propane ammoxidation Original Research Article
Pages 413-422
Jerker Nilsson, Angel R. Landa-Cánovas, Staffan Hansen, Arne Andersson

Influence of antimony content in the iron antimony oxide catalyst and reaction conditions on the (Amm)Oxidation of propene and propane Original Research Article
Pages 423-432
Eric van Steen, Gunther Kuwert, Alvin Naidoo, Marco Williams

Catalytic selective oxidation of C2–C4 alkanes over reduced heteropolymolybdates Original Research Article
Pages 433-442
Wen Li, Wataru Ueda

The role of metal oxides as promoters of V2O5/γ-Al2O3 catalysts in the oxidative dehydrogenation of propane Original Research Article
Pages 443-452
J.M. López Nieto, R. Coenraads, A. Dejoz, M.I. Vazquez

Alkane oxidation over bulk and silica-supported VO(H2PO4)2-derived catalysts Original Research Article
Pages 453-460
G.K. Bethke, D. Wang, J.M.C. Bueno, M.C. Kung, H.H. Kung

The nature of the active site of the (VO)2P2O7 catalyst: An investigation of the chemical composition and dynamics of the catalyst surface Original Research Article
Pages 461-470
B. Kubias, F. Richter, H. Papp, A. Krepel, A. Kretschmer

Partial oxidation of C5 hydrocarbons to phthalic and maleic anhydrides over suboxides of vanadia: Use of dicyclopentadiene as a probe molecule Original Research Article
Pages 471-480
U.S. Ozkan, G. Karakas, B.T. Schilf, S. Ang

Role of homogeneous reactions in the control of the selectivity to maleic and phthalic anhydrides in the oxidation of n-pentane Original Research Article
Pages 481-489
Z. Sobalik, P. Ruiz, B. Delmon

Catalytic oxidation of alkanes at millisecond contact times Original Research Article
Pages 491-500
Lanny D. Schmidt, Christian T. Goralski Jr.

Catalytic oxidative dehydrogenation of isobutane in a Pd membrane reactor Original Research Article
Pages 501-507
T.M. Raybold, M.C. Huff

Chemoselective catalytic oxidation of polyols with dioxygen on gold supported catalysts Original Research Article
Pages 509-516
Laura Prati, Michele Rossi

Promoting effects of bismuth in carbon-supported bimetallic Pd-Bi catalysts for the selective oxidation of glucose to gluconic acid Original Research Article
Pages 517-526
M. Wenkin, C. Renard, P. Ruiz, B. Delmon, M. Devillers

Oxidative dehydrogenation of glycolic acid to glyoxylic acid over Fe-P-O catalyst Original Research Article
Pages 527-534
M. Ai, K. Ohdan

Shape selective epoxidation of crotyl alcohol with H2O2 in the presence of TS-1 Original Research Article
Pages 535-544
Graham J. Hutchings, Paul G. Firth, Darren F. Lee, Paul McMorn, Donald Bethell, Philip C. Bulman Page, Frank King, Frederick Hancock

Epoxidation of tertiary allylic alcohols and subsequent isomerization of tertiary epoxy-alcohols : a comparison of some catalytic systems for demanding ketonization processes Original Research Article
Pages 545-556
J.-M. Brégeault, C. Lepetit, F. Ziani-Derdar, O. Mohammedi, L. Salles, A. Deloffre

Metal-catalyzed oxidations with alkyl hydroperoxides: a comparison between tert-butyl hydroperoxide and pinane hydroperoxide Original Research Article
Pages 557-566
H.E.B. Lempers, R.A. Sheldon

On the way to redox-molecular sieves as multifunctional solid catalysts for the one-step conversion of olefins to aldehydes or ketones Original Research Article
Pages 567-576
M. van Klaveren, R.A. Sheldon

Liquid-phase oxidation of cyclohexane to adipic acid catalysed by cobalt containing β-zeolites Original Research Article
Pages 577-584
I. Belkhir, A. Germain, F. Fajula, E. Fache

Nitrogen oxides catalyzed selective oxidation by oxygen in the liquid phase Original Research Article
Pages 585-591
A.B. Levina, S.S. Chornaja, I.A. Grigorjeva, O.N. Sergejeva, S.R. Trusov

Oxidative coupling of isobutene in a two step process Original Research Article
Pages 593-602
H. Hiltner, G. Emig

Solid solutions for cleaning up chemical processes using hydrogen peroxide Original Research Article
Pages 603-613
Sharon L. Wilson, Craig W. Jones

Catalytic wet air oxidation of wastewaters Original Research Article
Pages 615-622
J.C. Béziat, M. Besson, P. Gallezot, S. Juif, S. Durécu

