This annual review of the literature, the 50th volume in the present series, provides a comprehensive and critical survey of a vast field of study involving organophosphorus compounds, ranging from phosphines, their chalcogenide derivatives and phosphonium salts, phosphorus (III) acid derivatives, phosphorus (V) acids, penta- and hexa-coordinated phosphorus compounds, phosphazenes and related phosphorus-nitrogen bonded compounds. Coverage is also presented of applications of organophosphorus compounds in homogeneous catalysis for synthesis of bulk and fine chemicals and also in applications as reagents in green synthetic procedures.
Author(s): Lee J. Higham, David W Allen, John C. Tebby
Publisher: Royal Society of Chemistry
Year: 2021
Language: English
Pages: 503
City: London
Cover
Preface
Author biographies
Contents
Abbreviations
Phosphines: preparation and reactivity
1 Reactions of elemental phosphorus
2 Organophosphorus catalysis
3 Phosphorus and frustrated Lewis pair chemistry
References
Tertiary phosphines: preparation and reactivity
1 Introduction
2 Preparation of phosphines
3 Reactivity of phosphines
References
Tervalent phosphorus acid derivatives
1 Introduction
2 Halophosphines
3 Tervalent phosphorus esters
4 Tervalent phosphorus amides
5 Mixed phosphorus (III) compounds
compounds
References
Phosphine chalcogenides
References
Phosphonium salts and P-ylides
1 Introduction
2 Phosphonium salts
3 Phosphonium based ionic liquids (PILs)
4 P-Ylides (phosphoranes)
References
Homogeneous catalysis for bulk and fine chemicals. Adventures with phosphorus ligands
1 Introduction
2 The first steps. Using water-soluble bisphosphine ligands in asymmetric imine hydrogenation
3 Research for bulk chemicals. Use of bulky bidentate phosphites in isomerising hydroformylation
4 Asymmetric hydrogenation part 2. Monodentate phosphoramidites
5 Secondary phosphine oxides. A new class of stable (chiral) ligands
Acknowledgements
References
Quinquevalent phosphorus acids
1 Introduction
2 Phosphoric acids and their derivatives
3 Phosphonic acids and their derivatives
4 Phosphinic acids and their derivatives
5 Quinquevalent phosphorus acids and their derivatives as catalysts
Acknowledgements
References
Pentacoordinated and hexacoordinated compounds
1 Introduction
2 Pentacoordinated phosphorus compounds
3 Hexacoordinated phosphorus compounds
References
Phosphazenes
a) Acyclic phosphazenes
b) Cyclophosphazenes
c) Polyphosphazenes
References
Green synthetic approaches in organophosphorus chemistry: recent developments
1 Introduction
2 Recent developments in green synthetic approaches in organophosphorus chemistry
3 Conclusions
Acknowledgements
References
