Photophysics of Supramolecular Architectures

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This reference provides collective information about the physical andphotophysical changes of supramolecules after encapsulation. It coversluminescent systems involving a range of host molecules such as calixarenes, cyclodextrin, resorcinanene-crowns, pillararenes, cucurbituril, andmetallacycles. Chapters also discuss the effect of the macrocyclic environment onthe properties of functionalized molecules, including the variations in foldingand unfolding patterns. Each chapter is supplemented with detailed references,making this an ideal resource for scholars interested in supramolecularphotophysics.

Author(s): Paulpandian Muthu Mareeswaran, Palaniswamy Suresh, Seenivasan Rajagopal
Publisher: Bentham Science Publishers
Year: 2022

Language: English
Pages: 235
City: Singapore

Cover
Title
Copyright
End User License Agreement
Contents
Foreword
Preface
List of Contributors
Luminescent Cyclodextrin Systems and Their Applications
Bosco Christin Maria Arputham Ashwin1, Venkatesan Sethuraman2 and Paulpandian Muthu Mareeswaran2,*
INTRODUCTION
HOST-GUEST SYSTEMS
LUMINESCENT CYCLODEXTRINS
FLUORESCENT SENSORS
BIOSENSORS
THERAPEUTIC APPLICATION
CONCLUSION
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Calixarene Based Luminescent Systems
Bosco Christin Maria Arputham Ashwin1, Venkatesan Sethuraman2 and Paulpandian Muthu Mareeswaran2,*
INTRODUCTION
LUMINESCENT HOST-GUEST SYSTEMS
Fluorescent Calixarene
ION SENSING APPLICATIONS
Anion Sensors
Solid State Sensor
MOLECULAR RECOGNITION
LUMINESCENT LANTHANOID CALIXARENE COMPLEXES
CONCLUSION
CONSENT OF PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Resorcinarene Crowns as Versatile Host Molecules and Their Potential Applications
Selvaraj Devi1, Somasundaram Anbu Anjugam Vandarkuzhali2,* and Vairaperumal Tharmaraj3,*
INTRODUCTION
Synthesis of Resorcinarenes
Selective Functionalization of Upper Rim Resorcinarene Crowns
Selective functionalization of lower rim resorcinarene crowns
APPLICATIONS OF RESORCINARENE CROWNS
Chemical Separations
Chemical Sensors
Catalytic Activity
Lithographic Application
Antioxidant and Antibacterial Applications
CONCLUSION
CONSENT OF PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Pillararenes: Younger Luminescent Supramolecular Systems
Palaniswamy Suresh1,* and Jeyaraj Belinda Asha1
INTRODUCTION
Pillararenes
Structure of Pillararenes
Synthesis of Pillararenes
Host-Guest Binding Behaviours of Pillararenes
Photophysical Behaviours of Pillararenes
Pillararenes Based Luminescence Systems
Pillararenes in Sensors Applications
Pillararenes in Metal Ions Scavenging
Pillararenes Derived Stimuli Luminescent Materials
CONCLUSIONS
CONSENT OF PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENT
REFERENCES
Cucurbit[n]urils Based Molecular Recognition with Fluorescence Signalling
Liju R.1 and E. Rajkumar1,*
INTRODUCTION
Cucurbituril CB[n]
Structural Features of CB[n]s
Physical Properties of CB[n]s
CB[n] Based Sensors
Detection Mechanism
Direct Binding Assay
Associative Binding Assay
Indicator Displacement Assay (IDA)
Detection of Metal Ions
Detection of Amino Acids and Peptide Molecules
Detection of Biomolecules
Detection of Organic Compound
Cucurbit[n]urils in Imaging and in Photodynamic Therapy
CONCLUSION
CONSENT OF PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENT
REFERENCES
Rhenium(I)-Based Metallacycles for Sensing Applications
Murugesan Velayudham1,* and Pounraj Thanasekaran2,*
INTRODUCTION
Rhenium(I)-Based Metallacycles
Binuclear Re(I) Complex
Trinuclear Re(I) Complex
Tetranuclear Re(I) Complex
Hexanuclear Re(I) Complex
Octanuclear Re(I) Complex
CONCLUSIONS
CONSENT FOR PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGEMENTS
REFERENCES
Recent Developments in the Dynamics of Fluorescently Labelled Macromolecules
Kandhasamy Durai Murugan1,*, Pandi Muthirulan2 and Vijayanand Chandrasekaran3
INTRODUCTION
POLY(ACRYLIC ACIDS) – STRUCTURAL TRANSITION AND DYNAMICS
PHOTOPHYSICS OF FLUOROPHORES IN POLYELECTROLYTES
PHOTOPHYSICS OF EXCITED STATE FLUOROPHORES
IMPORTANCE OF PHOTOPHYSICS AND PHOTOCHEMISTRY OF POLYMERIC MATERIALS
PHOTOPHYSICS AND CONFORMATIONAL DYNAMICS OF POLYELECTROLYTES
STEADY STATE FLUORESCENCE STUDIES AND FLUORESCENCE QUENCHING
EXCITED STATE ENERGY AND ELECTRON TRANSFER
EXCIMER AND EXCIPLEX FORMATION
TIME–RESOLVED FLUORESCENCE STUDIES AND SOLVATION DYNAMICS
POLYMER COMPLEXES
INTERPOLYMER COMPLEXES
HYDROGEN BONDED INTERPOLYMER COMPLEXES
CONCLUSION
CONSENT OF PUBLICATION
CONFLICT OF INTEREST
ACKNOWLEDGMENT
REFERENCES
Subject Index
Back Cover