Catalytic partial oxidation of methanol: H2 production for fuel cells Original Research Article
Pages 623-632
L. Alejo, R. Lago, M.A. Peña, J.L.G. Fierro

Catalytic liquid-phase phenol oxidation over metal oxides and molecular sieves. reaction kinetics and mechanism Original Research Article
Pages 633-642
Albin Pintar, Gorazd Berčič, Jurka Batista, Janez Levec

Ammonia oxidation over CuO/TiO2 catalyst: Selectivity and mechanistic study Original Research Article
Pages 643-652
G. Bagnasco, G. Peluso, G. Russo, M. Turco, G. Busca, G. Ramis

Metalloporphyrin-catalysed oxidation of azonaphthol dyes: the mechanism of oxidative bleaching by oxoiron(IV) porphyrins in aqueous solution Original Research Article
Pages 653-662
George Hodges, John R. Lindsay Smith, John Oakes

VOC's abatement: Photocatalytic oxidation of toluene in vapour phase on anatase TiO2 catalyst Original Research Article
Pages 663-672
V. Augugliaro, S. Coluccia, V. Loddo, L. Marchese, G. Martra, L. Palmisano, M. Pantaleone, M. Schiavello

Oxidation processes on stoichiometric and nonstoichiometric hydroxyapatites Original Research Article
Pages 673-681
H. Hayashi, H. Kanai, Y. Matsumura, S. Sugiyama, J.B. Moffat

Oxidative coupling of methane in solid oxide fuel cells Original Research Article
Pages 683-692
Guo Xiu-Mei, Kus Hidajat, Chi-Bun Ching, Hong-Fang Chen

Partial oxidation of methane to synthesis gas in a fast flow membrane reactor Original Research Article
Pages 693-700
M. Alibrando, E.E. Wolf

Sustainable Ni/BaTiO3 catalysts for partial oxidation of methane to synthesis gas Original Research Article
Pages 701-710
R. Shiozaki, A.G. Andersen, T. Hayakawa, S. Hamakawa, K. Suzuki, M. Shimizu, K. Takehira

Synthesis of early transition metal carbides and their application for the reforming of methane to synthesis gas Original Research Article
Pages 711-720
A.P.E. York, J.B. Claridge, C. Márquez-Alvarez, A.J. Brungs, S.C. Tsang, M.L.H. Green

Partial oxidation of methane to synthesis gas using LnCoO3 perovskites as catalyst precursors Original Research Article
Pages 721-730
R. Lago, G. Bini, M.A. Peña, J.L.G. Fierrio

Performance of catalytic properties of reagent catalyst in the processes such as methane oxidative coupling and hydrogen production by methane conversion Original Research Article
Pages 731-736
M.I. Levinbuk, N.Y. Usachev, M.L. Pavlov, A.U. Loginov, L.V. Surkova, E.M. Savin, V.K. Smirnov, I.V. Ivkova

The effect of the PbO loading in the oxidative coupling of methane over PbO/SiO2 catalysts Original Research Article
Pages 737-746
H.J. Lugo, N. Teran, L. Villasmil, G. Castillo, D.M. Finol

Catalytic combustion of ethane over high surface area Ln1−xKxMnO3 (Ln = La, Nd) perovskites: The effect of potassium substitution Original Research Article
Pages 747-756
Y. Ng Lee, F. Sapiña, E. Martímez, J.V. Folgado, V. Cortés Corberán

Effect of redox treatment on methane oxidation over binary catalyst Original Research Article
Pages 757-765
Yu.P. Tulenin, M.Yu. Sinev, V.V. Savkin, V.N. Korchak

Catalytic combustion of methane: Activation and characterization of Pd/Al2O3 Original Research Article
Pages 767-776
Maria Graça Carneiro da Rocha, Roger Frety

Activity of manganese dioxides towards VOC total oxidation in relation with their crystallographic characteristics Original Research Article
Pages 777-785
C. Lahousse, A. Bernier, E. Gaigneaux, P. Ruiz, P. Grange, B. Delmon

Understanding the surface chemistry for supported vanadium oxide systems modified with phosphorus oxide at hydrocarbons oxidation Original Research Article
Pages 787-796
V.A. Zazhigalov, L.V. Bogutskaya, L.V. Lyashenko, I.V. Bacherikova

Effects of cesium doping on the kinetics and mechanism of the n-butane oxidative dehydrogenation over nickel molybdate catalysts Original Research Article
Pages 797-806
L.M. Madeira, M.F. Portela

A comparison of iron molybdate catalysts for methanol oxidation prepared by copreciptation and new sol-gel method Original Research Article
Pages 807-816
A.P. Vieira Soares, M. Farinha Portela, A. Kiennemann

Oxidation catalysts prepared by mechanically and thermally induced spreading of Sb2O3 and V2O5 on TiO2 Original Research Article
Pages 817-827
U.A. Schubert, J. Spengler, R.K. Grasselli, B. Pillep, P. Behrens, H. Knözinger

The effect of preparation parameters on the BET surface area of ZrO2 powder Original Research Article
Pages 829-834
YuanYang Wang, YanZhen Fan, YuHan Sun, SongYing Chen

Preparation of VOHPO4·0.5H2O and (VO)2P2O7 and their catalytic performance for maleic anhydride synthesis Original Research Article
Pages 835-845
T. Miyake, T. Doi

Hydroxylation of benzene on ZSM5 type catalysts Original Research Article
Pages 847-856
M. Häfele, A. Reitzmann, E. Klemm, G. Emig

Direct hydroxylation of benzene to phenol by nitrous oxide Original Research Article
Pages 857-864
Anthony K. Uriarte, Mikhail A. Rodkin, Michael J. Gross, Aleksandr S. Kharitonov, Gennady I. Panov

Rapid catalytic oxygenation of hydrocarbons with perhalogenated ruthenium porphyrin complexes Original Research Article
Pages 865-872
John T. Groves, Kirill V. Shalyaev, Marcella Bonchio, Tommaso Carofiglio

Ethanol oxidation using ozone over supported maganese oxide catalysts: An in situ laser raman study Original Research Article
Pages 873-882
Wei Li, S. Ted Oyama

Generation of singlet oxygen from the catalytic system H2O2/Ca(OH)2 and applications to the selective oxidation of unsaturated compounds Original Research Article
Pages 883-892
J.M. Aubry, V. Nardello

Toluene gas phase oxidation to benzaldehyde and phenol over V-containing micro- and mesoporous materials Original Research Article
Pages 893-902
G. Centi, F. Fazzini, L. Canesson, A. Tuel

A novel selective oxidation catalyst: ultrafine complex molybdenum based oxide particles Original Research Article
Pages 903-908
Y. Fan, W. Kuang, W. Zhang, Yi Chen

Liquid phase oxidation of alkylaromatic hydrocarbons over titanium silicalites Original Research Article
Pages 909-918
Georgi N. Vayssilov, Zdravka Popova, Stefanka Bratinova, Alain Tuel

Coupled vanadyl centres in vanadium phosphorus oxide catalysts: Essential structural units for effective catalytic performance in the ammoxidation of methylaromatics Original Research Article
Pages 919-928
A. Brückner, A. Martin, B. Lücke, F.K. Hannour

Ammoxidation of xylenes-kinetics and selectivity Original Research Article
Pages 929-937
Klaus Beschmann, Stephan Fuchs, Thomas Hahn

Vanadium-titanium oxide system in β-picoline oxidation Original Research Article
Pages 939-946
E.M. Al'kaeva, T.V. Andrushkevich, G.A. Zenkovets, G.N. Kryukova, S.V. Tsybulya, E.B. Burgina

Selective alkene epoxidation by molecular oxygen in the presence of aldehyde and different type catalysts containing cobalt Original Research Article
Pages 947-955
O.A. Kholdeeva, I.V. Khavrutskii, V.N. Romannikov, A.V. Tkachev, K.I. Zamaraev

Epoxidation of olefins over thermally stable polyimide-supported Mo(VI) complexes Original Research Article
Pages 957-964
J.H. Ahn, J.C. Kim, S.K. Ihm, D.C. Sherrington

Selective partial oxidation of propylene to propylene oxide on Au/Ti-MCM catalysts in the presence of hydrogen and oxygen Original Research Article
Pages 965-972
Yuri A. Kalvachev, Toshio Hayashi, Susumu Tsubota, Masatake Haruta

Immobilization of triazacyclononane-type metal complexes on inorganic supports via covalent linking: spectroscopy and catalytic activity in olefin oxidation Original Research Article
Pages 973-980
Y.V. Subba Rao, D.E. De Vos, B. Wouters, P.J. Grobet, P.A. Jacobs

Simultaneous determination of reaction kinetics and oxygen activity during selective oxidation of an aldehyde over an oxidic multicomponent catalyst Original Research Article
Pages 981-988
M. Estenfelder, H.-G. Lintz

On the mechanism of the selective oxy-dehydrogenation of n-butenes to 1,3-butadiene on magnesium ferrite: an FT-IR study Original Research Article
Pages 989-998
E. Finocchio, G. Busca, G. Ramis, V. Lorenzelli

Cyclohexene oxidation catalyzed by titanium modified hexagonal Y type zeolites Original Research Article
Pages 999-1006
Kenneth J. Balkus Jr., Alla K. Khanmamedova, Jimin Shi